Safety Data Sheet - Version 5.0 Preparation Date 10/6/2015 Latest Revision Date (If Revised) SDS Expiry Date 10/4/2018

Transcription

1 Safety Data Sheet - Version 5.0 Preparation Date 10/6/2015 Latest Revision Date (If Revised) SDS Expiry Date 10/4/ IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product Identifier Chemical Name Zinc Chloride Catalogue # Z Relevant Identified Uses of the Substance or Mixture and Uses Advised Against Product Uses To be used only for scientific research and development. Not for use in humans or animals. 1.3 Details of the Supplier of the Safety Data Sheet Company Toronto Research Chemicals 2 Brisbane Road Toronto, ON M3J 2J8 CANADA Telephone FAX orders@trc-canada.com 1.4 Emergency Telephone Number Emergency# between (GMT-5) 2. HAZARDS IDENTIFICATION WHMIS Classification (Canada) D1B Toxic Material Causing Immediate and Serious Toxic Effects Toxic by Ingestion D2B Toxic Material Causing Other Toxic Effects E Severe Eye Irritant Corrosive Material Corrosive to Skin WHMIS Symbols (Canada) 2.1/2.2 Classification of the Substance or Mixture and Label Elements GHS Hazards Classification (According to EU Regulation 1272/2008 and US OSHA ) Acute Toxicity, Oral (Category 4) Skin Corrosion (Category 1B) Serious Eye Damage (Category 1) Hazardous to the Aquatic Environment, Acute Hazard (Category 1) Hazardous to the Aquatic Environment, Long-Term Hazard (Category 1) EU Classification (According to EU Regulation 67/548/EEC) Harmful if swallowed. Causes severe burns. Risk of serious damage to the eyes. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. EU Risk and Safety Statements (According to EU Regulation 67/548/EEC) Hazard Statements Hazard Codes Corrosive C Harmful Xn Environmental Hazard N Toronto Research Chemicals - Z Page 1

2 Risk Codes and Phrases R22 R35 R41 R50/53 Signal Word GHS Hazard Statements H302 H314 H318 H400 H410 Harmful if swallowed. Causes severe burns. Risk of serious damage to the eyes. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety Precaution Codes and Phrases S61 Avoid release to the environment. Refer to special instructions. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). GHS Hazards Identification (According to EU Regulation 1272/2008 and US OSHA ) Danger Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. GHS Precautionary Statements P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P304/P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for P310 breathing. P305/P351/P338 Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 2.3 Unclassified Hazards/Hazards Not Otherwise Classified. 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substances Molecular Formula: Cl 2 Zn Molecular Weight: CAS Registry #: EC#: Synonyms 004F2/68; 3-13L; 4P32; AN 200; AN 325; Amino-Zn; Amiplus Zn; Asarco L 15; Bioplex Zinco; Blue powder; C.I. Pigment Black 16; Ecka 4; F 1000; F 1000 (metal); F 1500T; F 2000; F 2000 (metal); F 500; F 500 (metal); GTT; GTT (metal); HZH; Ipaligo zinc; KFZn 1000; KFZn 1200; KFZn 1500; KFZn 325; KFZn 400; KFZn 500; KFZn 625; KFZn 800; LS 10; LS 10 (metal); LS 2; LS 2 (element); LS 30; LS 4; LS 5; LS 5 (metal); Larvik Superfine 25; MCS; MCS (metal); MS 10; MS 10 (metal); MSC; NC-Zinc; PTs 1; PTs 2; PTs 4; PTs 4 (element); PTsV; PTzR 4; RZN11-1; SK 2; SK 2 (metal); Standard Zincflake GTT; Standart Zink Flake AT; Stapa TE Zinc AT; Sun Ti-Zn; Tc 8; Tc 8 (metal); Teprosyn F 2498; UF; UF (metal); Umicore 4P32; VM 4P16; Z 620; ZG 777; ZNE 01PB; Zinc (powder); Zinc Dust 3.2 Mixtures Not a mixture. 4. FIRST AID MEASURES 4.1 Description of First Aid Measures Toronto Research Chemicals - Z Page 2

