Safety Data Sheet acc. to OSHA HCS (29 CFR )

Transcription

1 Page 1 of 10 1 Identification Product identifier Trade name: Black Mamba Article number: No other identifiers Recommended use and restriction on use Recommended use: Application to enhance coated surfaces. Restrictions on use: No relevant information available. Details of the supplier of the Manufacturer/Supplier: Majestic Solutions, Inc Corporation Parkway, Ste. 110 Raleigh, NC Emergency telephone number: Hazard(s) identification Classification of the substance or mixture GHS05 Corrosion Eye Dam. 1 H318 Causes serious eye damage. GHS07 Skin Irrit. 2 H315 Causes skin irritation. Additional information: There are no other hazards not otherwise classified that have been identified. 0 % of the mixture consists of component(s) of unknown toxicity. Label elements GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms: GHS05 Signal word: Danger Hazard-determining components of labeling: Fatty acids, coco, reaction products with diethylenetriam ine and soya f atty acids, ethoxylated, chloromethane-quaternized Kerosine (petroleum) Hazard statements: H315 Causes skin irritation. (Cont'd. on page 2)

2 Page 2 of 10 (Cont'd. of page 1) H318 Causes serious eye damage. Precautionary statements: P264 Wash thoroughly after handling. P280 Wear protective gloves and eye protection. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302+P352 IF ON SKIN: Wash with plenty of water. P310 Immediately call a POISON CENTER/doctor. P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: Kerosine (petroleum) <10% Asp. Tox. 1, H304 Skin Irrit. 2, H315; STOT SE 3, H336 Flam. Liq. 4, H Propylene Glycol <10% Fatty acids, coco, reaction products with diethylenetriamine and soya fatty acids, <10% ethoxylated, chloromethane-quaternized Eye Dam. 1, H318 Acute Tox. 4, H302; Skin Irrit. 2, H315 Additional information: For the listed ingredient(s), the identity and exact percentage(s) are being withheld as a trade secret. For the wording of the listed Hazard Statements refer to section First-aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Immediately rinse with water. If skin irritation continues, consult a doctor. After eye contact: Protect unharmed eye. Remove contact lenses if worn. Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; immediately call for medical help. Information for doctor Most important symptoms and effects, both acute and delayed: Headache (Cont'd. on page 3)

3 Page 3 of 10 Coughing Irritant to skin and mucous membranes. Strong irritant with the danger of severe eye injury. Gastric or intestinal disorders when ingested. Danger: Causes serious eye damage. Indication of any immediate medical attention and special treatment needed: Medical supervision for at least 48 hours. (Cont'd. of page 2) 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: Water fog / haze Foam Fire-extinguishing powder Carbon dioxide For safety reasons unsuitable extinguishing agents: Water stream. Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. Additional information: Cool endangered receptacles with water fog. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures: Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation. Particular danger of slipping on leaked/spilled product. Environmental precautions: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Methods and material for containment and cleaning up: Absorb liquid components with liquid-binding material. Pick up mechanically. Send for recovery or disposal in suitable receptacles. Reference to other sections: See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Cont'd. on page 4)

4 Page 4 of 10 (Cont'd. of page 3) 7 Handling and storage Handling Precautions for safe handling: Use only in well ventilated areas. Keep out of reach of children. Information about protection against explosions and fires: No special measures required. Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and receptacles: Avoid storage near extreme heat, ignition sources or open flame. Information about storage in one common storage facility: Store away from foodstuffs. Store away from oxidizing agents. Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. Specific end use(s): No relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: Kerosine (petroleum) REL (USA) Long-term value: 100 mg/m³ Kerosine only TLV (USA) Long-term value: 200 mg/m³ as total hydrocarbon vapor; Skin; P EL (Canada) Long-term value: 200 mg/m³ Skin EV (Canada) Long-term value: 200(G) mg/m³ as total hydrocarbon vapour, Skin LMPE (Mexico) Long-term value: 200 mg/m³ A3, PIEL Propylene Glycol WEEL (USA) Long-term value: 10 mg/m³ EV (Canada) Long-term value: 155* 10** mg/m³, 50* ppm *vapour and aerosol;**aerosol only Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. (Cont'd. on page 5)

5 Page 5 of 10 Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. Engineering controls: No relevant information available. Breathing equipment: Not required under normal conditions of use. Use suitable respiratory protective device in case of insufficient ventilation. Protection of hands: (Cont'd. of page 4) Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Eye protection: Safety glasses Body protection: Protective work clothing Limitation and supervision of exposure into the environment No relevant information available. 9 Physical and chemical properties Information on basic physical and chemical properties General information Appearance: Form: Pasty Color: White or gray Odor: Solvent-like Odor threshold: ph-value: Change in condition: Melting point/melting range: Boiling point/boiling range: Flash point: Not applicable. Flammability (solid, gaseous): Not applicable. Auto-ignition temperature: Decomposition temperature: Auto igniting: Product is not self-igniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Upper: (Cont'd. on page 6)

