SAFETY DATA SHEET according to 1907/2006/EC, Article 31
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1 SAFETY DATA SHEET according to 1907/2006/EC, Article 1 Page 1/7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier date Product name 1.2. Relevant identified uses of the substance or mixture and uses advised against Product Use Description 1.. Details of the supplier of the safety data sheet Company Address Web [SU22] Professional uses: Public domain (administration, education, entertainment, services, craftsmen); [SU24] Scientific research and development; [PC9a] Coatings and paints, thinners, paint removers; Temperature indicating colour change paint. Thermographic Measurements Ltd Riverside Buildings Dock Road Connah s Quay Flintshire CH5 4DS United Kingdom Telephone +44 (0) Fax +44 (0) address of the competent person 1.4. Emergency telephone number sales@t-m-c.com chrisc@t-m-com Emergency telephone number +44 (0) Intended use SECTION 2: Hazards identification Hours to Classification of the substance or mixture For professional use only in scientific research and development. Temperature measurement and thermal mapping Classification /45/ЕC Main hazards Classification - EC 1272/ Label elements Xn; R20/21 Xi; R8 R10 Symbols: Xn: Harmful. Flammable. Harmful by inhalation and in contact with skin. Irritating to skin. Flam. Liq. : H226; Skin Irrit. 2: H15; Eye Irrit. 2: H19;
2 date Page 2/ Label elements Hazard pictograms Signal Word Hazard Statement Prevention Response Storage Disposal Warning Flam. Liq. : H226 - Flammable liquid and vapour. Skin Irrit. 2: H15 - Causes skin irritation. Eye Irrit. 2: H19 - Causes serious eye irritation. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P2 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting// equipment. P242 - Use only non-sparking tools. P24 - Take precautionary measures against static discharge. P264 - Wash thoroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P02+P52 - IF ON SKIN: Wash with plenty of water/. P0+P61+P5 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P05+P51+P8 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P21 - Specific treatment (see on this label). P2+P1 - If skin irritation occurs: Get medical advice/attention. P7+P1 - If eye irritation persists: Get medical advice/attention. P70+P78 - In case of fire: Use to extinguish. P40+P25 - Store in a well-ventilated place. Keep cool. P501 - Dispose of contents/container to SECTION : Composition/information on ingredients.2. Mixtures 67/548/EEC / 1999/45/EC Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification 2-methoxy-1-methylethyl acetate % R10 M-factor. Xylene % R10 Xn; R20/21 Xi; R8 Pigment 10-20% Xi; R6/7/8 Ethylbenzene % F; R11 Xn; R20 EC 1272/2008 Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification 2-methoxy-1-methylethyl acetate % Flam. Liq. : H226; M-factor. Xylene % Flam. Liq. : H226; Acute Tox. 4: H2; Acute Tox. 4: H12; Skin Irrit. 2: H15; Pigment 10-20% Skin Irrit. 2: H15; Eye Irrit. 2: H19; STOT SE : H5; Ethylbenzene % Flam. Liq. 2: H225; Acute Tox. 4: H2; SECTION 4: First aid measures
3 / Description of first aid measures Inhalation Eye contact Skin contact Ingestion Move the exposed person to fresh air. Seek medical attention Most important symptoms and effects, both acute and delayed Inhalation Eye contact Skin contact Ingestion date Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical attention if irritation or symptoms persist. Wash off immediately with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Ingestion is irritating to the respiratory tract and may cause damage to the central nervous system. DO NOT INDUCE VOMITING. If swallowed, seek medical advice immediately and show this container or label. Harmful by inhalation. Inhalation may cause nausea and vomiting. May cause dizziness and headache. May cause irritation to eyes. May cause irritation to skin. May cause dermatitis. Harmful if swallowed. 4.. Indication of any immediate medical attention and special treatment needed Inhalation Eye contact Skin contact Ingestion SECTION 5: Firefighting measures 5.1. Extinguishing media 5.2. Special hazards arising from the substance or mixture Move the exposed person to fresh air. Seek medical attention. Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical attention if irritation or symptoms persist. Seek medical attention if irritation or symptoms persist. If swallowed, seek medical advice immediately and show this container or label. Use as appropriate: Carbon dioxide (CO2), Dry chemical, Foam. 5.. Advice for firefighters Burning produces irritating, toxic and obnoxious fumes. Vapour may travel considerable distance to source of ignition and flash back. Wear suitable respiratory equipment when necessary. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions 6.. Methods and material for containment and cleaning up SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Ensure adequate ventilation of the working area. Eliminate all sources of ignition. Wear suitable protective equipment. Do not allow product to enter drains. Prevent further spillage if safe. Absorb with inert, absorbent material. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Use explosion proof equipment. Keep away from sources of ignition - No smoking. Adopt best Manual Handling considerations when handling, carrying and dispensing. Keep in a cool, dry, well ventilated area. Keep containers tightly closed.
