Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/2006 Loctite 3463 Page 1 of 12 sds no. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Loctite Relevant identified uses of the substance or mixture and uses advised against Intended use: Epoxy resin 1.3. Details of the supplier of the safety data sheet Henkel Limited Technologies House Wood Lane End HP2 4RQ Hemel Hempstead Great Britain Phone: +44 (0) Fax-no.: +44 (0) ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (DPD): Xi - Irritant R36/38 Irritating to eyes and skin. carcinogenic, category 3 R40 Limited evidence of a carcinogenic effect. Sensitizing R43 May cause sensitisation by skin contact. Dangerous for the environment R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Label elements

2 Loctite 3463 Page 2 of 12 Label elements (DPD): Xn - Harmful Risk phrases: R36/38 Irritating to eyes and skin. R40 Limited evidence of a carcinogenic effect. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water and soap. S36/37 Wear suitable protective clothing and gloves. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Additional labeling: Contains epoxy constituents. See information supplied by the manufacturer. For consumer use only: S2 Keep out of the reach of children S46 If swallowed, seek medical advice immediately and show this container or label. Contains:, Glass, oxide, chemicals 2.3. Other hazards None if used properly. General chemical description: Epoxy resin SECTION 3: Composition/information on ingredients Declaration of the ingredients according to CLP (EC) No 1272/2008: EC Number REACH-Reg No content Classification >= 10- < 20 % Flammable solids 2 H228 Glass, oxide, chemicals ,4,6-Tris(dimethylaminomethyl)phenol >= 10- < 20 % Skin sensitizer 1 H317 Chronic hazards to the aquatic environment 2 H411 Serious eye irritation 2 H319 Skin irritation 2 H >= 10- < 20 % Carcinogenicity 2 H >= 5- < 10 % Skin irritation 2 H315 Acute toxicity 4; Oral H302 Serious eye irritation 2 H319 For full text of the H - statements and other abbreviations see section 16 "Other information".

3 Loctite 3463 Page 3 of 12 Substances without classification may have community workplace exposure limits available. Declaration of ingredients according to DPD (EC) No 1999/45: EC Number REACH-Reg No content Classification >= 10 - < 20 % F - Highly flammable; R11 Glass, oxide, chemicals ,4,6- Tris(dimethylaminomethyl)phenol >= 10 - < 20 % R43 Xi - Irritant; R36/38 N - Dangerous for the environment; R51/ >= 10 - < 20 % carcinogenic, category 3; R >= 5 - < 10 % Xn - Harmful; R22 Xi - Irritant; R36/38 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available Description of first aid measures SECTION 4: First aid measures Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Rinse with running water and soap. Seek medical advice. Eye contact: Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary. Ingestion: Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting. Seek medical advice Most important symptoms and effects, both acute and delayed EYE: Irritation, conjunctivitis. SKIN: Rash, Urticaria. SKIN: Redness, inflammation. Limited evidence of a carcinogenic effect (carcinogenic category 3) Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: Carbon dioxide, foam, powder SECTION 5: Firefighting measures 5.2. Special hazards arising from the substance or mixture In case of fire, keep containers cool with water spray. Oxides of carbon, oxides of nitrogen, irritating organic vapors Advice for firefighters Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

4 Loctite 3463 Page 4 of 12 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid skin and eye contact Environmental precautions Do not let product enter drains Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Dispose of contaminated material as waste according to Chapter Reference to other sections See advice in chapter 8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Use only in well-ventilated areas. Avoid skin and eye contact. Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation. Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed Conditions for safe storage, including any incompatibilities Store in a cool, well-ventilated place. For optimum shelf life store in original containers under refrigerated conditions at 2-8 C ( F) 7.3. Specific end use(s) Epoxy resin SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Great Britain None

5 Loctite 3463 Page 5 of 12 Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment aqua (freshwater) aqua (marine water) aqua (intermittent releases) STP sediment (freshwater) sediment (marine water) period Value mg/l ppm mg/kg others 0,006 mg/l 0,996 mg/kg 0,0996 mg/kg soil 0,196 mg/kg oral 0,0006 mg/l 0,018 mg/l 10 mg/l 11 mg/kg food Remarks

