Safety Data Sheet acc. to OSHA HCS

Transcription

1 Page 1/10 * 1 Identification Product identifier Article number: Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Laboratory chemicals Details of the supplier of the safety data sheet Manufacturer/Supplier: PerkinElmer Health Sciences B.V. Rigaweg TH Groningen The Netherlands P.O. Box GE Groningen The Netherlands Phone: Fax: Information department: Quality Assurance, Environment, Safety & Health (QA/ESH) SDS.Groningen@perkinelmer.com Emergency telephone number: CHEMTREC (within U.S.A. and Canada) CHEMTREC (from outside U.S.A. and Canada) * 2 Hazard(s) identification Classification of the substance or mixture GHS08 Health hazard STOT SE 2 STOT RE 2 Asp. Tox. 1 H371 May cause damage to organs. H373 May cause damage to organs through prolonged or repeated exposure. H304 May be fatal if swallowed and enters airways. GHS05 Corrosion Eye Dam. 1 H318 Causes serious eye damage. GHS09 Environment Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects. (Contd. on page 2)

2 Page 2/10 (Contd. of page 1) GHS07 Acute Tox. 4 H312 Harmful in contact with skin. Skin Irrit. 2 H315 Causes skin irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. Label elements GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS05 GHS07 GHS08 GHS09 Signal word Danger Hazard-determining components of labeling: Mixture of Phenylethylxylenes Phenol, ethoxylated, phosphated, diethanolamine salt Hazard statements H312 Harmful in contact with skin. H315 Causes skin irritation. H318 Causes serious eye damage. H317 May cause an allergic skin reaction. H371 May cause damage to organs. H373 May cause damage to organs through prolonged or repeated exposure. H304 May be fatal if swallowed and enters airways. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 If swallowed: Immediately call a poison center/doctor. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 Take off contaminated clothing and wash before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P302+P352 If on skin: Wash with plenty of water. Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. (Contd. on page 3)

3 Page 3/10 (Contd. of page 2) * 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture: consisting of the following components. Dangerous components: Mixture of Phenylethylxylenes STOT SE 2, H371; STOT RE 2, H373; Asp. Tox. 1, H304 Aquatic Acute 1, H400; Aquatic Chronic 1, H410 Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315; Skin Sens. 1, H Alkylphenol Polyglycolether Aquatic Chronic 2, H411 Skin Irrit. 2, H315; Eye Irrit. 2A, H (2-butoxyethoxy)ethanol Eye Irrit. 2, H Phenol, ethoxylated, phosphated, diethanolamine salt Eye Dam. 1, H318 Skin Irrit. 2, H % 20-40% % % Non-Dangerous components ,5-Diphenyloxazole (PPO) 2.5% ,4-Bis-(2-methylstyryl)-benzene (bis-msb) 2.5% water, distilled, conductivity or of similar purity Additional information: For the wording of the listed risk phrases refer to section First-aid measures Description of first aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: Foam Fire-extinguishing powder Carbon dioxide (Contd. on page 4)

4 Page 4/10 Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: Wear fully protective suit. (Contd. of page 3) 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Handling: Precautions for safe handling No special measures required. Information about protection against explosions and fires: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: phosphoric acid PEL 1 mg/m³ REL Short-term value: 3 mg/m³ Long-term value: 1 mg/m³ TLV Short-term value: 3 mg/m³ Long-term value: 1 mg/m³ Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. (Contd. on page 5)

5 Page 5/10 Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Breathing equipment: Not required. Protection of hands: (Contd. of page 4) Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Fluid Color: Colorless Odor: Characteristic ph-value at 20 C (68 F): 5.9 Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 295 C (563 F) Flash point: 149 C (300 F) Ignition temperature: 450 C (842 F) Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. (Contd. on page 6)

