Reaper 688SG. Agritrade 411 Blenheim Road Sockburn Christchurch CHEMCALL ( ) 24hrs HSR100959

Transcription

1 Page 1 of 7 1. Identification of the Substance/Mixture and Supplier. Product name: Other names: Recommended Use: Company details: Telephone: Facsimile: Emergency telephone: Glyphosate 688g/kg as the mono-ammonium salt in the form of a water soluble granule A concentrated granular herbicide for the control of a wide range of broadleaf weeds and grasses in agriculture, horticulture, forestry and non-cropland areas. Agritrade 411 Blenheim Road Sockburn Christchurch CHEMCALL ( ) 24hrs 2. Hazards Identification. HSNO Approval Number: Classification: Hazard and Precautionary Statements: HSR HSNO Hazard Classifications 6.1E, 6.3A, 8.3A, 9.1B Read product label and safety data sheets before use. WARNING - May be harmful if swallowed, inhaled or absorbed through the skin. Causes skin irritation. DANGER - May cause serious eye damage EXOCTOXIC Toxic to aquatic life with long lasting effects. Avoid contamination of any water supply with product or empty container PERSONAL PROTECTION: Avoid skin and eye contact. Do not breathe dust or spray mist. Do not eat, drink or smoke while using. Use only outdoors or in a well-ventilated area. Wear Page 1 of 7

2 Page 2 of 7 protective clothing such as face shield, impervious gloves, overalls and boots when handling. Wash splashes of concentrate from skin immediately. Remove protective clothing and wash hands and face thoroughly before meals and after work. Wash contaminated clothing before re-use. STORAGE: Keep out of reach of children. Store in original container tightly closed and in a locked, dry, cool area away from foodstuffs. Store in accordance with NZS 8409 Management of Agrichemicals. DISPOSAL: Crush and bury empty packaging in a suitable landfill. Dispose of product only by using according to the label, or at an approved landfill. Avoid contamination of any water supply with product or empty container. 3. Composition/Information on Ingredients. Chemical Identity of Ingredients with health or environmental hazards: Mixture: Ingredient CAS No. Content (%w/w) Glyphosate (present as the ammonium salt) % Ethoxylated tallow amine % 4. First Aid Measures. Description of necessary first aid measures: Ingestion: Eye Contact: Skin Contact: Inhalation: In case of poisoning, or if you feel unwell or are exposed or concerned, contact the NATIONAL POISONS CENTRE, Phone , (0800 POISON). Do NOT induce vomiting. Immediately call the National Poisons Centre 0800 POISON ( ) or a doctor. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call the National Poisons Centre 0800 POISON ( ) or a doctor. Remove contaminated clothing and wash affected area with plenty of soap and water. If skin irritation or rash occurs get medical advice/attention. Call the National Poisons Centre 0800 POISON ( ) or a doctor if you feel unwell. Page 2 of 7

3 Workplace facilities: Hygiene Practices: Page 3 of 7 Emergency showers and eyewashes should be available in the immediate vicinity of any potential exposure. Avoid skin and eye contact. Do not breathe dust or spray mist. Do not eat, drink or smoke while using. Use only outdoors or in a well-ventilated area. Wear protective clothing such as face shield, impervious gloves, overalls and boots when handling. Wash splashes of concentrate from skin immediately. Remove protective clothing and wash hands and face thoroughly before meals and after work. Wash contaminated clothing before reuse. 5. Fire-Fighting Measures. Decomposition: Extinguishing media: HAZCHEM code: Special Protective Equipment and Precautions for Fire Fighters Product may release oxides of carbon and nitrogen in case of fire. Fight fire with water spray, foam, CO 2, or powder. 2X In case of fire wear full chemical resistant protective clothing and a self-contained breathing apparatus. Prevent run-off water contaminating drains, sewers or watercourses (bund if necessary); inform appropriate authorities immediately if product or runoff enters waterways. IER GUIDE Accidental Release Measures. Personal Precautions: Environmental Precautions: Procedure for Clean-up: Release or Spill: Wear protective clothing (overalls buttoned at wrist and neck), chemical resistant gloves and boots, and face shield. Prevent chemical contaminating drains or watercourses by activating emergency shut-off valves or using bunding. Inform appropriate authorities immediately if spill enters waterways or sewers. Prevent chemical contaminating soil. Bund spill and absorb with inert absorbent material, such as sand or clay granules. Sweep absorbent material into a waste container and dispose of at an approved facility. Cover the area with water and absorb. Prevent runoff entering waterways or contaminating soil. Page 3 of 7

