SAFETY DATA SHEET 266, REV B Effective Date: May 14, 2004

Transcription

1 Revised Date: vember 15, 2005 Page: 1 of 7 SECTION 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Colline 902H, Collins Complete, black ink cartridges for the AddressRight Addressing Systems DA400 and DA950 Reorder 412-2: Complete 412-3: 902H Manufacturer: Pitney Bowes Inc. Address: 1 Elmcroft Road, Stamford, CT For MSDS Copies: (go to Pitney Bowes, Ltd search) The Pinnacles Harlow Essex, CM19 5BD Contact Compliance Engineering Emergency/Chemtrec: rth America MSDS Prepared By: Chemical Review Board WHMIS Reviewed vember 15, (0) International (collect call) SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT NAME CAS NO./EINECS NO. % EC SUBSTANCE CLASSIFICATION (67/548/EEC) Pigments and Dyes Proprietary <40 t Applicable Carbon Black <20 t Applicable Triethylene Glycol <20 Xi, R36/37/38 Triethanolamine <2 Xi, R36 5-chloro-2-methyl / <0.1 C, N, R34, R43, R50 isothiazoline-3-one Water >50 t Applicable ADDITIONAL INFORMATION Remaining ingredients are non-hazardous. See Section 16 for full text of EC Classification and R Phrases SECTION 3 HAZARDS IDENTIFICATION Emergency Overview: Black liquid with a slight characteristic odor. May cause eye and skin irritation. Direct contact may stain tissues. EU Preparation Classification t classified as dangerous (1999/45/EC): See Section 16 for full text of EC Classification and R Phrases

2 Revised Date: vember 15, 2005 Page: 2 of 7 SECTION 4 FIRST AID MEASURES Eyes: Immediately flush with plenty of running cool water for 15 minutes, holding eyelids open to assure thorough rinsing. Get medical attention. Skin: Remove contaminated clothing. Wash exposed skin with soap and water. Launder clothing before reuse. Get medical attention if irritation persists. Ingestion: If swallowed, get medical attention. If medical advice is not available and victim is conscious, give large quantities of water and induce vomiting. Never give fluids if the victim is unconscious, having convulsions, or cannot swallow. Inhalation: Remove person to fresh air. If irritation or pulmonary symptoms develop, consult a physician. SECTION 5 FIRE FIGHTING PROCEDURES Extinguishing Media: Use media appropriate for surrounding fire. Fire Fighting Instructions: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. This product may discolor run-off water. Unusual Fire and Explosion ne known. Hazards: Known or Anticipated Carbon monoxide, carbon dioxide, and nitrogen oxides. Hazardous s of Combustion: SECTION 6 ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Wipe up with absorbent material and place into a suitable container for disposal. Rinse residue with water. IT may not be possible to decolorize stains. Personal Precautions: Avoid contact with eyes, skin and clothing. Environmental Precautions: It is recommended to keep away from drains, surface and ground-water. Methods for Cleanup: Collect with an inert absorbent material. Large Spill: t sold in large quantities. Small Spill: Collect with an inert absorbent material and place into a suitable container. Keep out of sewers and watercourses. SECTION 7 HANDLING AND STORAGE Handling: Avoid contact with eyes, skin and clothing. Avoid inhalation of mists. Keep container closed when not in use. Wash skin thoroughly with soap and water after use. Storage: Store in a cool, dry place. Keep container closed. Keep out of the reach of children. Other Precautions: ne required under normal use conditions. SECTION 8 EXPOSURE CONTROLS & PERSONAL PROTECTION

3 Revised Date: vember 15, 2005 Page: 3 of 7 SECTION 8 EXPOSURE CONTROLS & PERSONAL PROTECTION Occupational Exposure Limits: Pigments and Dyes ne Established Carbon Black Triethylene Glycol Triethanolamine 5-chloro-2-methyl-4- isothiazoline-3-one Water 3.5 mg/m3 TWA ACGIH-TLV 3.5 mg/m3 TWA OSHA-PEL 3.5 mg/m3 TWA, 7 mg/m3 STEL UK WEL ne Established 5 mg/m3 TWA ACGIH-TLV ne Established ne Established Engineering Controls: Ventilation Requirements: Personal Protective Equipment: Eye/Face Protection: Skin Protection: Respiratory Protection: Other Protective Clothing or Equipment: ne required with normal use. General office ventilation is adequate under normal use conditions. For operations where mists may be generated, mechanical ventilation such as local exhaust may be used. ne normally required. In situations where contact can occur, wear safety glasses with sideshields or chemical goggles. t normally required. If skin contact is likely, wear rubber gloves. t required under normal use conditions. t required under normal use conditions. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance: Black liquid with a slight characteristic odor. Boiling Point: >212 F (>100 C) Color: Black liquid Freezing Point: t determined Melting Point: <59 F (15 C) Octanol/Water Partition Coefficient: Odor: Slight, characteristic odor Odor Threshold: Percent Volatile: <9.34 lb/gal ph Value: ph Concentration: Physical State: Liquid Reactivity in Water: ne Solubility in Water: Miscible Specific Gravity or Density (Water=1): Vapor Density: t determined

