SAFETY DATA SHEET. For the treatment and control of cobalt and selenium deficiency in sheep and cattle HORIZON AGRESOURCES (NZ) LTD
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1 Page 1 of 6 1. IDENTIFICATION OF SUBSTANCE AND SUPPLIER Product name: ACVM Approval No. Recommended use: Supplier: Address: Cobalject Se A06903 For the treatment and control of cobalt and selenium deficiency in sheep and cattle HORIZON AGRESOURCES (NZ) LTD Gloucester Court, Contact number: Gloucester St, Napier Emergency contact number: (24 hours) Document version and date: December DETAILS OF FORMULATION Product ingredients: C.A.S Number Concentration: Hydroxocobalamin (Vitamin B12) g/l Selenium selenate g/l Remaining ingredients are commercially sensitive and cannot be disclosed in a public document. 3. EPA HAZAR CLASSIFICATION This product is an approved substance under the Hazardous Substances and New Organisms Act (HSNO). Approval code: HSR Hazard Classification Hazard statements 6.1E Acute oral toxin May be harmful if swallowed 9.1C Aquatic toxin (crustacean and algae) Harmful to aquatic life with long lasting effects. 9.2C Soil toxin Harmful to the soil environment KEEP OUT OF REACH OF CHILDREN Warning Dangerous to the environment Avoid contamination of any water supply with product or empty container. Avoid release to the environment.
2 Page 2 of 6 4. FIRST AID INSTRUCTIONS Necessary first aid measures: Workplace facilities: Required instructions: Notes for medical personnel: 5. FIRE FIGHTING MEASURES Fire and explosion hazards: Suitable extinguishing substances: Unsuitable extinguishing substances: Products of combustion: Protective equipment: Hazchem code: For advice contact the National Poisons Centre on 0800 POISON ( ), or a doctor immediately. INGESTION: If swallowed seek medical attention immediately. Have product container to hand. Rinse mouth out. Do NOT induce vomiting. EYES: If splashed in eyes wash out immediately with water. SKIN: If skin or hair contact occurs remove contaminated clothing and flush skin and hair with running water. INHALATION: Remove to fresh air. SELF-INJECTION: Seek medical attention immediately. Have product container to hand. No special facilities required. Observe good work practices and avoid skin and eye contact. Wash hands and exposed skin before meals and after use. Do not eat or drink while using. Launder protective clothing separately from other clothing, and before each re-use. Apply symptomatic therapy (no specific antidote). Note the nature of the product (reproductive/developmental toxin, and sensitizer). Non flammable, Non combustible, Non explosive Carbon dioxide, extinguishing powder or water jet. Fight larger fires with water jet or alcohol resistant foam. Not known. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Water. May form toxic mixtures in air and may accumulate in sumps, pits and other low-lying spaces, forming potentially explosive mixtures. Self-contained breathing apparatus. Safety boots, non-flammable overalls, gloves, hat and eye protection. 1T 6. ACCIDENTAL RELEASE MEASURES Emergency procedures: Containment for bulk storage: Wear suitable protective clothing. Restrict access to contaminated area. Contain the spill and prevent further dispersion. Retrieve intact containers from site. Place damaged containers into containment devices. Absorb spills with inert material (e.g. sand or vermiculite), and place in waste containers. Wash the area with water and absorb with further inert material. Collect spilled material and place in sealable containers for subsequent disposal. Prevent contamination of water courses or sewers. Dispose of waste safely. If greater than 1000L is stored in one location, secondary containment and emergency plans to manage any potential spills must be in place. In all cases design storage to prevent discharge to stormwater drains. (If this occurs contact your regional council immediately).
3 7. HANDLING AND STORAGE Precautions for safe handling: Regulatory requirements: Approved handler requirements Conditions for safe storage: Store site requirements: Packaging: Page 3 of 6 Apply with well-maintained and calibrated equipment. Handle with care. Store below 25 C. Protect from light. Store locked up and out of reach of children This substance is subject to a requirement for an emergency management plan, secondary containment and signage, whenever it is held in quantities of 100L or more. See Hazardous Substances (Emergency management) regulations 25 to 42. Packaging Schedule 3 (UN Packing Group III) for quantities >1L (Hazardous Substances Packaging Regulations 2001). 8. EXPOSURE CONTROL/PERSONAL PROTECTION Work place exposure standards: Application in the workplace Exposure standards outside the workplace: Engineering controls: Personal protection: References: Sodium selenite 0.1 mg/m 3 (WES-TWA) Prevent exposure by using engineering controls, personal protective equipment and work practices that prevent skin and eye contact. TELs and EELs are not set at this time. Clothing should consist of overalls with long sleeves, and impervious gloves. Wear eye protection (e.g. glasses, goggles or face shield). 9. PHYSICAL AND CHEMICAL CHARACTERISTICS Formulation Type: Appearance: Specific gravity: Vapour pressure: Solubility in water: Auto ignition temperature: Hazards: Liquid Clear red-tinted solution g/ml Soluble in water. Not known Non-flammable; non-corrosive; non-oxidizing; non-explosive. 10. STABILITY AND REACTIVITY Stability of the substance: Conditions to avoid: Material to avoid: Hazardous decomposition products: Hazardous polymerization: Specific data: Stable under normal conditions of use and storage. No specific conditions to avoid No specific materials to avoid. Hazardous decomposition products are expected when heated to decomposition temperatures. Use appropriate PPE when fighting fires. Components are not expected to form hazardous polymers.