3 4.2 Most Important Symptoms and Effects, Both Acute and Delayed The most important known symptoms and effects are described in the labeling (see section 2.2) and/or in section Indication of any Immediate Medical Attention and Special Treatment Needed. 5. FIREFIGHTING MEASURES 5.1 Extinguishing Media Conditions of flammability Not flammable or combustible. Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.2 Special Hazards Arising from the Substance or Mixture Zinc oxides 5.3 Advice for Firefighters Wear self contained breathing apparatus for fire fighting if necessary. 5.4 Further Information. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Wear respiratory protection. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Method and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Keep in a dry place. Storage conditions: No Data Available Toronto Research Chemicals - Z Page 3

4 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control Parameters Components with workplace control parameters Components CAS-No. Value Control parameters Basis Zinc chloride TWA mg/m3 Canada. British Columbia OEL STEL mg/m3 Canada. British Columbia OEL TWA mg/m3 Canada. Alberta, Occupational Health and Safety Code (table 2: OEL) Remarks Occupational exposure limit is based on irritation effects and its adjustment to compensate for unusual work schedules is not required STEL mg/m3 Canada. Alberta, Occupational Health and Safety Code (table 2: OEL) Occupational exposure limit is based on irritation effects and its adjustment to compensate for unusual work schedules is not required TWA mg/m3 Canada. British Columbia OEL STEL mg/m3 Canada. British Columbia OEL TWAEV mg/m3 Que bec. Regulation respecting occupational health and safety, Schedule 1, Part 1: Permissible exposure values for airborne contaminants TWA mg/m3 Canada. Alberta, Occupational Health and Safety Code (table 2: OEL) Occupational exposure limit is based on irritation effects and its adjustment to compensate for unusual work schedules is not required STEL mg/m3 Canada. Alberta, Occupational Health and Safety Code (table 2: OEL) Occupational exposure limit is based on irritation effects and its adjustment to compensate for unusual work schedules is not required TWAEV mg/m3 Que bec. Regulation respecting occupational health and safety, Schedule 1, Part 1: Permissible exposure values for airborne contaminants TWA mg/m3 USA. ACGIH Threshold Limit Values (TLV) STEL mg/m3 USA. ACGIH Threshold Limit Values (TLV) TWA mg/m3 USA. ACGIH Threshold Limit Values (TLV) 8.2 Exposure Controls STEL mg/m3 USA. ACGIH Threshold Limit Values (TLV) Toronto Research Chemicals - Z Page 4

5 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on Basic Physical and Chemical Properties A) Appearance B) Odour No Data Available C) Odour Threshold D) ph E) Melting Point/Freezing Point F) Initial Boiling Point/Boiling Range No Data Available G) Flash point H) Evaporation Rate I) Flammability (Solid/Gas) J) Upper/Lower Flammability/Explosive Limits K) Vapour Pressure L) Vapour Density 1 hpa (1 mmhg) at 428 C (802 F) M) Relative Density N) Solubility g/cm3 O) Partition Coefficient: n-octanol/water No Data Available P) Auto-Ignition Temperature Q) Decomposition Temperature R) Viscosity S) Explosive Properties T) Oxidizing Properties 9.2 Other Information no data available 10. STABILITY AND REACTIVITY 10.1 Reactivity Toronto Research Chemicals - Z Page 5

