Safety Data Sheet acc. to OSHA HCS 29CFR

Transcription

1 Page 1/10 * 1 Identification Article number: C Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Details of the supplier of the safety data sheet Manufacturer/Supplier: Kester Inc. 800 West Thorndale Avenue Itasca, IL A Tel (630) Tel International ITW Specialty Materials (Suzhou) Co., Ltd. Heng Qiao Road Wujiang Economic Development Zone Suzhou, Jiangsu China Tel Kester GmbH Ganghofer Strasse 45 D Gernlinden Germany Tel +49 (0) Information department: Product Compliance: EHS_Kester@kester.com Emergency telephone number: CHEMTREC 24-Hour Emergency Response Telephone Number : (800) CHEMTREC 24-Hour Emergency Response (Outside & Canada) Telephone Number : (703) * 2 Hazard(s) identification Classification of the substance or mixture Health hazard Carc. 2 STOT RE 2 H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. Corrosion Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. Acute Tox. 4 H302 Harmful if swallowed. Label elements GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). (Contd. on page 2)

2 Page 2/10 Hazard pictograms (Contd. of page 1) GHS05 GHS07 GHS08 Signal word Danger Hazard-determining components of labeling: diethanolamine ethanolamine Hazard statements H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapors/spray. P264 Wash thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Classification system: NFPA ratings (scale 0-4) Health = 3 Fire = 1 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH *3 FIRE 1 REACTIVITY 0 Health = *3 Fire = 1 Reactivity = 0 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. * 3 Composition/information on ingredients Description: Mixture of the substances listed below with nonhazardous additions. CAS No. Description % Range Eye Irrit. 2A, H % (Contd. on page 3)

3 Page 3/10 Aliphatic hydroxyl diol (Contd. of page 2) Carc. 2, H351; STOT RE 2, H % Skin Corr. 1B, H314; Eye Dam. 1, H318 Acute Tox. 4, H302 Acute Tox. 3, H % Skin Corr. 1B, H314; Eye Dam. 1, H318 Acute Tox. 4, H332 Flam. Liq. 4, H227 Eye Irrit. 2A, H % Flam. Liq. 4, H227 * 4 First-aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Follow general first aid procedures. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Seek immediate medical advice. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. * 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture Nitrogen oxides (NOx) In case of fire, the following can be released: Advice for firefighters Protective equipment: No special measures required. * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Contd. on page 4)

4 Page 4/10 Protective Action Criteria for Chemicals PAC-1: Aliphatic hydroxyl diol PAC-2: Aliphatic hydroxyl diol PAC-3: Aliphatic hydroxyl diol (Contd. of page 3) 30 ppm 3 mg/m3 6 ppm 30 mg/m3 33 ppm 28 mg/m3 170 ppm 330 mg/m3 200 ppm 130 mg/m3 1,000 ppm 2,000 mg/m3 * 7 Handling and storage Handling: Precautions for safe handling Store in cool, dry place in tightly closed receptacles. Prevent formation of aerosols. Information about protection against explosions and fires: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed. Specific end use(s) No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the remaining constituent has no known exposure limits. TLV Long-term value: 67.5* mg/m³, 10* ppm *Inhalable fraction and vapor REL Long-term value: 15 mg/m³, 3 ppm TLV Long-term value: 1* mg/m³, 0.2* ppm Skin; *inhalable fraction and vapor (Contd. on page 5)

5 Page 5/10 PEL Long-term value: 6 mg/m³, 3 ppm REL Short-term value: 15 mg/m³, 6 ppm Long-term value: 8 mg/m³, 3 ppm TLV Short-term value: 15 mg/m³, 6 ppm Long-term value: 7.5 mg/m³, 3 ppm Additional information: PEL = Permissible Exposure Limit (OSHA) TLV= Threshold Limit Value (ACGIH) OSHA= Occupational Safety and Health Administration ACGIH= American Conference of Governmental Industrial Hygienists (Contd. of page 4) Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Breathing equipment: When ventilation is not sufficient to remove fumes from the breathing zone, a safety approved respirator or self-contained breathing apparatus should be worn. Not necessary if room is well-ventilated. Use suitable respiratory protective device in case of insufficient ventilation. Protection of hands: Protective gloves Material of gloves: Nitrile rubber, NBR Natural rubber, NR Penetration time of glove material: The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Safety glasses * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Liquid Color: Colorless to light yellow Odor: Ammonia-like ph-value at 20 C (68 F): 11.4 (Contd. on page 6)

6 Page 6/10 Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 171 C (339.8 F) Flash point: Ignition temperature: Auto igniting: Danger of explosion: > 100 C (>212 F) 225 C (437 F) Explosion limits: Lower: 0.9Vol % Upper: 10.6Vol % Product is not selfigniting. Vapor pressure at 20 C (68 F): 0.3hPa (0.2 mm Hg) Density at 20 C (68 F): Solubility in / Miscibility with Water: Solvent content: Organic solvents: 97.1% Solids content: 0.2% Product does not present an explosion hazard. 0.99g/cm³ (8.26 lbs/gal) Not miscible or difficult to mix. (Contd. of page 5) * 10 Stability and reactivity Reactivity No further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: Strong acids, strong oxidizers. Hazardous decomposition products: Nitrogen oxides When heated to soldering temperatures, solvents will be evaporated and organic matierial may release aliphatic aldehydes and acids. * 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: Oral LD50 5,660 mg/kg (rat) Dermal LD50 4,000 mg/kg (rabbit) Oral LD50 1,600 mg/kg (rat) Dermal LD50 12,200 mg/kg (rabbit) (Contd. on page 7)

