EMERGENCY PHONE: or (651) (24 hours)

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1 Material Safety Data Sheet Copyright, 2008, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) Scotch-Weld(TM) Rubber and Gasket Adhesive 4799 MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes Division ADDRESS: 3M Center St. Paul, MN EMERGENCY PHONE: or (651) (24 hours) Issue Date: 01/28/2008 Supercedes Date: 05/17/2005 Document Group: Product Use: Specific Use: Intended Use: Adhesive for rubber to metal. Industrial use SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt Naphtha (Petroleum), solvent-refined light n-hexane Talc Toluene Hydrocarbon Resin Polyisoprene Styrene-Butadiene Polymer Magnesium Resinate Cyclohexane Zinc Resinate Ethyl Alcohol Zinc Oxide Carbon Black SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: black, mild odor Page 1 of 10

2 General Physical Form: Liquid Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. May be absorbed through skin and cause target organ effects. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of the hands and feet, tremors and muscle atrophy. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Page 2 of 10

3 Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. NOTE: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. Ingredient C.A.S. No. Class Description Regulation Carbon Black Group 2B International Agency for Research on Cancer Ethyl Alcohol Group 1 International Agency for Research on Cancer SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL No Data Available -14 ºF [Test Method: Closed Cup] 1 % volume 7 % volume 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely Page 3 of 10

4 flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line ( ) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only nonsparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Ground containers securely when transferring contents. Wear low static or properly grounded shoes. Avoid breathing of vapors, mists or spray. Avoid static discharge. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Vapors may ignite explosively. May cause flash fire. Prevent build-up of vapors - open all windows and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross-ventilation. Without adequate ventilation, vapors may settle in low-lying areas. Keep away from heat, sparks, and open flame. Do not smoke or ignite matches, lighters, etc. Avoid contact with oxidizing agents. 7.2 STORAGE Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container tightly closed. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Provide appropriate local exhaust ventilation on open containers. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) Eye/Face Protection Avoid eye contact with vapors, mists, or spray. Page 4 of 10

5 The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Polyvinyl Alcohol (PVA) Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M Respiratory Selection Guide for additional information or call for 3M technical assistance Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information Carbon Black ACGIH TWA 3.5 mg/m3 Table A4 Carbon Black CMRG TWA 0.5 mg/m3 Carbon Black OSHA TWA 3.5 mg/m3 Table Z-1 Cyclohexane ACGIH TWA 100 ppm Cyclohexane OSHA TWA 300 ppm Table Z-1 Ethyl Alcohol ACGIH TWA 1000 ppm Table A4 Ethyl Alcohol OSHA TWA 1000 ppm Table Z-1 n-hexane ACGIH TWA 50 ppm Skin Notation* n-hexane OSHA TWA, Vacated 50 ppm Table Z-1A n-hexane OSHA TWA 500 ppm Table Z-1A Talc ACGIH TWA, respirable 2 mg/m3 Table A4 Talc CMRG TWA, as respirable 0.5 mg/m3 dust Talc OSHA TWA, respirable 2 mg/m3 Table Z-1A Toluene ACGIH TWA 20 ppm Table A4 Toluene CMRG STEL 75 ppm Skin Notation* Toluene OSHA TWA, Vacated 100 ppm Toluene OSHA STEL, Vacated 150 ppm Toluene OSHA TWA 200 ppm Table Z-2 Toluene OSHA CEIL 300 ppm Table Z-2 Zinc Oxide ACGIH TWA, respirable 2 mg/m3 Zinc Oxide ACGIH STEL 10 mg/m3 Zinc Oxide OSHA TWA, as fume 5 mg/m3 Table Z-1 Zinc Oxide OSHA TWA, respirable 5 mg/m3 Table Z-1 Zinc Oxide OSHA STEL, Vacated, as 10 mg/m3 fume Zinc Oxide OSHA TWA, Vacated, as 10 mg/m3 dust Zinc Oxide OSHA TWA, as total dust 15 mg/m3 Table Z-1 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency. SOURCE OF EXPOSURE LIMIT DATA: Page 5 of 10

6 ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: black, mild odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point -14 ºF [Test Method: Closed Cup] Flammable Limits - LEL 1 % volume Flammable Limits - UEL 7 % volume Boiling point 140 ºF Density 0.82 g/ml Vapor Density 3 [Ref Std: AIR=1] Vapor Pressure 120 mmhg [Details: 68F] Specific Gravity ph Melting point 0.82 [Ref Std: WATER=1] No Data Available No Data Available Solubility in Water Slight (less than 10%) Evaporation rate 2.50 [Ref Std: ETHER=1] Hazardous Air Pollutants Approximately 22 % weight [Test Method: Calculated] Volatile Organic Compounds 587 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile Approximately 65 % weight VOC Less H2O & Exempt Solvents 587 g/l [Test Method: calculated SCAQMD rule 443.1] Viscosity centipoise SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Aldehydes Hydrocarbons Carbon monoxide Carbon dioxide Ketones Oxides of Zinc Condition Page 6 of 10

7 SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): , , , , , , , , XS Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Page 7 of 10

8 Ingredient C.A.S. No % by Wt Toluene Zinc Resinate (ZINC COMPOUNDS) n-hexane Cyclohexane Zinc Oxide (ZINC COMPOUNDS) This material contains a chemical which requires export notification under TSCA Section 12[b]: Ingredient (Category if applicable) C.A.S. No Regulation Status Cyclohexane Toxic Substances Control Act (TSCA) 4 Test Applicable Rule Chemicals STATE REGULATIONS Contact 3M for more information. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No. Classification Carbon Black **Carcinogen Toluene *Developmental Toxin * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm. ** WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR SECTION 16: OTHER INFORMATION NFPA Hazard Classification Page 8 of 10

9 Health: 2 Flammability: 3 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product name was modified. Section 1: Product use information was modified. Section 1: Division name was modified. Copyright was modified. Section 3: Potential effects from eye contact was modified. Section 3: Potential effects from inhalation information was modified. Section 7: Handling information was modified. Section 8: Engineering controls information was modified. Section 8: Prevention of swallowing information was modified. Section 3: Other health effects information was modified. Page Heading: Product name was modified. Section 9: Property description for optional properties was modified. Section 9: Specific gravity information was modified. Section 9: Density information was added. Section 14: ID Number Heading Template 1 was added. Section 14: ID Number(s) Template 1 was added. Section 2: Ingredient table was added. Section 15: TSCA section 12[b] text was added. Section 15: EPCRA 313 information was added. Section 15: EPCRA 313 text was added. Section 8: Exposure guidelines ingredient information was added. Section 8: Exposure guidelines legend was added. Section 8: Exposure guideline note was added. Section 15: TSCA section 12[b] information was added. Section 8: Exposure guidelines data source legend was added. Section 3: Carcinogenicity table was added. Section 3: Carcinogenicity heading was added. Section 15: California proposition 65 ingredient information was added. Section 15: California proposition 65 heading was added. Section 15: California proposition 65 cancer warning was added. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at Page 9 of 10

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EMERGENCY PHONE: or (651) (24 hours)

EMERGENCY PHONE: or (651) (24 hours) Material Safety Data Sheet Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1)