6 Page 6 of 10 Oxidizing properties: Vapor pressure: Density: Relative density: Vapor density: Evaporation rate: Solubility in / Miscibility with: Water: Soluble. Partition coefficient (n-octanol/water): Viscosity: Dynamic: Kinematic: Other information No relevant information available. (Cont'd. of page 5) 10 Stability and reactivity Reactivity: No relevant information available. Chemical stability: Stable under normal temperatures and pressures. Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. Possibility of hazardous reactions: Reacts with strong alkali. Reacts with strong acids and oxidizing agents. Conditions to avoid: Excessive heat. Incompatible materials: Oxidizers, strong bases, strong acids Hazardous decomposition products: Carbon monoxide and carbon dioxide Nitrogen oxides (NOx) 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: None. Primary irritant effect: On the skin: Irritant to skin and mucous membranes. On the eye: Strong irritant with the danger of severe eye injury. Sensitization: No sensitizing effects known. Additional toxicological information: Carcinogenic categories IARC (International Agency for Research on Cancer) (Cont'd. on page 7)

7 Page 7 of 10 NTP (National Toxicology Program): OSHA-Ca (Occupational Safety & Health Administration): Probable route(s) of exposure: Ingestion. Inhalation. Eye contact. Skin contact. Acute effects (acute toxicity, irritation and corrosivity): Causes serious eye damage. Irritating to skin. Repeated dose toxicity: No relevant information available. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Germ cell mutagenicity: Based on available data, the classification criteria are not met. Carcinogenicity: Based on available data, the classification criteria are not met. Reproductive toxicity: Based on available data, the classification criteria are not met. STOT-single exposure: Based on available data, the classification criteria are not met. STOT-repeated exposure: Based on available data, the classification criteria are not met. Aspiration hazard: Based on available data, the classification criteria are not met. (Cont'd. of page 6) 12 Ecological information Toxicity Aquatic toxicity: No relevant information available. Persistence and degradability: No relevant information available. Behavior in environmental systems Bioaccumulative potential: No relevant information available. Mobility in soil: No relevant information available. Ecotoxical effects: Remark: Due to mechanical actions of the product (e.g. agglutinations), damages may occur. Harmful to fish Additional ecological information General notes: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Other adverse effects: No relevant information available. (Cont'd. on page 8)

8 Page 8 of 10 (Cont'd. of page 7) 13 Disposal considerations Waste treatment methods Recommendation: Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts in accordance with Local Authority requirements. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. Uncleaned packagings Recommendation: Disposal must be made according to official regulations. Recommended cleansing agent: Water, if necessary with cleansing agents. 14 Transport information UN-Number DOT, ADR, IMDG, IATA Not regulated. UN proper shipping name DOT, ADR, IMDG, IATA Not regulated. Transport hazard class(es) DOT, ADR, IMDG, IATA Class Not regulated. Packing group DOT, ADR, IMDG, IATA Not regulated. Environmental hazards Not applicable. Special precautions for user Not applicable. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. UN "Model Regulation" Not regulated. 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture United States (USA) SARA Section 302 (extremely hazardous substances): Section 304 (emergency release notification): (Cont'd. on page 9)

9 Page 9 of 10 Sections 311/312 (hazardous chemical threshold planning quantity in pounds): Section 355 (extremely hazardous substances): Section 313 (Specific toxic chemical listings): TSCA (Toxic Substances Control Act) All ingredients are listed. Proposition 65 (California) Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: Carcinogenic categories EPA (Environmental Protection Agency): (Cont'd. of page 8) IARC (International Agency for Research on Cancer): Kerosine (petroleum) 3 NIOSH-Ca (National Institute for Occupational Safety and Health): Canadian substance listings Canadian Domestic Substances List (DSL): All ingredients are listed. Canadian Ingredient Disclosure list (limit 0.1%): Canadian Ingredient Disclosure list (limit 1%): Propylene Glycol 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision 12/11/2015 / - Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods (Cont'd. on page 10)

10 Page 10 of 10 (Cont'd. of page 9) DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Flam. Liq. 4: Flammable liquids, Hazard Category 4 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 Asp. Tox. 1: Aspiration hazard, Hazard Category 1 Sources Website, European Chemicals Agency ( Website, US EPA Substance Registry Services ( home/overview/home.do) Website, Chemical Abstracts Registry, American Chemical Society ( Patty's Industrial Hygiene, 6th ed., Rose, Vernon, ed. ISBN: ISBN: Casarett and Doull's Toxicology: The Basic Science of Poisons, 8th Ed., Klaasen, Curtis D., ed., ISBN: s, Individual Manufacturers SDS Prepared by: Majestic Solutions 1001 Corporation Parkway, Ste. 110 Raleigh, NC 26710