MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET Product name CAS # Product Use Manufacturer. Product and Company Identification Sifto Safe Step Xtreme, Sifto Xtreme Performance, Sifto Professional Mixture De-icer. CANUTEC Emergency overview Potential short term health effects Routes of exposure Eyes Skin Target organs Chronic effects Signs and symptoms Potential environmental effects See section 2. Sifto Canada Inc. A Compass Minerals Company 99 West 9th Street, Suite Overland Park, KS 662 US Phone: Hazards Identification CAUTION CAUSES EYE IRRITATION. Exposure to powder or dusts may be irritating to eyes, nose and throat. Eye, Skin contact,,. Causes irritation. Dust in the eyes will cause irritation. May cause irritation. Dust or powder may irritate the skin. Dusts of this product may cause irritation of the nose, throat, and respiratory tract. Dust may irritate respiratory system. May cause stomach distress, nausea or vomiting. May cause irritation. Eyes. Skin. Respiratory system. Prolonged or repeated exposure can cause drying, defatting and dermatitis. Symptoms may include redness, oedema, drying, defatting and cracking of the skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. 3. Composition/Information on Ingredients Components CAS # Percent Calcium chloride Composition comments The criteria for listing components in this section are: Carcinogens, Respiratory Sensitizers, Mutagens, Teratogens and Reproductive toxins are listed when present at.% or greater; components which are otherwise hazardous according to WHMIS are listed when present at.% or greater. Non hazardous components are not listed. The deicing pertaining to this MSDS have various proportions of components which do not meet the listing criteria. 4. First Aid Measures First aid procedures Eye contact Skin contact Notes to physician General advice Imtely flush with cool water. Remove contact lenses, if applicable, and continue flushing for 5 minutes. Obtain medical attention if irritation develops or persists. Brush away excess of dry material. Flush with water. Obtain medical attention if irritation persists. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. Treat patient symptomatically. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes. Wear safety glasses. Keep out of reach of children. #226 Page: of 5 Issue date 9-January-24

2 5. Fire Fighting Measures Flammable properties Extinguishing Suitable extinguishing Unsuitable extinguishing Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Not flammable by WHMIS criteria. Treat for surrounding material. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Hydrogen chloride. Oxides of sodium. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Avoid contact with eyes. Do not contaminate water. Prevent entry into waterways, sewers, basements or confined areas. Before attempting clean up, refer to hazard data given above. Use broom or dry vacuum to collect material for proper disposal without raising dust. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. 7. Handling and Storage Handling Storage Use good industrial hygiene practices in handling this material. Avoid contact with eyes. Avoid breathing dusts from this material. Keep out of reach of children. Keep containers tightly closed in a cool, well-ventilated place. 8. Exposure Controls/Personal Protection Exposure limits Engineering controls This material does not have established exposure limits. TWA PEL: No specific limits have been established for sodium chloride, potassium chloride or calcium chloride (soluble substances). As a guideline, OSHA (United States) has established the following limits which are generally recognized for inert or nuisance dust. Particulates Not Otherwise Regulated (PNOR): 5mg/cu.m. Respirable Dust 8-Hour TWA PEL, 5mg/cu.m. Total Dust 8-Hour TWA PEL. Personal protective equipment Eye/Face protection Hand protection TWA TLV: No specific limits have been established for sodium chloride, potassium chloride or calcium chloride (soluble substances). As a guideline, ACGIH (United States) has established the following limits which are generally recognized for inert or nuisance dust. Particulates (insolubles) Not Otherwise Classified (PNOC): mg/cu.m. Inhalable Particulate 8-Hours TWA TLV, 3mg/cu.m. Respirable Particulate TWA TLV. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. If user operations generate dust, fumes, or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Safety glasses Rubber gloves. Confirm with a reputable supplier first. Skin and body protection As required by employer code. Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. #226 Page: 2 of 5 Issue date 9-January-24

3 General hygiene considerations Handle in accordance with good industrial hygiene and safety practices. When using do not eat or drink. Wash hands before breaks and imtely after handling the product. 9. Physical and Chemical Properties Appearance Colour Form Odour Odour threshold Physical state ph Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability Limits in Air, Upper, % by Volume Flammability Limits in Air, Lower, % by Volume Heat of combustion Vapour pressure Vapour density Specific gravity Partition coefficient (n-octanol/water) Solubility (Water) Relative density Viscosity VOC Percent volatile Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition Crystalline. Blue / White Crystals Odourless Solid. Partially soluble. Stability and Reactivity None known. Hazardous polymerisation does not occur. Stable under recommended storage conditions. Do not mix with other chemicals. Acids. Oxidizers. May include and are not limited to: Hydrogen chloride. Sodium oxides.. Toxicological Information Toxicological data Components Calcium chloride (CAS ) Acute Dermal LD5 Oral LD5 Rat Mouse 263 mg/kg 94 mg/kg #226 Page: 3 of 5 Issue date 9-January-24

4 Components Rat mg/kg Effects of acute exposure Eye contact Skin contact Sensitisation Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products Causes irritation. Dust in the eyes will cause irritation. May cause irritation. Dust or powder may irritate the skin. Dusts of this product may cause irritation of the nose, throat, and respiratory tract. Dust may irritate respiratory system. May cause stomach distress, nausea or vomiting. May cause irritation. Not classified or listed by IARC, NTP, OSHA and ACGIH. 2. Ecological Information Ecotoxicity Ecotoxicological data Components Calcium chloride (CAS ) Crustacea Aquatic Fish May be harmful to freshwater aquatic species and to plants that are not saline tolerant. EC5 LC5 Persistence and degradability Bioaccumulation/accumulation Mobility in environmental Environmental effects Aquatic toxicity Partition coefficient Chemical fate information Daphnia Fathead minnow (Pimephales promelas) 3. Disposal Considerations 52 mg/l, 48 Hours mg/l, 96 hours Disposal instructions Waste from residues / unused Contaminated packaging Waste must be disposed of in accordance with federal, state/provincial and local environmental control regulations. 4. Transport Information Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods. Canadian federal regulations 5. Regulatory Information This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Canada Priority Substances List (Second List): Listed substance Calcium chloride (CAS ) Listed. #226 Page: 4 of 5 Issue date 9-January-24

5 WHMIS status WHMIS Classification WHMIS labeling Controlled Class D - Division 2B Inventory status Country(s) or region Inventory Name On Inventory (Yes/No)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 6. Other Information Severe Serious Moderate Slight Minimal LEGEND HEALTH FLAMMABILITY PHYSICAL HAZARD PERSONAL PROTECTION / X Disclaimer Issue date Effective date Expiry Date Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. 9-January-24 -January-24 -January-27 Prepared by Dell Tech Laboratories Ltd. Phone: (59) Other information This MSDS conforms to the ANSI Z4./Z29.-2 Standard. #226 Page: 5 of 5 Issue date 9-January-24