Safety Data Sheet according to Regulation (EC) No1907/2006

Transcription

1 Safety Data Sheet according to Regulation (EC) No1907/2006 LOCTITE ABLESTIK 104MOD3 PTB known as ECCOBOND 104 MOD Page 1 of 9 SDS No. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Contains: Benzene-1,2:4,5-tetracarboxylic dianhydride 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Adhesive 1.3. Details of the supplier of the safety data sheet Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Serious eye damage Category 1 H318 Causes serious eye damage. Respiratory sensitizer Category 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin sensitizer Category 1 H317 May cause an allergic skin reaction. Classification (DPD): Sensitizing R42/43 May cause sensitization by inhalation and skin contact. Xi - Irritant R41 Risk of serious damage to eyes Label elements Label elements (CLP):

2 Page 2 of 9 Hazard pictogram: Signal word: Danger Hazard statement: Precautionary statement: Prevention Precautionary statement: Response H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. P261 Avoid breathing dust. P280 Wear protective gloves/eye protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Label elements (DPD): Xn - Harmful Risk phrases: R41 Risk of serious damage to eyes. R42/43 May cause sensitization by inhalation and skin contact. Safety phrases: S22 Do not breathe dust. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39 Wear suitable gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Contains: Benzene-1,2:4,5-tetracarboxylic dianhydride 2.3. Other hazards None if used properly. SECTION 3: Composition/information on ingredients

3 Page 3 of 9 Declaration of the ingredients according to CLP (EC) No 1272/2008: Benzene-1,2:4,5-tetracarboxylic dianhydride Benzene-1,2,4,5-tetracarboxylic acid EC Number REACH-Reg No. content Classification >= 25- < 50 % Serious eye damage 1 H318 Respiratory sensitizer 1 H334 Skin sensitizer 1 H >= 1- < 5 % Serious eye irritation 2 H319 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. Declaration of ingredients according to DPD (EC) No 1999/45: Benzene-1,2:4,5-tetracarboxylic dianhydride Benzene-1,2,4,5-tetracarboxylic acid EC Number REACH-Reg No. content Classification >= 25 - < 50 % Xi - Irritant; R41 R42/ >= 1 - < 5 % Xi - Irritant; R36 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available Description of first aid measures SECTION 4: First aid measures Inhalation: Should not be a problem as product is of low volatility. However, if feeling unwell remove patient to fresh air. Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical advice. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor Most important symptoms and effects, both acute and delayed May cause allergy or asthma symptoms or breathing difficulties if inhaled. SKIN: Rash, Urticaria. EYE: Irritation, conjunctivitis Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures

4 Page 4 of Extinguishing media Suitable extinguishing media: water, carbon dioxide, foam, powder Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released. In case of fire, keep containers cool with water spray. carbon oxides Advice for firefighters Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. Wear protective equipment Environmental precautions Do not empty into drains / surface water / ground water Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal Reference to other sections See advice in section Precautions for safe handling Avoid skin and eye contact. See advice in section 8 Hygiene measures: Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. SECTION 7: Handling and storage 7.2. Conditions for safe storage, including any incompatibilities Ensure good ventilation/extraction. Keep container tightly sealed. Store at room temperature Specific end use(s) Adhesive

5 Page 5 of 9 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational Exposure Limits Valid for Great Britain Ingredient ppm mg/m 3 Type Category Remarks MICA, RESPIRABLE 0,8 Time Weighted Average EH40 WEL (TWA): MICA, TOTAL INHALABLE Time Weighted Average (TWA): EH40 WEL Biological Exposure Indices: None 8.2. Exposure controls: Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance powder Off white Odour threshold ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density Bulk density Viscosity Viscosity (kinematic) Not applicable

6 Page 6 of 9 Explosive properties Solubility (qualitative) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties 9.2. Other information Reactivity Reacts with alcohols and amines. Oxidizers Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid No decomposition if stored and applied as directed Incompatible materials See section reactivity Hazardous decomposition products carbon oxides. Hydrocarbons SECTION 10: Stability and reactivity Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Oral toxicity: May cause irritation to the digestive tract. Inhalative toxicity: May cause sensitization by inhalation. Skin irritation: Prolonged or repeated contact may cause skin irritation. Eye irritation: Causes serious eye damage. Sensitizing: May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

7 Page 7 of 9 Acute oral toxicity: Benzene-1,2:4,5- tetracarboxylic dianhydride Value Value Route of Exposure Species type application time LD mg/kg oral rat Method Acute inhalative toxicity: Value type Value Route of application Exposure time Species Method Acute dermal toxicity: Value type Value Route of application Exposure time Species Method SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following Toxicity Ecotoxicity: Do not empty into drains / surface water / ground water Persistence and degradability Persistence and Biodegradability: The product is not biodegradable Bioaccumulative potential / Mobility in soil Mobility: Cured adhesives are immobile. Benzene-1,2:4,5- tetracarboxylic dianhydride LogKow Bioconcentration factor (BCF) 2,14 Exposure time Species Temperature Method Results of PBT and vpvb assessment No data available Other adverse effects No data available Waste treatment methods SECTION 13: Disposal considerations

8 Page 8 of 9 Product disposal: Do not empty into drains / surface water / ground water. Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you. SECTION 14: Transport information UN number UN proper shipping name Transport hazard class(es) Packaging group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content < 3 % (1999/13/EC) Chemical safety assessment A chemical safety assessment has not been carried out.

9 Page 9 of 9 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R36 Irritating to eyes. R41 Risk of serious damage to eyes. R42/43 May cause sensitization by inhalation and skin contact. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.