6 Chemical Stability Stable under recommended storage conditions Possibility of Hazardous Reactions Conditions to Avoid Exposure to moisture Incompatible Materials Strong oxidizing agents Hazardous Decomposition Products In the event of fire: See section 5. Other decomposition products:. 11. TOXICOLOGICAL INFORMATION 11.1 Information on Toxicological Effects A) Acute Toxicity Oral LD50: Rat mg/kg Dermal LD50:. Inhalation LC50:. B) Skin Corrosion/Irritation Corrosive - causes skin and eye burns. May also cause respiratory tract damage. C) Serious Eye Damage/Irritation Corrosive - causes skin and eye burns. May also cause respiratory tract damage. D) Respiratory or Skin Sensitization E) Germ Cell Mutagenicity F) Carcinogenicity G) Reproductive Toxicity/Teratogenicity Limited laboratory results have shown reproductive toxicity/teratogenicity in animal models. H) Single Target Organ Toxicity - Single Exposure I) Single Target Organ Toxicity - Repeated Exposure J) Aspiration Hazard K) Potential Health Effects and Routes of Exposure Inhalation May be harmful if inhaled. Material is extremely destructive to the mucous membranes and respiratory tract. Ingestion Toxic if swallowed. Skin May be harmful if absorbed through skin. Causes skin burns. Eyes Causes severe eye burns and possible permanent eye damage. L) Signs and Symptoms of Exposure The most important known symptoms and effects are described in the labeling (see section 2.2) and/or in section 11. To the best of our knowledge, the chemical, physical, and toxicological properties of this material have not been thoroughly investigated. M) Additional Information RTECS: ZH ECOLOGICAL INFORMATION 12.1 Toxicity Toronto Research Chemicals - Z Page 6

7 12.2 Persistance and Degradability Bioaccumulative Potential Pimephales promelas (fathead minnow) - 63 d Bioconcentration factor (BCF): 21, Mobility in Soil Results of PBT and vpvb Assessment Other Adverse Effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic life with long lasting effects. 13. DISPOSAL CONSIDERATIONS 13.1 Waste Treatment Methods A) Product Product may be burned in an incinerator equipped with afterburner and scrubber. Excess and expired materials are to be offered to a licensed hazardous material disposal company. Ensure that all Federal and Local regulations regarding the disposal and destruction of this material are followed. B) Contaminated Packaging Dispose of as above. C) Other Considerations Product is not to be disposed of in sanitary sewers, storm sewers, or landfills. 14. TRANSPORT INFORMATION 14.1 UN Number DOT (US): UN2331 IATA: UN2331 IMDG: UN2331 ADR/RID: UN UN Proper Shipping Name DOT (US)/IATA: Zinc chloride, anhydrous IMDG/ARD/RID: ZINC CHLORIDE, ANHYDROUS 14.3 Transport Hazard Class(es) DOT (US): 8 IATA: 8 IMDG: 8 ADR/RID: Packing Group DOT (US): III IATA: III IMDG: III ADR/RID: III 14.5 Environmental Hazards DOT (US): None IATA: None IMDG: None ADR/RID: None 14.6 Special Precautions for User None 15. REGULATORY INFORMATION This safety data sheet complies with the requirements of WHMIS (Canada), OSHA (US), and EU Regulation EC No. 1907/2006 (European Union) Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture A) Canada DSL/NDSL Status: This product or a component of this product is registered on the Canadian DSL/NDSL. B) United States TSCA Status: This product or a component is listed on the US EPA TSCA. C) European Union ECHA Status: This product or a component is registered with the EU ECHA Chemical Safety Assessment 16. OTHER INFORMATION Toronto Research Chemicals - Z Page 7

8 16.1 Revision History Original Publication Date: 10/6/ List of Abbreviations LD50 Median lethal dose of a substance required to kill 50% of a test population. LC50 Medial lethal concentration of a substance required to kill 50% of a test population. LDLo Lowest known lethal dose TDLo Lowest known toxic dose IARC International Agency for Research on Cancer NTP National Toxicology Program RTECS Registry of Toxic Effects of Chemical Substances 16.3 Further Information Copyright Toronto Research Chemicals Inc. Copies may be made for internal use only. The above information is believed to be correct to the best of our knowledge, but is to be only used as a guide. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Please take all due care when handling this product. Toronto Research Chemicals - Z Page 8