GRAS Flavoring Substances
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1 GRAS Flavoring Substances GRAS Flavoring Substances. This list of substances will appear in the 28 th publication authored by the Expert Panel of the Flavor and Extract Manufacturers Association on recent progress in the consideration of flavoring ingredients generally recognized as safe (GRAS) under conditions of their intended use in food flavorings in accordance with the 1958 Food Additives Amendment to the Federal Food, Drug and Cosmetic Act. For more information on FEMA GRAS see About the FEMA GRAS Program on the FEMA website. FEMA EXPERT PANEL Samuel M. Cohen, Ph.D, M.D., Chair of the FEMA Expert Panel, Professor, Dept. of Pathology and Microbiology, and Havlik-Wall Professor of Oncology, University of Nebraska Medical Center, Omaha, NE; Shoji Fukushima, M.D., Director, Japan Bioassay Research Center, Japan Industrial Safety and Health Association, Kanagawa, Japan; Nigel J. Gooderham, Ph.D., Professor of Molecular Toxicology and Senior College Consul, Dept. of Surgery and Cancer, Imperial College London, England; F. Peter Guengerich, Ph.D., Tadashi Inagami Professor of Biochemistry, Department of Biochemistry, Vanderbilt University School of Medicine, Nashville, TN; Stephen S. Hecht, Ph.D., Wallin Professor of Cancer Prevention, Masonic Cancer Center and Dept. of Laboratory Medicine and Pathology, University of Minnesota, Minneapolis, MN; Ivonne M.C.M. Rietjens, Ph.D., Vice-Chair FEMA Expert Panel, Professor of Toxicology and Chair, Dept. of Toxicology, Wageningen; and Robert L. Smith, Emeritus Professor and Senior Research Fellow in Molecular Toxicology, Dept. of Surgery and Cancer, Imperial College London, London. DISCLAIMER: Interim GRAS 28 and the use categories, use levels and designated technical effect for FEMA GRAS flavor ingredients represent the conditions of intended use that serve as some of the bases for FEMA GRAS status. The use categories are limitations on GRAS status if a use category is not listed then the substance is not GRAS for that use. Use levels are not limits but significant deviations from these conditions of intended use may result in a substance no longer qualifying as GRAS. The designated technical effect is an important component of the conditions of intended use FEMA GRAS status provides regulatory authority to use the substance only for the designated technical effect. Some substances that are FEMA GRAS may have either a separate listing by FDA in the Code of Federal Regulations as an approved food additive or as a GRAS substance, and such listings may specify use consistent with good manufacturing practice or FDA-mandated use limitations. FEMA makes no warranty, express or implied, for the accuracy of this information. Information provided in this compilation should not be the only resource employed for any business purpose or for determining regulatory compliance such as whether specific flavor ingredients qualify as GRAS or are permitted for use in a specific jurisdiction. Users of this compilation and the information in it are solely responsible for compliance with all regulatory requirements in all jurisdictions, and agree that the use of this compilation is at the user s sole risk and that FEMA shall have no liability to any person, corporation or other entity for any loss or damage arising out of the use of this compilation. The use categories and use levels contained herein are subject to change. It is the responsibility of the user to ensure the information is up to date.
2 STATEMENT REGARDING GENERALLY RECOGNIZED AS SAFE STATUS OF EUGENYL METHYL ETHER (METHYL EUGENOL) The FEMA GRAS status of methyl eugenol (CAS NO ; FEMA No. 2475) under its conditions of intended use as a flavor ingredient, was reviewed by the FEMA Expert Panel. After reviewing the available information relevant to the FEMA GRAS status of methyl eugenol, including recent studies, the Expert Panel concluded that additional data are required to support the continuation of its GRAS status. Such data should clarify the relevance to humans of DNA adducts formed by methyl eugenol. Until such data are available for review by the Expert Panel, the flavor ingredient methyl eugenol has been removed from the FEMA GRAS list. The Expert Panel also considered the FEMA GRAS status of herbs, spices, and essential oils that contain naturally-occurring methyl eugenol, including basil, pimento, allspice, etc. and their extractives. The Panel concluded that these flavorings continue to meet the criteria for FEMA GRAS under their conditions of intended use as flavorings.