6 Loctite 3463 Page 6 of 12 Derived No-Effect Level (DNEL): Name on list Application Area Route of oral inhalation Health Effect Long term Long term local effects worker inhalation Long term local effects worker dermal Acute/short term worker inhalation Acute/short term worker dermal Long term worker inhalation Long term dermal inhalation oral dermal inhalation oral Acute/short term Acute/short term Acute/short term Long term Long term Long term Time Value 0,71 mg/kg bw/day 1,5 mg/m3 3 mg/m3 8,3 mg/kg bw/day 12,3 mg/m3 8,3 mg/kg bw/day 12,3 mg/m3 3,6 mg/kg bw/day 0,75 mg/m3 0,75 mg/kg bw/day 3,6 mg/kg bw/day 0,75 mg/m3 0,75 mg/kg bw/day Remarks Biological Indices: None 8.2. controls: Respiratory protection: Suitable breathing mask when there is inadequate ventilation. Suitable respiratory protection: Filter type: A

7 Loctite 3463 Page 7 of 12 Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Wear protective glasses. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste grey Odor Mild Odour threshold ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density () Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) (Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties 390 C (734 F) 284 C (543.2 F); None 2,1038 g/cm3 Not miscible 9.2. Other information SECTION 10: Stability and reactivity Reactivity Reaction with strong acids. Reacts with strong oxidants Chemical stability Stable under recommended storage conditions.

8 Loctite 3463 Page 8 of Possibility of hazardous reactions See section reactivity Conditions to avoid None if used for intended purpose Incompatible materials None if used properly Hazardous decomposition products None known Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Oral toxicity: May cause irritation to the digestive tract. Inhalative toxicity: May cause irritation to respiratory system. Skin irritation: Irritating to the skin. Eye irritation: Irritating to eyes. Sensitizing: May cause sensitization by skin contact. Carcinogenicity: Limited evidence of a carcinogenic effect Acute oral toxicity: 2,4,6- Tris(dimethylaminomethy l)phenol Value Value type LD mg/kg Route of application time Species Method oral rat OECD Guideline 401 (Acute Oral Toxicity) Acute dermal toxicity: 2,4,6- Tris(dimethylaminomethy l)phenol Value Value Route of Species type application time LD50 dermal rat Method Skin corrosion/irritation: Reaction product: bisphenol-a- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) Result time Species Method slightly irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion)

9 Loctite 3463 Page 9 of 12 Serious eye damage/irritation: Reaction product: bisphenol-a- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) Result time Species Method not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiratory or skin sensitization: Reaction product: bisphenol-a- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) 2,4,6- Tris(dimethylaminomethy l)phenol sensitising not sensitising Result Test type Species Method Mouse local lymphnod e assay (LLNA) Buehler test mouse guinea pig OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: Reaction product: bisphenol-a- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / time Species Method OECD Guideline 472 (Genetic Toxicology: Escherichia coli, Reverse Mutation Assay) SECTION 12: Ecological information General ecological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following Toxicity Ecotoxicity: Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Do not empty into drains / surface water / ground water.

10 Loctite 3463 Page 10 of 12 Reaction product: bisphenol- A-(epichlorhydrin); epoxy resin (number average molecular weight <= 700) Glass, oxide, chemicals Glass, oxide, chemicals Glass, oxide, chemicals ,4,6- Tris(dimethylaminomethyl)ph enol Value type Value Acute Toxicity Study time Species Method LC50 > mg/l Fish 48 h Leuciscus idus OECD Guideline 203 (Fish, Acute Toxicity Test) LC50 1, mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) LC50 > mg/l Fish OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 > mg/l Daphnia Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > mg/l Algae OECD Guideline 201 (Alga, Growth Inhibition Test) LC mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) Persistence and degradability Persistence and Biodegradability: The product is not biodegradable Bioaccumulative potential / Mobility in soil Mobility: Cured adhesives are immobile. Bioaccumulative potential: No data available. 2,4,6- Tris(dimethylaminomethyl)ph enol LogKow Bioconcentration factor (BCF) 0,77 time Species Temperature Method Results of PBT and vpvb assessment (epichlorhydrin); epoxy resin (number average molecular weight <= 700) PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling PBT (persistent/bioaccummulative/toxic) criteria Other adverse effects No data available. SECTION 13: Disposal considerations Waste treatment methods

11 Loctite 3463 Page 11 of 12 Product disposal: Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Disposal must be made according to official regulations. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances SECTION 14: Transport information UN number Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR UN proper shipping name Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Transport hazard class(es) Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Packaging group Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Environmental hazards Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Special precautions for user Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content < 3 % (1999/13/EC) Chemical safety assessment A chemical safety assessment has not been carried out.

12 Loctite 3463 Page 12 of 12 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R11 Highly flammable. R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. R40 Limited evidence of a carcinogenic effect. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. H228 Flammable solid. H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H351 Suspected of causing cancer. H411 Toxic to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.