MATERIAL SAFETY DATA SHEET

Transcription

1 SECTION 1 : IDENTIFICATION Product identifier: Chemical family : Product Use: CLEANER ALL PURPOSE Mixture: All purpose cleaner Cleaner Supplier s name: LAVO Inc Address : Boul. Saint-Jean Baptiste Montréal, Québec Canada H1C 2J3 Telephone : or Emergency phone : CANUTEC (transport) SECTION 2 : HAZARD IDENTIFICATION Emergency Overview: CAUTION. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. POTENTIAL HEALTH EFFECTS: Signs and symptoms of short-term (acute) exposure Routes of exposure: Eye. Skin contact. Skin absorption. Inhalation. Ingestion Eyes : May cause irritation. Skin : May cause irritation. May be absorbed through the skin. ACGIH - Threshold Limit Values - Skin Notations Methanol Skin - potential significant contribution to overall exposure by the cutaneous route NIOSH - Pocket Guide - Skin Notations Methanol Potential for dermal absorption Inhalation: May cause respiratory tract irritation. Ingestion : May cause stomach distress, nausea or vomiting. Target organs: Eyes. Skin. Chronic Effects: Prolonged or repeated contact may cause drying, de-fatting and dermatitis. Signs and symptoms: Symptoms may include redness, oedema, drying, defatting and cracking of the skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Potential environmental Components of this product have been identified as having potential environmental concerns. effect : SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS Ingredients CAS Percent Methyl Alcohol % Ethyl Alcohol % Alkyl Poly Glycoside C8-C % SECTION 4 : FIRST AID MEASURES Eye contact : Skin contact: Inhalation : Ingestion : Notes for physician : Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention if irritation develops or persists. Flush with cool water. Obtain medical attention if irritation persists. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. Symptoms may be delayed / /076/082/083/ Page 1 / 5

2 SECTION 5 : FIRE FIGHTING MEASURES Flammability properties: Media extinguishing: Protection of firefighters: Explosion data: Hazardous combustion products: Not flammable by WHMIS criteria. Treat for surrounding material. Firefighters should wear full protective clothing including self contained breadthing. May include and are not limited to: Oxides of carbon. SECTION 6 : ACCIDENTAL RELEASE MEASURES Personal precautions: Environmental precautions: Method for containment: Prohibited materials: Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. Do not discharge into lakes, streams, ponds or public waters. Stop leak if you can do so without risk. Prevent entry into waterways, sewers, basements or confined areas. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labeled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use. SECTION 7 : HANDLING AND STORAGE Safe Handling procedures: Storage: Wear chemically resistant protective equipment during handling. Use only in well ventilated areas. Avoid contact with eyes and skin. Keep out of reach of children. Store in a closed container away from incompatible materials. SECTION 8 : EXPOSURE CONTROLS AND PERSONAL PROTECTION Exposure Limits ACGIH TLV Ingredients CAS TWA STEL Methyl Alcohol ppm 250 ppm Ethyl Alcohol ppm 1000 ppm Alkyl Poly Glycoside C8-C Not established Not established Engineering measures : Eye/Face protection : Hand protection: Skin and body protection : Respiratory protection : General hygiene considerations : General ventilation normally adequate. Safety glasses if eye contact is possible. Rubber gloves. Confirm with a reputable supplier first. As required by employer code. Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Avoid contact with eyes and skin. Wash hands before eating, drinking, smoking or use of toilet facilities. SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES Physical state Liquid Appearance Clear colored liquid. Odor Characteristic Odor threshold N/Av ph Density Boiling Point N/Av Coefficient of water/oil distribution N/Av Melting/Freezing Point N/Av Solubility in water Completely miscible Vapor Pressure N/Av Evaporation rate (n-butylic acetate=1) N/Av / /076/082/083/ Page 2 / 5