4 4/7 date 7.. Specific end use(s) Do not spray on naked flame or any other incandescent material. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure Limit Values 2-methoxy-1-methylethyl acetate WEL 8-hr limit ppm: 50 WEL 8-hr limit mg/m: 274 WEL 15 min limit ppm: 100 WEL 15 min limit mg/m: 548 WEL 8-hr limit mg/m total - WEL 15 min limit mg/m total - WEL 8-hr limit mg/m total - WEL 15 min limit mg/m total - Ethylbenzene WEL 8-hr limit ppm: 100 WEL 8-hr limit mg/m: 441 WEL 15 min limit ppm: 125 WEL 15 min limit mg/m: 552 WEL 8-hr limit mg/m total - WEL 15 min limit mg/m total - WEL 8-hr limit mg/m total - WEL 15 min limit mg/m total - Xylene WEL 8-hr limit ppm: 50 WEL 8-hr limit mg/m: Exposure controls WEL 15 min limit ppm: 100 WEL 15 min limit mg/m: 441 WEL 8-hr limit mg/m total - WEL 15 min limit mg/m total - WEL 8-hr limit mg/m total - WEL 15 min limit mg/m total Appropriate engineering controls Individual protection measures Eye / face protection Skin protection - Handprotection Respiratory protection Ensure adequate ventilation of the working area. Wear chemical protective clothing. Approved safety goggles. Chemical resistant gloves (PVC). Self-contained breathing apparatus. Wear protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Liquid Colour Blue Odour Mild Initial boiling point 140 Flash point 2 Relative density 1.1 Solubility Slightly miscible in water 9.2. Other information VOC (Volatile organic 56 compounds) Total Solids 44 SECTION 10: Stability and reactivity Reactivity Avoid sparks, flames, heat and sources of ignition.
5 5/7 date Chemical stability 10.. Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Stable under normal conditions. Oxidising agents. Heat, sparks and open flames. Oxidising agents. SECTION 11: Toxicological information Toxicological Information Burning produces obnoxious and irritating fumes. 2-methoxy-1-methylethyl acetate Oral Rat LD50: 852 mg/kg Dermal Rabbit LD50: >5 gm/kg Ethylbenzene Inhalation Rat LC50/2H h: mg/m Oral Rat LD50: 500 mg/kg Inhalation Mouse LC50/2H h: 5500 mg/m Dermal Rabbit LD50: ul/kg Xylene Inhalation Rat LC50/4H h: 5000 ppm Oral Rat LD50: 400 mg/kg SECTION 12: Ecological information Further information SECTION 1: Disposal considerations General information Disposal methods SECTION 14: Transport information Hazard pictograms Oral Mouse LD50: 2119 mg/kg Dermal Rabbit LD50: >1700 mg/kg An environmental hazard cannot be eliminated in the event of unproffesional handling or disposal. Do not allow product to enter drains. Dispose of in compliance with all local and national regulations. Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point UN number UN UN proper shipping name PAINT 14.. Transport hazard class(es) ADR/RID Subsidiary risk - IMDG Subsidiary risk -
6 6/7 date 14.. Transport hazard class(es) IATA Subsidiary risk Packing group Packing group Environmental hazards Environmental hazards Marine pollutant ADR/RID III No No Hazard ID Tunnel Category IMDG EmS Code IATA (D/E) Packing Instruction (Cargo) 66 Maximum quantity Packing Instruction (Passenger) Maximum quantity F-E S-E 220 L L SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Regulations Further information This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. COMMISSION REGULATION (EU) No 45/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 79/9 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 9/67/EEC, 9/105/EC and 2000/21/EC. For this product a chemical safety assessment was not carried out. SECTION 16: Other information Other information Text of risk phrases in Section This document differs from the previous version in the following areas:. 1 - Product Use Classification - EC 1272/ Hazard pictograms. 2 - Signal Word. 2 - Prevention. 2 - Response. 2 - Storage. 2 - Disposal Information on basic physical and chemical properties (Initial boiling point) Information on basic physical and chemical properties (Relative density) Information on basic physical and chemical properties (Solubility) Toxicity. R10 - Flammable R11 - Highly flammable. R20/21 - Harmful by inhalation and in contact with skin.
7 7/7 date Other information Text of Hazard Statements in Section Maximum content of VOC 56. Further information R20 - Harmful by inhalation. R6/7/8 - Irritating to eyes, respiratory system and skin. R8 - Irritating to skin. Flam. Liq. : H226 - Flammable liquid and vapour. Acute Tox. 4: H12 - Harmful in contact with skin. Skin Irrit. 2: H15 - Causes skin irritation. Acute Tox. 4: H2 - Harmful if inhaled. Eye Irrit. 2: H19 - Causes serious eye irritation. STOT SE : H5 - May cause respiratory irritation. Flam. Liq. 2: H225 - Highly flammable liquid and vapour. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process.
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