MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Version # Revision date Product Name Manufacturer information DLB DLB040 Friction Material (Asbestos free) Shandong Double Link Brake Material Co., Ltd. No. 8, Haicheng Street, Rushan City, Shandong Province, , China Telephone Number: Attn: Jiaju Geng 2. Hazards Identification Physical state Appearance Emergency overview Greyish solid WARNING Exposure to airborne dust may cause eye, skin and respiratory tract irritation. May cause allergic skin reaction. High concentrations of dust may form explosive mixture with air. Potential health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms Inhalation. Eye contact. Skin contact. Dust may irritate the eyes. Dust may irritate skin. May cause allergic skin reaction. May cause respiratory tract irritation. Dust may irritate throat and respiratory system and cause coughing. May cause discomfort if swallowed. Eyes. Skin. Respiratory system Frequent inhalation of fume/dust over a long period of time increases the risk of developing lung diseases. Upper respiratory tract irritation. Coughing. Irritation of eyes and mucous membranes. Skin irritation. Sensitization. The product components are not classified as environmentally hazardous. However, this does not Potential environmental effects exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. 3. Composition / Information on Ingredients Components Straight Phenolic Resin Asbestos free Cashew nutshell Polymer Asbestos free Synthetic Barium Sulfate Asbestos free, less than 0.1% Crystalline Silica CAS # Percent 15-17% 10-18% 13-16% Glass Fiber Asbestos free % Powder Aluminum Oxide Asbestos free % Synthetic Graphite Asbestos free Calcium Carbonate Asbestos free Calcium Hydroxide Asbestos free % 25-28% 6-9% 4. First Aid Measures First aid procedures Eye contact Skin contact Inhalation Dust in the eyes: Do not rub eyes. Imtely flush with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Get medical attention if irritation develops and persists. Flush skin thoroughly with water. Get medical attention if irritation develops or persists. Move to fresh air. Get medical attention if any discomfort continues. 1/5

2 Ingestion Notes to physician General advice 5. Fire Fighting Measures Flammable properties Rinse mouth thoroughly. Do not induce vomiting without advice from poison control center. Never give anything by mouth to an unconscious person. If ingestion of a large amount does occur, call a poison control center imtely. Get medical attention if any discomfort occurs. Treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. High concentrations of dust may form explosive mixture with air. Extinguishing Suitable extinguishing Unsuitable extinguishing Protection of firefighters Specific hazards arising from the chemical Protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods Foam. Carbon dioxide (CO2). Dry powder. Water fog. None known. During fire, gases hazardous to health may be formed. High concentrations of dust may form explosive mixture with air. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace. Move containers from fire area if you can do it without risk. Cool containers with flooding quantities of water until well after fire is out. Use standard firefighting procedures and consider the hazards of other involved materials. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Other information Ensure adequate ventilation. Avoid inhalation of dust and contact with skin and eyes. Wear suitable protective clothing. See Section 8 of the MSDS for Personal Protective Equipment. Avoid discharge into drains, water courses or onto the ground. Collect spillage. If sweeping of a contaminated area is necessary use a dust suppressant agent which does not react with the product. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in imte area). Collect dust using a vacuum cleaner equipped with HEPA filter. If not possible, moisten dust with water before it is collected with shovel, broom or the like. Avoid dust formation. Clean up in accordance with all applicable regulations. 7. Handling and Storage Handling Storage Provide adequate ventilation. Keep away from heat, sparks and open flame. Avoid inhalation of dust and contact with skin and eyes. Avoid breathing fumes if this product is used at high temperatures. Use only with adequate ventilation. Dust clouds may be explosive under certain conditions. Take precautionary measures against static discharges when there is a risk of dust explosion. To prevent and minimize fire or explosion risk from static accumulation and discharge, effectively bond and/or ground product transfer system. Wear appropriate personal protective equipment. Change contaminated clothing. Wash contaminated clothing before reuse. Observe good industrial hygiene practices. Keep container tightly closed and in a well-ventilated place. Keep away from heat, sparks and open flame. 8. Exposure Controls / Personal Protection Occupational exposure limits Synthetic Barium Sulfate Powder Aluminum Oxide Synthetic Graphite Calcium Carbonate Calcium Hydroxide Engineering controls Personal protective equipment Eye / face protection Skin protection Respiratory protection ACGIH: 5 mg/m3 TWA (inhalable fraction, particulate matter containing no asbestos and < 1% crystalline silica) OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) OSHA: 15 mg/ m3 TWA (total dust); 5 mg/ m3 TWA (respirable fraction) ACGIH: 2 mg/m3 TWA (all forms except graphite fibers, respirable fraction) OSHA: 15 mg/m3 TWA (synthetic, total dust); 5 mg/m3 TWA (synthetic, respirable fraction) ACGIH: 15 mg/ m3 TWA (total dust); 5 mg/ m3 TWA (respirable fraction) ACGIH: 5 mg/m3 TWA OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Ventilate as needed to control airborne dust. Use explosion-proof ventilation equipment if airborne dust levels are high. Wear dust-resistant safety goggles where there is danger of eye contact. Wear protective gloves. Rubber gloves are recommended. Wear appropriate chemical resistant clothing to prevent any possibility of skin contact. In case of inadequate ventilation or risk of inhalation of dust, use suitable respiratory equipment with particle filter. 2/5