6 Page 6/10 Density at 20 C (68 F): 1.00 g/cm³ (8.345 lbs/gal) Solubility in / Miscibility with Water: Not miscible or difficult to mix. Solvent content: VOC content: % Other information No further relevant information available. (Contd. of page 5) 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: Carbon monoxide and carbon dioxide * 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin: Irritant to skin and mucous membranes. on the eye: Irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant Carcinogenic categories IARC (International Agency for Research on Cancer) ,6-di-tert-butyl-p-cresol 3 NTP (National Toxicology Program) OSHA-Ca (Occupational Safety & Health Administration) 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. (Contd. on page 7)

7 Page 7/10 Behavior in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. (Contd. of page 6) * 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. * 14 Transport information UN-Number ADR, IMDG, IATA UN3082 UN proper shipping name ADR 3082 ENVIRONMENTALLY HAZARDO SUBSTANCE, LIQUID, N.O.S. (Mixture of Phenylethylxylenes, Alkylphenol Polyglycolether) IMDG ENVIRONMENTALLY HAZARDO SUBSTANCE, LIQUID, N.O.S. (Mixture of Phenylethylxylenes, Alkylphenol Polyglycolether), MARINE POLLUTANT IATA ENVIRONMENTALLY HAZARDO SUBSTANCE, LIQUID, N.O.S. (Mixture of Phenylethylxylenes, Alkylphenol Polyglycolether) Transport hazard class(es) ADR Class 9 (M6) Miscellaneous dangerous substances and articles Label 9 IMDG, IATA Class 9 Miscellaneous dangerous substances and articles (Contd. on page 8)

8 Page 8/10 Label 9 Packing group ADR, IMDG, IATA III (Contd. of page 7) Environmental hazards: Product contains environmentally hazardous substances: Mixture of Phenylethylxylenes, Alkylphenol Polyglycolether Marine pollutant: Yes Symbol (fish and tree) Special marking (ADR): Symbol (fish and tree) Special marking (IATA): Symbol (fish and tree) Special precautions for user Warning: Miscellaneous dangerous substances and articles Danger code (Kemler): 90 EMS Number: F-A,S-F Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: Not dangerous according to the above specifications. UN "Model Regulation": UN3082, Environmentally hazardous substances, liquid, n.o.s. (Mixture of Phenylethylxylenes, Alkylphenol Polyglycolether), 9, III * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredient is listed. Section 313 (Specific toxic chemical listings): TSCA (Toxic Substances Control Act): Mixture of Phenylethylxylenes (2-butoxyethoxy)ethanol Phenol, ethoxylated, phosphated, diethanolamine salt ,5-Diphenyloxazole (PPO) water, distilled, conductivity or of similar purity Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: (Contd. on page 9)

9 Page 9/10 Chemicals known to cause developmental toxicity: (Contd. of page 8) Carcinogenic categories EPA (Environmental Protection Agency) TLV (Threshold Limit Value established by ACGIH) ,6-di-tert-butyl-p-cresol A4 MAK (German Maximum Workplace Concentration) ,6-di-tert-butyl-p-cresol 4 NIOSH-Ca (National Institute for Occupational Safety and Health) National regulations: Technical instructions (air): Class Share in % Wasser NK Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H371 May cause damage to organs. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. Department issuing SDS: Quality Assurance, Environment, Safety & Health (QA/ESH) Contact: SDS.Groningen@perkinelmer.com Date of preparation / last revision 10/28/2015 / 2 Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) (Contd. on page 10)

10 Page 10/10 (Contd. of page 9) ICAO: International Civil Aviation Organisation ICAO-TI: Technical Instructions by the "International Civil Aviation Organisation" (ICAO) ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (A) HMIS: Hazardous Materials Identification System (A) VOC: Volatile Organic Compounds (A, EU) Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 STOT SE 2: Specific target organ toxicity - Single exposure, Hazard Category 2 STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2 Asp. Tox. 1: Aspiration hazard, Hazard Category 1 Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - Chronic Hazard, Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2 * Data compared to the previous version altered.