4 11. TOXICOLOGICAL INFORMATION Data and interpretation: Summary data: Page 4 of 6 Harmful if swallowed. Exposure may cause skin allergy. Moxidectin can affect development of the unborn child and/or reproduction. May cause harm to breast-fed children. Sodium selenate Refer to EPA website for full details of toxicity classifications: 6.1B (oral) R PHRASE: R 25 [Company Data] 6.1B (inhalation) Inhalation Form: R PHRASE: R 23 [Company Data] 6.4A CROSS REFERENCE: Cas # SPECIES: RESULT: Severe eye irritation may be seen with selenium dust exposure. REFERENCE SOURCE: [Rumack BH POISINDEX(R) Information System Micromedex, Inc., Englewood, CO, 2003; CCIS Volume 118, edition expires Nov, Hall AH & Rumack BH (Eds): TOMES(R) Information System Micromedex, Inc., Englewood, CO, 2003; CCIS Volume 118, edition expires Nov, 2003.]**PEER REVIEWED** [HSDB] 6.6B CROSS REFERENCE: Cas # Sodium selenite and sodium selenate, fed by gavaging to age-matched male Swiss albino mice and observed after 24 h following a colchicinefixative-air-drying-giemsa schedule, were found to induce chromosome breaks and spindle disturbances in bone marrow cells. The four concentrations used were fractions of LD50 and the effects were directly proportionate to the concentration of the chemical. Sodium selenite induced a slightly higher frequency of chromosomal aberrations than sodium selenate. (Selenium salts and chromosome damage. Authors: Biswas S, Talukder G, Sharma A. Author Address: Department of Pathology, Vivekananda Institute of Medical Sciences, Calcutta, India. Source: Mutat Res 1997 May 23;390(3):201-5) [EMIC][MEDLINE] There remains some concern that human exposure to selenium compounds may be associated with a mutagenic risk (Committee for Veterinary Medicinal Products - Potassium and Sodium salts of Selenium - SUMMARY REPORT EMEA/MRL/249/97-Final October 1997) [EMEA] 6.9B (oral) EndPoint: Primary Organ: R PHRASE: R 33 [Company Data]
5 12. ECOLOGICAL INFORMATION Page 5 of 6 Data and interpretation: Very toxic to aquatic organisms. Harmful to the soil environment. Harmful to terrestrial vertebrates. Harmful to terrestrial invertebrates. Summary data: Sodium selenate Ecotoxicity to: 9.1A (fish) R PHRASE: R 50/53 [Company Data] Bioccumulative: ND Rapidly Degradable: ND 9.1A (crustacean) R PHRASE: R 50/53 [Company Data] Bioccumulative: ND Rapidly Degradable: ND 9.1A (algal) R PHRASE: R 50/53 [Company Data] Bioccumulative: ND Rapidly Degradable: ND 9.2A CROSS REFERENCE: Cas # Effect of Selenic acid, Disodium salt on Medicago sativa (Alfalfa) Development ENDPOINT: 22 day(s) EC20 of 3.3 mg/kg soil (NR: NR) on Measurement: Emergence; Response Site: NR Effect of Selenic acid, Disodium salt on Medicago sativa Growth Endpoint Data Only Height; Response Site: Shoot Length; Response Site: Root Number of nodules/nodulated plant roots; Response Site: NR Weight; Response Site: Whole Organism Weight; Response Site: Whole Organism Weight; Response Site: Whole Organism Effect of Selenic acid, Disodium salt on Medicago sativa (Alfalfa) Mortality ENDPOINT: 22 day(s) EC20 of 0.3 mg/kg soil (NR: NR) on Measurement: Mortality; Response Site: NR Effect of Selenic acid, Disodium salt on Medicago sativa (Alfalfa) Population Biomass; Response Site: Root Biomass; Response Site: Shoot Biomass; Response Site: Whole Organism Reference Number: Author(s): TN&Associates Inc. Publication Year: 2000 Title: Plant Toxicity Testing to Support Development of Ecological Soil Screening Levels Reference Source: Subcontract Agreement No.SC-IDIQ , National Center for Environ.Assess., Washington, D.C. :53 p. [ECOTOX] [begin: STI on 2006/05/01 at 10:18] The Agency have used the lowest of the 22 days plant data from the EPA (Environmental Protection Agency) as there was no 14 days one. The EC20 is 0.1 mg/kg based on the effect of Component F to Medicago sativa (Alfalfa). This data lead the Agency to classify the Component 9.2A [end: STI on 2006/05/01 at 10:18] Soil DT 50 > 30 days: ND 9.3A R PHRASE: R 25 [Company Data]