3 General hygiene considerations Do not breathe dust. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical & Chemical Properties Appearance Color Odor Odor threshold Physical state Form ph Melting point Freezing point Boiling point Flash point Grey solid Grey None 11 Evaporation rate Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Vapor density Specific gravity 1.83 ( Water = 1) Solubility (water) Insoluble in water. Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Percent volatile Not available 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions 11. Toxicological Information Acute effects Local effects Sensitization Chronic effects Carcinogenicity Epidemiology Mutagenicity Reproductive effects Material is stable under normal conditions. Heat, sparks, and flames. None known. Carbon oxides. Will not occur. May cause discomfort if swallowed. Dusts may irritate the respiratory tract, skin and eyes. May cause allergic skin reaction. Can cause sensitization to individuals allergic to the Rhus-family of plants ( Anacardiaceae). Frequent inhalation of dust over a long period of time increases the risk of developing lung diseases. Not classified. 3/5

4 Symptoms and target organs Further information 12. Ecological Information Ecotoxicity Environmental effects Persistence and degradability Bioaccumulation / Accumulation Partition coefficient (n-octanol/water) Mobility in environmental Sensitization. Upper respiratory tract irritation. Coughing. Irritation of eyes and mucous membranes. Skin irritation. No other specific acute or chronic health impact noted. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. The product is insoluble in water. 13. Disposal Considerations Waste codes Disposal instructions Waste from residues / unused products Contaminated packaging 14. Transport Information DOT IATA IMDG TDG Not regulated. This material and/or its container must be disposed of as hazardous waste. Avoid discharge into water courses or onto the ground. Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Dispose of in accordance with local regulations. Waste is suitable for incineration. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 15. Regulatory Information US federal regulations The product is considered manufactured articles and are exempt under OSHA s Hazard Communication Standard 29 CFR All components are on the U.S. EPA TSCA Inventory List. CERCLA (Superfund) reportable quantity (lbs) None Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Imte Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Section 302 extremely No hazardous substance Section 311 hazardous Yes chemical Drug Enforcement Agency Not controlled (DEA) 4/5

5 Canadian regulations WHMIS status This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Not Controlled Inventory status Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information Recommended restrictions Further information HMIS ratings HMIS is a registered trade and service mark of the NPCA. F - Safety Glasses, Gloves, Apron, Dust Respirator Not Applicable NFPA ratings Not Applicable Disclaimer Issue date To the best of our knowledge, the information contained herein is accurate. However no warranty, guarantee or representation is made as to its accuracy, reliability or completeness. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability to assure proper use, disposal, and safety of these materials /5