SECTION 1: Identification. SECTION 2: Hazard(s) identification Identification

Transcription

1 SECTION 1: Identification 1.1. Identification Product form Polyethylene glycol diacrylate (PEGDA 200) Date of issue: 06/07/2018 Version: 1.0 : Substance Substance name : Polyethylene glycol diacrylate (PEGDA 200) CAS No : Product code : Recommended use and restrictions on use Recommended use 1.3. Supplier 1.4. Emergency telephone number : Use as laboratory reagent, Manufacture of substances SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Skin sensitization, Category 1 H315 H318 H317 Full text of H statements : see section 16 Causes skin irritation Causes serious eye damage May cause an allergic skin reaction 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger 2.3. Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) : H315 - Causes skin irritation H317 - May cause an allergic skin reaction H318 - Causes serious eye damage : P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. P264 - Wash hands, forearms and face thoroughly after handling. P272 - Contaminated work clothing must not be allowed out of the workplace P280 - Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 - If on skin: Wash with plenty of water P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a poison center or doctor P321 - Specific treatment (see supplemental first aid instruction on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P363 - Wash contaminated clothing before reuse. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation 06/07/2018 EN (English US) Page 1

2 SECTION 3: Composition/Information on ingredients 3.1. Substances Name Product identifier % GHS-US classification Polyethylene glycol diacrylate (PEGDA 200) (Main constituent) Full text of hazard classes and H-statements : see section Mixtures SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects after skin contact Symptoms/effects after eye contact (CAS No) <= 100 Skin Irrit. 2, H315 Eye Dam. 1, H318 Skin Sens. 1, H317 : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately. : Call a poison center/doctor/physician if you feel unwell. : Irritation. May cause an allergic skin reaction. : Serious damage to eyes Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media 5.2. Specific hazards arising from the chemical Reactivity : Water spray. Dry powder. Foam. Carbon dioxide Special protective equipment and precautions for fire-fighters Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : The product is non-reactive under normal conditions of use, storage and transport. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. Avoid breathing dust/fume/gas/mist/vapors/spray. 06/07/2018 EN (English US) 2/5

3 Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Storage temperature : 22 C SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. : Store in a well-ventilated place. Keep cool Appropriate engineering controls Appropriate engineering controls Environmental exposure controls : Ensure good ventilation of the work station. : Avoid release to the environment Individual protection measures/personal protective equipment Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color Odor Odor threshold ph Melting point : Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) :. Vapor pressure Relative vapor density at 20 C Relative density Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 06/07/2018 EN (English US) 3/5

4 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Symptoms/effects after skin contact Symptoms/effects after eye contact SECTION 12: Ecological information Toxicity Ecology - general : Causes skin irritation. : Causes serious eye damage. : May cause an allergic skin reaction. : Irritation. May cause an allergic skin reaction. : Serious damage to eyes. : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects SECTION 13: Disposal considerations Disposal methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. 06/07/2018 EN (English US) 4/5

5 SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT TDG Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Polyethylene glycol diacrylate (PEGDA 200) ( ) Listed on the United States TSCA (Toxic Substances Control Act) inventory EPA TSCA Regulatory Flag XU - XU - indicates a substance exempt from reporting under Chemical Data Reporting Rule (formerly the Inventory Update Reporting Rule), i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 711) International regulations CANADA Polyethylene glycol diacrylate (PEGDA 200) ( ) Listed on the Canadian DSL (Domestic Substances List) EU-Regulations National regulations US State regulations SECTION 16: Other information Full text of H-phrases: H315 H317 H318 Causes skin irritation May cause an allergic skin reaction Causes serious eye damage SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 06/07/2018 EN (English US) 5/5