4 Page 4 of 7 7. Handling and Storage. Handling Practices: Approved Handler: Storage: Packaging: When mixing or applying wear protective clothing, gloves and face shield. Avoid contact with skin and eyes and avoid breathing dust or spray mist. Wash hands and face after work and before meals. Do not eat, drink or smoke while using. Wash protective clothing after work. Use in a well-ventilated area. This product must be under the control of an Approved Handler when applied where the substance is applied onto or into water and the water has the potential to leave the place containing the application area. Keep out of reach of children. Store in original container, tightly closed and in a locked, dry, well ventilated area away from sources seed and foodstuffs. Store only in original packaging. 8. Exposure Control/Personal Protection. Workplace Exposure Standards: Engineering controls: Hand protection: Eye protection: Skin Protection General hygiene: Components with limit values that require monitoring in the workplace: No WES or TEL values are set for any component of this substance at this time. Use in well ventilated areas to maintain air concentrations below exposure standards. Wear pvc, rubber, neoprene or nitrile gloves. Check regularly for condition when using. Wear goggles with side pieces or a face shield. Wear overalls (disposable, or clean reusable), and rubber or PVC boots. Do not eat, drink or smoke while using. Wash hands and exposed skin thoroughly with soap and water before meals and after work. Wash protective clothing daily after work. Page 4 of 7

5 Page 5 of 7 9. Physical and Chemical Properties. Appearance: Odour: ph: Vapour Pressure: Vapour Density: Boiling Point: Lower and upper flammability limits: Flashpoint: Auto ignition temperature: Melting point: Solubility: Density: Homogenous, free-flowing light yellow granule Odourless ph4-6 Not flammable Not self-igniting Not data Readily soluble in water g/mL 10. Stability and Reactivity. Stability of the Substance: Incompatible Materials: Hazardous reactions: Stable under normal conditions of storage and use. Corrosive to mild steel, galvanized steel and zinc. Spray solutions of this product should be mixed, stored or applied using only stainless steel, aluminium, fiberglass, plastic or plastic lined containers. None 11. Toxicological Information. Ingestion: Inhalation: Eye contact: Skin contact: Rat oral LD 50 >4640mg/kg. Rat inhalation LC 50 (4hr) aerosol, slightly toxic Rabbit 4 Days, slight to moderate irritation. Evident at day 1 but cleared by day 4. Rat dermal LD 50 >2150mg/kg. Rabbit skin irritation no signs of skin irritation during 14 day study period. Page 5 of 7

6 Page 6 of Ecological Information. Aquatic toxicity: EC 50/LC 50 values for Glyphosate Algae (acute): Skeletonema costatum (diatom) EC50 (96 hr) 1.2 mg/l (based on chlorophyll a decrease) Algae (chronic): Skeletonema costatum (diatom) EC50 (7 day) 0.77 ppm (= 0.77 mg/l) Fish (acute): Bluegill sunfish LC50 (96 hr) 45 ppm (= 45 mg/l) Fish (chronic): Salmo gairdnerii NOEC (21 day) 52 mg/l Avarian toxicity: Toxicity to honey bees: Mobility: Persistence/degradability: Disposal Considerations. Product Disposal: Container Disposal: Dispose of this product only by using according to the label, or at an approved landfill or other approved facility such as Agrecovery Chemical Recovery service. Crush empty packaging and bury at a suitable landfill. If allowed under local authority, burn if circumstances, especially wind direction permit. 14. Transportation Information. UN Proper shipping name: UN Number: UN Class: Packing Group: Rail/Road (ADR) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains Glyphosate 68.8%) III UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains Glyphosate 68.8%) Class 9, Packaging Group III, Hazchem Code 2X Page 6 of 7

7 Sea (IMDG-Code) Air (ICAO/IATA) Segregation: Page 7 of 7 UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains Glyphosate 68.8%) Class 9, Packaging Group III, Hazchem Code 2X Marine Pollutant. UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains Glyphosate 68.8%) Class 9, Packaging Group III, Hazchem Code 2X Must not be loaded with Class 1 (Explosives). 15. Regulatory Information. HSNO Approval Number: HSNO Controls: HSR See for controls. Workplace Exposure Standards: No WES or TEL values are set for any component of this substance at this time. Approved Handler: ACVM Registration: ACVM Conditions: This product must be under the control of an Approved Handler when applied where the substance is applied onto or into water and the water has the potential to leave the place containing the application area. P9050 See for registration conditions. 16. Other Information. 6.1E (oral) Warning May be harmful if swallowed 6.1E (dermal) Warning May be harmful in contact with skin 6.1E (inhalation) Warning May be harmful if inhaled 6.3A Warning Causes skin irritation 8.3A Danger Causes serious eye damage 9.1B Toxic to aquatic life with long lasting effects Date of preparation: 10 th November Version: 2 The data given here is based on current knowledge and experience. The purpose of this Safety Data Sheet is to describe products in terms of their safety requirements. The above details do not imply any guarantee concerning composition, properties or performance of the product. Page 7 of 7