6 13. DISPOSAL CONSIDERATIONS Disposal information: Page 6 of 6 Preferably dispose of the product by its intended use (as a drench). If this isn t possible, dispose of product and packaging at an approved landfill or other approved hazardous waste disposal facility. Avoid contamination of any water source. Preferably recycle empty container using a suitable drench container recovery program (e.g. AgRecovery: for details visit the site If this isn t possible then burn empty container in an appropriate incinerator, providing circumstances permit; i.e. suitable wind direction. Otherwise crush or puncture and bury in a suitable landfill. Do NOT re-use container for any other purpose. 14. TRANSPORT INFORMATION Relevant information: Other requirements: Dangerous Goods for transport. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Sodium selenite 0.4%) UN Number: 2630 Dangerous Goods Class: 6.1 The maximum quantity per package of this substance allowed for carriage on public transport is 1000L. 15. REGULATORY INFORMATION Registered pursuant to the ACVM Act 1997, No. A06903 See for registration conditions Regulatory status: This product is an approved substance under the Hazardous Substances and New Organisms Act (HSNO). Approval code: HSR SDS is required for quantities greater than or equal to 0.1L
7 Page 7 of OTHER INFORMATION Abbreviations: References: Disclaimer: ACVM Agricultural Compounds and Veterinary Medicines ARTG Australian Register of Therapeutic Goods CAS Number Unique Chemical Abstracts Service Registry Number Ceiling Exposure Value: The maximum airborne concentration of a biological or chemical agent to which a worker may be exposed at any time. Controls Matrix List of default controls linking regulation numbers to Matrix code (e.g. T1, I16). EC50 Ecotoxic Concentration 50% concentration in water which is fatal to 50% of a test population (e.g. daphnia, fish species) ERMA Environmental Risk Management Authority (now EPA) EPA Environmental Protection Agency (previously known as ERMA) HAZCHEM Code Emergency action code of numbers and letters that provide information to emergency services, especially fire fighters HSNO Hazardous Substances and New Organisms (Act and Regulations) IARC International Agency for Research on Cancer LEL Lower Explosive Limit LD50 Lethal Dose 50% dose which is fatal to 50% of a test population (usually rats). LC50 Lethal Concentration 50% concentration in air which is fatal to 50% of a test population (usually rats) MSDS Material Safety Data Sheet (or Safety Data Sheet) STEL Short Term Exposure Limit - The maximum airborne concentration of a chemical or biological agent to which a worker may be exposed in any 15-minute period, provided the TWA is not exceeded TWA Time Weighted Average generally referred to WES averaged over typical work day (usually 8 hours) UEL Upper Explosive Limit UN Number United Nations Number WES Workplace Exposure Standard - The airborne Unless otherwise stated, toxicity information has been obtained from the EPA HSNO chemical classification information database (CCID) for specific chemicals. EPA Transfer Gazettes Classifications and controls assigned for specific ingredients (consolidated gazette, 2004) Controls Matrix Part of the EPA New Zealand User Guide to the HSNO Control Regulations WES 2013 The NZ Workplace Exposure Standards Effective from 2013, published by WorkSafe NZ and available on their web site Other References: Suppliers MSDSs This MSDS was prepared by Horizon AgResources Ltd., and is based on our current state of knowledge, including information obtained from suppliers. This SDS is written in good faith and constitutes a guideline (not a guarantee of safety). The level of risk each substance poses is relevant to its properties (as summarised in the MSDS) AND HOW THE SUBSTANCE IS USED. While guidelines are given for personal protective equipment, such precautions must be relevant to the use. The likely HSNO classifications, are based on experience, EPA Guidelines and international classifications. This MSDS is copyright Horizon AgResources Ltd, and must not be edited without the permission of the copyright holder or used for other than intended purpose.
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