3 Table 1. Primary names (in boldface) Synonyms (in lightface) FEMA No. Primary Names and Synonyms 4819 Erythritol (2R,3S ) rel 1,2,3,4 Butanetetrol (2R,3S ) Butane 1,2,3,4 tetrol meso Erythritol Mesoerythritol 4820 Purified Damar Gum ,6 Dipropyl 5,6 dihydro 2H thiopyran 3 carboxaldehyde (5 Isopropyl 2 methyl tetrahydrothiophen 2 yl) ethyl acetate Tetrahydro 2 methyl 5 (1 methylethyl) 2 thiopheneethanol acetate 4825 E 6 Nonenal trans 6 Nonenal Pyrrolidone (3 Benzyloxypropyl)pyridine 4838 Valencene 80 Extract 4839 Mixture of 3 and 4 butyl 2 thiophenecarboxyaldehyde Interim FEMA GRAS List August 2016
4 Table 2. Average Usual Use Levels (ppm)/average Maximum Use Levels (ppm) on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS) Erythritol Purified Damar Gum 2,6-Dipropyl-5,6-dihydro- 2H-thiopyran-3- carboxaldehyde 2-(5Isopropyl-2methyltetrahydrothiophen-2- yl)- ethy acetate Category/FEMA No Baked Goods 0/0 0/0 0/0 0.3/ /0.01 Beverages, Non-Alcoholic 5000/ / /5 0.1/ / Beverages,Alcoholic 0/0 100/ /10 0.3/ / Breakfast Cereals 0/0 0/0 0/0 0.3/ /0.01 Cheeses 0/0 0/0 0/0 0/ /0.01 Chewing Gum 0/0 0/0 10/100 1/ /0.001 Condiments and Relishes 0/0 0/0 0/0 0/0 0/0 Confections and Frostings 0/0 0/0 0.3/30 0.5/ /0.001 Egg Products 0/0 0/0 0/0 0/ /0.001 Fats and Oils 0/0 0/0 0/0 0.3/1 0.01/0.1 Fish Products 0/0 0/0 0/0 0/ /0.001 Frozen Dairy 0/0 0/0 0.5/50 0.1/ /0.001 Fruit Ices 5000/ /0 0.05/5 0.1/ /0.001 Gelatins and Puddings 0/0 0/0 0.2/10 0.1/ /0.001 Granulated Sugar 0/0 0/0 0/0 0/0 0/0 Gravies 0/0 0/0 0/0 0/ /0.01 Hard Candy 0/0 0/0 0.5/50 0.5/ /0.01 Imitation Dairy 0/0 0/0 0.05/5 0/ /0.01 Instant Coffee and Tea 5000/ /0 0.05/5 0.2/ / Jams and Jellies 0/0 0/0 0.5/20 0.3/1 0/0 Meat Products 0/0 0/0 0/0 0/ /0.001 Milk Products 0/0 0/0 0.05/5 0.1/ / Nut Products 0/0 0/0 0/0 0/ /0.001 Other Grains 0/0 0/0 0/0 0/ /0.001 Poultry 0/0 0/0 0/0 0/0 0/0 Processed Fruits 5000/ /0 0.05/5 0.1/0.5 0/0 Processed Vegetables 0/0 0/0 0/0 0/0 0/0 Reconstituted Vegetables 0/0 0/0 0/0 0/0 0/0 Seasonings and Flavors 0/0 0/0 0.5/20 0.1/ /1.0 Snack Foods 0/0 0/0 0/0 0.1/ /0.001 Soft Candy 0/0 0/0 0.2/5 0.5/ /0.001 Soups 0/0 0/0 0/0 0/ /0.001 Sugar Substitutes 0/0 0/0 0/0 0/0 0/0 Sweet Sauces 0/0 0/0 0.2/10 0/0 0/0 E -6-Nonenal
5 Table 2. Average Usual Use Levels (ppm)/average Maximum Use Levels (ppm) on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS) 2-Pyrrolidone 2-(3-Benzyloxypropyl) pyridine Valencene 80 Extract Mixture of 3- and 4-butyl-2- thiophenecarboxyaldehyde /20 1/10 0.9/0.9 0/0 5/20 0.1/1 0.6/ /5 5/20 0/0 0.9/ /10 5/20 0/0 0.9/0.9 0/0 5/20 1/10 0/0 0/0 50/200 0/0 20/1000 1/20 10/40 0/0 0.9/ /10 5/20 0.2/2 0/0 0/0 5/20 0/0 0/0 0.5/10 5/20 0.1/1 0.9/ /5 5/20 0/0 0/0 0.2/5 5/20 0/0 0.9/0.9 0/0 40/160 0/0 0/0 0/0 5/20 1/10 0/0 0/0 10/40 0/0 0/0 0.6/10 5/20 0/0 0/0 0.3/5 10/40 0/0 0/0 0.5/10 5/20 0.2/2 0.9/0.9 0/0 5/20 0.1/1 0/0 0/0 5/20 0/0 0/0 0.2/5 5/20 0.1/1 0/0 0/0 5/20 0.1/1 0/0 0/0 5/20 1/10 0/0 0.5/10 5/20 1/10 0/0 0/0 10/40 0/0 0/0 0.6/10 10/40 0/0 0/0 0/0