7 Page 7/10 (Contd. of page 6) Oral LD50 2,050 mg/kg (rat) Dermal LD50 1,000 mg/kg (rabbit) Inhalative LC50/4 h 11 mg/l (ATE) Primary irritant effect: on the skin: Caustic effect on skin and mucous membranes. on the eye: Irritating effect. through inhalation: May cause respiratory irritation. through ingestion: May cause gastrointestinal irritation. Sensitization: Sensitization possible through inhalation. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Corrosive Irritant Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. Carcinogenic categories IARC (International Agency for Research on Cancer) NTP (National Toxicology Program) None of the ingredients is listed. OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 2B * 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Additional ecological information: General notes: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or unneutralized. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. * 13 Disposal considerations Waste treatment methods Recommendation: Disposal must be made according to official regulations. Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. (Contd. on page 8)

8 Page 8/10 * 14 Transport information (Contd. of page 7) UN-Number DOT, ADR, IMDG, IATA UN3267 UN proper shipping name DOT Corrosive liquid, basic, organic, n.o.s. (diethanolamine) ADR 3267 Corrosive liquid, basic, organic, n.o.s. (diethanolamine) IMDG, IATA CORRO SIVE LIQUID, BASIC, O RGANIC, N.O.S. (diethanolamine) Transport hazard class(es) DOT Class 8 Corrosive substances Label 8 ADR, IMDG, IATA Class 8 Corrosive substances Label 8 Packing group DOT, IMDG, IATA II Marine pollutant: No Special precautions for user Not applicable. Danger code (Kemler): 80 EMS Number: F-A,S-B Segregation groups Alkalis Stowage Category B Stowage Code SW2 Clear of living quarters. Segregation Code SG35 Stow "separated from" acids. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: DOT Quantity limitations ADR Excepted quantities (EQ) IMDG Limited quantities (LQ) Excepted quantities (EQ) On passenger aircraft/rail: 1 L On cargo aircraft only: 30 L Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml 1L Maximum net quantity per inner packaging: 30 ml (Contd. on page 9)

9 Page 9/10 UN "Model Regulation": (Contd. of page 8) UN 3267 CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (DIETHANOLAMINE), 8, II * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture All ingredients are listed on the following Government Inventories: China: Inventory of Existing Chemical Substances in China (IECSC) Korea: Korea Existing Chemicals List (ECL) Europe: European Inventory of Existing Commercial Chemical Substances (EINECS) Japan: Inventory of Existing and New Chemical Substances (ENCS) Philippines: Philippine Inventory of Chemicals and Chemical Substances (PICCS) A: TSCA (Toxic Substances Control Act) TSCA Inventory of Chemical Substances A The following information relates to product regulation specific to the A. SARA (Superfund Amendments and Reauthorization Act) Section 355 (extremely hazardous substances): None of the ingredient is listed. Section 313 (Specific toxic chemical listings): California Proposition 65 Chemicals known to cause cancer: diethanolamine Chemicals known to cause reproductive toxicity: None of the ingredients is listed. Carcinogenic categories EPA (Environmental Protection Agency) None of the ingredients is listed. NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. CANADA: Workplace Hazardous Materials Identification (WHMIS): This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulation (CPR) and the (SDS) contains all of the information required by the CPR. GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS05 GHS07 GHS08 Signal word Danger Hazard-determining components of labeling: diethanolamine ethanolamine (Contd. on page 10)

10 Page 10/10 (Contd. of page 9) Hazard statements H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapors/spray. P264 Wash thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. * 16 Other information The information contained herein is based on data considered accurate and is offered solely for information, consideration and investigation. Kester extends no warranties, makes no representations and assumes no responsibilty as to the accuracy, completeness or suitability of this data for any purchaser's use. The data on this Material relates only to this product and does not relate to use with any other material or in any process. All chemical products should be used only by, or under the direction of, technically qualified personnel who are aware of the hazards involved and the necessity for reasonable care in handling. Hazard communication regulations require that employees must be trained on how to use a Material as a source for hazard information. Department issuing (SDS): Product Compliance / EHS Department Contact: EHS_Kester@kester.com Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organisation ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (A) HMIS: Hazardous Materials Identification System (A) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vpvb: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Flam. Liq. 4: Flammable liquids Category 4 Acute Tox. 4: Acute toxicity Category 4 Acute Tox. 3: Acute toxicity Category 3 Skin Corr. 1B: Skin corrosion/irritation Category 1B Eye Dam. 1: Serious eye damage/eye irritation Category 1 Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A Carc. 2: Carcinogenicity Category 2 Carc. 2: Carcinogenicity Category 2 STOT RE 2: Specific target organ toxicity (repeated exposure) Category 2 * Data compared to the previous version altered.