4 Revised Date: vember 15, 2005 Page: 4 of 7 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Vapor Pressure: t determined Vapor Pressure Temperature: Volatile Organic Compounds: t determined Water/Oil Distribution t determined Coefficient: Weight Per Gallon: t determined Flammable Limits in Air (% by Volume): Flash Point: >305 F (151 C) TCC Autoignition Temperature: t determined SECTION 10 STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: Keep away from excessive heat. Incompatibility With Other Avoid contact with strong oxidizing agents and water Materials: reactive materials. Hazardous Decomposition Carbon monoxide, carbon dioxide and oxides of s: nitrogen. Hazardous Polymerization: Will not occur. Conditions to Avoid: SECTION 11 TOXICOLOGICAL INFORMATION Relevant Routes of Exposure: Skin and eyes. Signs and Symptoms of Acute May cause eye irritation with redness and burning. Overexposure: May impair vision by staining the eye. May cause skin irritation with redness and drying of the skin. Inhalation of mists may cause upper respiratory tract irritation with coughing. Swallowing may cause gastric upset. Signs and Symptoms of ne expected. Chronic Overexposure: Medical Conditions Generally ne known. Aggravated By Exposure: Potential Health Effects: Eyes: May cause eye irritation with redness and burning. May impair vision by staining the eye. Skin: May cause irritation with redness, itching and drying of the skin. Direct contact may stain the skin. Ingestion: Swallowing will stain the mouth and esophagus. Swallowing large amounts may cause mucous and gastrointestinal tract irritation and may cause difficulty in swallowing. Inhalation: Inhalation of mists may cause mucous membrane and upper respiratory tract irritation. Carcinogenicity: NTP: IARC: OSHA: ACGIH:

5 Revised Date: vember 15, 2005 Page: 5 of 7 SECTION 11 TOXICOLOGICAL INFORMATION OTHER: Acute Toxicity Data VALUE ANIMAL ROUTES COMPONENTS LD50: >15 g/kg Rat Oral SECTION 12 ECOLOGICAL INFORMATION Ecological Information: data available. SECTION 13 DISPOSAL CONSIDERATIONS Disposal Considerations: Dispose in accordance with local, state or provincial and federal or national regulations. SECTION 14 TRANSPORT INFORMATION U.S. DOT Proper Shipping t regulated Hazard Class: ID Packing Group: Labels: ne Special Provisions: ne Packaging Exceptions: n-bulk Packaging: Bulk Packaging: Air/Rail Limit: Air Cargo Limit: Vessel Stowage: Other Stowage: ne Reportable Quantity: ne rth America Emergency Response Guide Number AIR ICAO OR IATA Proper Shipping t regulated Hazard Class: ID Risk: Packing Group: Hazard Labels: ne Packing Instructions: Air Passenger/Cargo Limit Per Package: Packing Instruction Cargo: Air Cargo Limit Per Package: Special Provisions Code: ne WATER IMDG Proper Shipping t regulated Hazard Class:

6 Revised Date: vember 15, 2005 Page: 6 of 7 SECTION 14 TRANSPORT INFORMATION ID Packing Group: Risk: Emergency Procedures Code: Medical First Aid Guide Code: SECTION 15 REGULATORY INFORMATION U.S. Federal Regulations: This product does not contain chemical or chemical compounds listed in the following SARA Title III categories: Extremely Hazardous Substances (302), Toxic Chemical Release Reporting (313). All the components of this product are listed in the EPA TSCA Inventory. SARA Hazards: Acute: Yes Chronic: Reactive: Fire: Pressure: State Regulations: International Regulations: EU Labeling: Special Provisions under 1999/45/EC Annex V This product does not contain any chemicals subject to California Proposition 65. All of the components are listed on the EINECS inventory. Canada: Class D 2- B (Toxic material causing other chronic effects). All of the components are listed in the Canadian DSL. Australia: All of the components are listed on the Australian AICS inventory. Japan: All of the chemicals are listed on the Japanese METI ENCS List. t classified as a dangerous material. Safety Data Sheet available to professional user on request SECTION 16 OTHER INFORMATION NFPA Codes: Health: 1 Flammability: 0 Reactivity: 0 Other: 0 HMIS Codes: Health: 1 Flammability: 0 Reactivity: 0 Protection: EU Classes and Risk Phrases for Reference (See Sections 2 and 3): Xi Irritant C Corrosive N Dangerous to the environment

7 Revised Date: vember 15, 2005 Page: 7 of 7 SECTION 16 OTHER INFORMATION R34 Causes burns R36 Irritating to eyes R36/37/38 Irritating to eyes, respiratory system and skin R43 May cause sensitization by skin contact R50 Very toxic to aquatic organisms Other Information: Keep out of reach of children.