Revision Number: Issue date: 03/13/ PRODUCT AND COMPANY IDENTIFICATION. IDH number: HAZARDS IDENTIFICATION

Transcription

1 Safety Data Sheet Revision Number: Issue date: 03/13/ PRODUCT AND COMPANY IDENTIFICATION Product name: BONDERITE S-MA 2474 MASKANT known as P3 PEELABLE MASKING IDH number: Product type: Strippable protective paint coating Restriction of Use: identified Region: Canada Company address: Henkel Canada Corporation Meadowpine Boulevard 2515 Mississauga, Ontario L5N 6C3 Contact information: Telephone: +1 (905) MEDICAL EMERGENCY Phone: Poison Control Center (toll free) or TRANSPORT EMERGENCY Phone: CHEMTREC (toll free) or Internet: 2. HAZARDS IDENTIFICATION DANGER: EMERGENCY OVERVIEW CAUSES SERIOUS EYE IRRITATION. MAY CAUSE CANCER. EYE IRRITATION CARCINOGENICITY HAZARD CLASS PICTOGRAM(S) HAZARD CATEGORY 2A 1A Precautionary Statements Prevention: Response: Storage: Disposal: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wash affected area thoroughly after handling. Wear protective gloves, clothing, eye and face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical attention. If eye irritation persists: Get medical attention. Store locked up. Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. 1 % of the mixture consists of ingredient(s) of unknown acute toxicity. Classification complies with Canadian Hazardous Products Regulations (WHMIS 2015) and is consistent with the provision of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Page 1 of 6

2 Hazardous Component(s) CAS Number Weight %* Limestone Trimethyl pentanediol mono-isobutyrate Titanium dioxide Potassium salt of a phosphated coester of alcohol and aliphatic ethoxylate Quartz (SiO2) * Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: If mist or vapor of this product is inhaled, remove person immediately to fresh air. Seek medical attention if symptoms develop or persist. Immediately flush skin with plenty of water (using soap, if available). If symptoms develop and persist, get medical attention. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Immediate medical treatment necessary. DO NOT induce vomiting unless directed to do so by medical personnel. Symptoms: See Section 11. Notes to physician: Treat symptomatically and supportively. 5. FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Use media appropriate for surrounding material. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. This product is an aqueous mixture which will not burn. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Prevent further leakage or spillage if safe to do so. Wear appropriate protective equipment and clothing during clean-up. Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations. Page 2 of 6

3 7. HANDLING AND STORAGE Handling: Storage: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Avoid breathing vapors or mists of this product. Provide adequate ventilation. Do not take internally. For industrial use only. For safe storage, store at or above 40 F (4.4 C) Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Do not freeze. Thaw and mix thoroughly if frozen. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Limestone 10 mg/m3 TWA 5 mg/m3 PEL 15 mg/m3 PEL Trimethyl pentanediol mono-isobutyrate Titanium dioxide 10 mg/m3 TWA 15 mg/m3 PEL 15 MPPCF TWA 15 mg/m3 TWA 50 MPPCF TWA 5 mg/m3 TWA Potassium salt of a phosphated coester of alcohol and aliphatic ethoxylate Quartz (SiO2) mg/m3 TWA 2.4 MPPCF TWA Respirable. 0.1 mg/m3 TWA Respirable mg/m3 TWA (Respirable dust.) (Respirable dust.) mg/m3 OSHA_ACT (Respirable dust.) 0.05 mg/m3 PEL Respirable dust. Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product. If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, appropriate NIOSH/MSHA respiratory protection must be provided. Wear chemical goggles; face shield (if splashing is possible). Chemical resistant, impermeable gloves. Gloves should be tested to determine suitability for prolonged contact. Use of impervious apron and boots are recommended. Page 3 of 6

4 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: White Odor: Amine Odor threshold: ph: Vapor pressure: < 1 mm hg Boiling point/range: > 98.9 C (> 210 F) Melting point/ range: Not determined Specific gravity: at 21 C (69.8 F) Vapor density: Not determined Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Flammability: Evaporation rate: Solubility in water: Complete Partition coefficient (n-octanol/water): Not determined VOC content: 5 % EPA Method 24 Viscosity: 2,000-5,000 cp Decomposition temperature: 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Reactivity: Conditions to avoid: Stable at normal conditions. Will not occur. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. This product may react with strong oxidizing agents. Keep away from heat, ignition sources and incompatible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes Page 4 of 6

5 Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: Inhalation of vapors or mists of the product may be irritating to the respiratory system. Excessive inhalation of this material causes headache, dizziness, nausea and incoordination. Prolonged or repeated skin contact may cause skin irritation or allergic skin sensitization reaction. This product may cause irritation to the eyes. Can cause irritation of mucous membranes. Ingestion of this product may cause nausea, vomiting and diarrhea. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Limestone Nuisance dust Trimethyl pentanediol mono-isobutyrate No Target Organs Titanium dioxide Potassium salt of a phosphated coester of alcohol and aliphatic ethoxylate Quartz (SiO2) Hazardous Component(s) NTP Carcinogen IARC Carcinogen Irritant, Respiratory, Some evidence of carcinogenicity No Target Organs Immune system, Lung, Some evidence of carcinogenicity OSHA Carcinogen (Specifically Regulated) Limestone No No No Trimethyl pentanediol mono-isobutyrate No No No Titanium dioxide No Group 2B No Potassium salt of a phosphated coester of alcohol and aliphatic ethoxylate Quartz (SiO2) No No No Known To Be Human Carcinogen. Group ECOLOGICAL INFORMATION Yes Ecological information: No data available. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. Canada Transportation of Dangerous Goods - Ground Proper shipping name: Not regulated Hazard class or division: Identification number: Packing group: International Air Transportation (ICAO/IATA) Proper shipping name: Not regulated Hazard class or division: Identification number: Packing group: Page 5 of 6

6 Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: Not regulated 15. REGULATORY INFORMATION Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. United States Regulatory Information TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: Reviewed MSDS. Reissued with new date. Prepared by: Jennifer Mckay, Regulatory Affairs Specialist Issue date: 03/13/2017 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 6 of 6