3 SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES (SUITE) Volatile organic Compounds N/Av Absolute pressure of container N/Av Flash Point N/Av Viscosity N/Av Flash Point, method N/Av Auto-ignition temperature N/Av Lower flammable limit (%vol) N/Av Upper flammable limit (%vol) N/Av Volatiles (% by weight) N/Av Flashback observed N/Av SECTION 10 : STABILITY AND REACTIVITY Stability/Reactivity: Hazardous polymerization : Conditions to avoid Incompatible materials: Hazardous decomposition products : Stable under recommended storage condition. This product may react with strong acids. Hazardous polymerization does not occur. Do not mix with other chemicals. Acids. May include and are not limited to: Oxides of carbon. SECTION 11 : TOXICOLOGICAL INFORMATION Toxicological data: There is no available data for the product itself, only for the ingredients. See below for individual ingredient acute toxicity data. Ingredients CAS CL50(4hr) inh, rat LD50 (Oral, rat) Methyl Alcohol mg/kg rat ; 7300 mg/kg mouse ; mg/kg rabbit ; 7600 mg/kg monkey Ethyl Alcohol ppm 3450 mg/kg mouse ; 7060 mg/kg rat Alkyl Poly Glycoside C8-C mg/kg Effects of acute exposure Eye: Skin: Inhalation: Ingestion: Sensitization: May cause irritation. May cause irritation. May be absorbed through the skin. ACGIH Threshold limit values Skin notations Methyl Alcohol Skin Potential significant contribution to overall exposure by the cutaneous route. NIOSH Pocket Guide Skin Notations Methyl Alcohol Potential for dermal absorption. Chronic effects: Carcinogenic Status: Mutagenicity : May cause respiratory tract irritation. May cause stomach distress, nausea or vomiting. ACGIH Threshold limit value - Carcinogens Ethyl Alcohol A3 Confirmed animal carcinogen with unknown relevance to humans. IARC Group1 (carcinogenic to Humans) Ethyl Alcohol Monograph 100E (in preparation) (in alcoholic beverage); Monograph 96 (2010) (in alcoholic beverages) Reproductive effects : Teratogenicity : Synergistic materials: Methanol has produced teratogenic effects in mice exposed by inhalation to high concentrations that did not produce significant material toxicity / /076/082/083/ Page 3 / 5

4 SECTION 12 : ECOLOGICAL INFORMATION Eco toxicity : No data is available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. Ingredient: CAS Ecotoxicity Freshwater Fish Acurate Toxicity Data Methanol h LC50 (Pimephales promelas):28200mg/l flow through 96h LC50 (Pimephales promelas):>100mg/l static 96h LC50 (Oncohynchus mykiss): mg/l flow through 96h LC50 (Oncohynchus mykiss):18 20mL/L static 96h LC50 (Leponis macrochirus): mg/l flow through Ethanol h LC50 (Oncohynchus mykiss): mL/L static 96h LC50 (Pimephales promelas): >100mg/L static 96h LC50 (Pimephales promelas): mg/l flow through Ingredient: CAS Ecotoxicity Water Fleah Acurate Toxicity Data Ethanol h LC50 Daphnia magna: mg/l 24h EC50 Daphnia magna: 10800mg/L 48h EC50 Daphnia magna: 2mg/L static Persistence and degradability : Aquatic toxicity: Bioaccumulation Potential: Partition coefficient: Mobility in environmental media: Chemical fate information: Environmental effects : Other adverse effects: SECTION 13 : DISPOSAL CONSIDERATIONS Disposal instruction: Waste for residues / Unused products: Contaminated packaging: Dispose in accordance with all applicable regulations. SECTION 14 : TRANSPORT INFORMATION Transportation of Dangerous Goods (TDG - Canada): Not regulated as dangerous goods. SECTION 15 : REGULATORY INFORMATION Canadian federal regulations : This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS classification Class D - Division 2A (materials Causing Other Toxic Effects, Very Toxic material) Class D - Division 2B. (materials Causing Other Toxic Effects, Toxic material) WHMIS status Controlled Canada SIMDUT- Ingredient disclosure list WHMIS labeling: Methanol % Ethanol % Canadian inventory status: All components of this product are either on the Domestic Substances List (DSL), the Non Domestic Substances list (NDSL) or exempt / /076/082/083/ Page 4 / 5

5 SECTION 16 : OTHER INFORMATION HMIS LEGEND 0- Minimal 1-Slight 2-Moderate 3-Serious Health: 1 Flammability : 0 Reactivity : 0 Disclaimer of liability: The information in the Material Safety Data Sheet is offered for your consideration and guidance when exposed to this product. Lavo Inc. expressly disclaims all expressed or implied warranties for the accuracy or completeness of the data contained herein and assumes no responsibilities for any involved damages by above data. Product s users have to do their own tests to establish the applicability of the information for a specific use of the product. MSDS data does not apply to use with any other product or in any other process. Other information: For an update MSDS, Please contact the supplier/manufacturer listed on the first page of the document. Reference: MSDS of suppliers. SIMDUT regulation Prepared by : Lavo Inc Boul. Saint-Jean Baptiste Montréal, QC, Canada H1C 2J3 Telephone : Issuing date: 15- March-2013 Due date: March / /076/082/083/ Page 5 / 5