6 Table 3. Updated Average Usual Use Levels (ppm)/average Maximum Use Levels (ppm) for flavoring substances previously recognized as FEMA GRAS. Superscript * represents a new use level. Thaumatin Neohesperidine dihydrochalcone Thaumatin B- Recombinant N-(2-Methylcyclohexyl)- 2,3,4,5,6- pentafluorobenzamide Category/FEMA No Baked Goods 7*/7* 5/7* 1/1 1*/5* 150*/500* Beverages, Non Alcoholic 7*/7* 5/15 5/7* 1/5 125/175* Beverages, Alcoholic 7*/7* 5/15 5/7* 0/0 125/175* Breakfast Cereals 7*/7* 8/20 1/2 0/0 200*/500* Cheeses 7*/7* 3/4 7*/7* 0/0 100/133* Chewing Gum 150*/150* 200/ /150* 10/20 500*/1500* Condiments and Relishes 7*/7* 2/3 1/2 0/0 125/200* Confections and Frostings 7*/7* 3/3 2/5 1/5 50/100 Egg Products 7/7* 2/3 2/5 0/0 0/0 Fats and Oils 7*/7* 4/4 0/0 0/0 125/189* Fish Products 7*/7* 2/3 5/7* 0/0 0/0 Frozen Dairy 7/7* 2/8 1/2 1/5 125/133* Fruit Ices 7/7* 2/3 2/5 1/5 125/133* Gelatins and Puddings 7*/7* 3/8 1/2 1/5 125/133* Granulated Sugar 0/0 0/0 0/0 0/0 0/0 Gravies 7*/7* 3/4 2/5 0/0 125/133* Hard Candy 7*/7* 5/15 2/5 1/5 100/133* Imitation Dairy 7*/7* 3/10 7*/7* 0/0 125/250* Instant Coffee and Tea 7*/7* 3/6 2/5 1/5 125/175* Jams and Jellies 7*/7* 2/3 2/5 1*/5* 125*/200* Meat Products 7*/7* 2/3 2/2 0/0 0/0 Milk Products 7*/7* 3/10 3/6 1/5 133*/225* Nut Products 7*/7* 3/4 5/7* 0/0 133*/175* Other Grains 7*/7* 3/4 0/0 0/0 100/133* Poultry 7*/7* 2/3 2/5 0/0 0/0 Processed Fruits 7*/7* 2/3 2/5 1/5 133*/200* Processed Vegetables 7*/7* 2/3 2/5 0/0 100/133* Reconstituted Vegetables 7*/7* 2/3 2/5 0/0 133*/133* Seasonings and Flavors 7/7* 3/4 0.5/1 0/0 133*/175* Snack Foods 7*/7* 3/3 1/2 0/0 133*/133* Soft Candy 7*/7* 4/10 2/5 1/5 100/133* Soups 7*/7* 5/7* 2/5 0/0 133*/133* Sugar Substitutes 0/0 0*/0* 0*/0* 0/0 0*/0* Sweet Sauces 7*/7* 2/3 2/5 1/5 133*/133* Glucosyl steviol glycosides
7 Table 4. Identity for Natural Flavor Complexes as Evaluated by the FEMA Expert Panel FEM The Identification value as reviewed by the FEMA Expert FEMA Primary Name A No. Panel 4728 Glucosyl steviol glycosides Total steviol glycosides 80-90% inclusive of supraglucosylated steviol glycosides 75-80%; Rebaudioside A 1-6%; stevioside 2-4% and other individual steviol glycosides not further glucosylated each less than 3%. Maltodextrin 3-20% 4820 Purified Damar Gum Oxygenated triterpenes and sequiterpenes 34-39% typically measured as isomers of hydroxydammarenone, dammerene diol, oleanonic aldehyde and urosonic aldehyde and acid and polycadenene 14-17%.
GRAS Flavoring Substances
GRAS Flavoring Substances 28 28. GRAS Flavoring Substances. This list of substances will appear in the 28 th publication authored by the Expert Panel of the Flavor and Extract Manufacturers Association
GRAS Flavoring Substances
GRAS Flavoring Substances 29 29. GRAS Flavoring Substances. This list of substances will appear in the 29 th publication authored by the Expert Panel of the Flavor and Extract Manufacturers Association
GRAS Flavoring Substances
GRAS Flavoring Substances 29 29. GRAS Flavoring Substances. This list of substances will appear in the 29 th publication authored by the Expert Panel of the Flavor and Extract Manufacturers Association
GRAS Flavoring Substances
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GRAS Flavoring Substances
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