Safety Data Sheet in accordance with Regulation (EC) No. 1907/2006

Transcription

1 Page: 1 / 7 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND THE COMPANY/UNDERTAKING 1.1 Product identifier Trade name Substance/mixture Gasket maker no odor Mixture 1.2 Relevant identified uses of the substance/mixture and inadvisable uses Identified uses: Sealer 1.3 Details of the supplier of the Supplier: Kidričeva cesta 97 SI4220 Škofja Loka Telephone: Telephone: address of the person responsible for drawing up the : info@zolleks.si 1.4 Emergency telephone number Emergency call Slovenia: HAZARD IDENTIFICATION 2.1 Classification of the substance/mixture Classification in accordance with Regulation EC No. 1272/2008 Skin Sens.1B; H317 Eye Irrit. 2; H319 For the full text of the Hstatements mentioned in this Section, see Section Label elements Classification in accordance with Regulation EC No. 1272/2008 Pictogram: Signal word: Caution Hazard statements: H317 May cause an allergic skin reaction.

2 Page: 2 / 7 H319 Causes serious eye irritation. Contains: Vinyltri(methylethylketoxime)silane Precautionary statements: P102 Keep out of reach of children. P280 Wear protective gloves/eye protection/face protection Other hazards None. 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures Chemical Name Dimethylsiloxane, hydroxy terminated Calcium carbonate Garnet nonhazardous Vinyltri(methylethylket oxime)silane Silica amorphous, fumed, hydrophobic CAS ES Index REACH Reg. No. Content in % 4050% 2040% 2040% 1<10% 110% Classification (Regulation EC No. 1272/2008) Skin Sens.1B; H317 Eye Dam. 1; H318 STOT RE H373 For the full text of the Rphrases mentioned in this Section, see Section 16. For the full text of the Hstatements mentioned in this Section, see Section FIRST AID MEASURES 4.1 Description of firstaid measures Inhalation Skin contact Eye contact Ingestion Move affected person to fresh air. If symptoms persist, seek medical advice. Remove contaminated clothing. Wash skin thoroughly with soap and water. If irritation persists, seek medical advice. Wash clothing before the next use. Immediately wash the eyes with plenty of water for at least 15 minutes. Wash the eyelids as well. Remove contact lenses, if present and easy to do. Continue rinsing. If irritation persists, seek medical advice. Do not induce vomiting, seek medical attention. Rinse mouth with water and let the injured person rest. 4.2 Most important symptoms and effects, both acute and delayed

3 Page: 3 / Indication of immediate medical attention and special treatment needed, if necessary Treat symptomatically. 5. FIREFIGHTING MEASURES 5.1 Extinguishing agents Suitable extinguishing agents Water fog, carbon dioxide, powder. Unsuitable extinguishing agents Direct water stream. 5.2 Special hazards arising from the substance or mixture Special hazards Keep containers cool with water spray. Burning causes release of: carbon oxides, nitrogen oxides, methylethyl ketone; possible even methyl ethyl ketoxime, silica fume, formaldehyde. 5.3 Advice for firefighters Special protective equipment for firefighters Wear selfcontained breathing apparatus that is independent of the ambient atmosphere and protective clothing. 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment (see Section 8). 6.2 Environmental precautions Prevent the substance from leaking into the water courses or drains. 6.3 Cleaning up methods, materials and retention Blot or scrape up spill in a well ventilated area and let it dry until it turns into rubber. Dispose in accordance with description in Section 13. Clean the floor thoroughly making certain the floor is free from residues that can cause slipping. 6.4 Reference to other sections Personal protective equipment See Section 8. Waste management See Section HANDLING AND STORAGE 7.1 Precautions for safe handling

4 Page: 4 / 7 Advice for safe handling Keep out of the reach of children. Avoid contact with eyes and skin. Wash hands before eating and smoking. 7.2 Conditions for a safe storage, including any incompatibilities Technical measures/storage conditions Keep container tightly closed, away from moisture or water, in a cool and wellventilated place. 7.3 Specific end uses 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters Occupational exposure limit values for ingredients: Source: Rules on the protection of workers from the risks related to exposure to chemical substances at work (OG RS No. 102/2010) 8.2 Exposure controls Engineering controls Use only in wellventilated areas. In confined spaces use general ventilation or local suction system. Personal protective equipment Product may emit formaldehyde vapours at temperatures above 148,88 o C (300 o F) in the presence of air. Formaldehyde is potentially carcinogenic and known to cause respiratory and skin sensitisation. For safe handling it is advised to keep the concentration of formaldehyde vapours below the permissible limit. General information Respiratory protection Hand protection Eye protection Avoid contact with eyes, skin and clothing. When using this product do not eat, drink or smoke. Immediately remove contaminated, soaked clothing. Wash hands before break and at the end of work. The product should be handled using good hygienic and working practices. In case of insufficient ventilation wear suitable mask with filter of organic product vapours. Use of neoprene or nitrile protective gloves is recommended. Recommended material of safety gloves: fluoroelastomer (viton), nitrile rubber, polyethylene/ethylene vinyl alcohol. Safety glasses. Skin and body protection Work clothing Environmental exposure controls General information Not determined.

5 Page: 5 / 7 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance Paste Colour Distinctive Odour Acidic ph No information available Flash point No information available Boiling point No information available Vapour pressure <5 mm 80 F Specific weight (water = 1) 0.95~1.05 Vapour density 3.0 Evaporation rate Not determined Water solubility Polymerises VOC <4% 9.2 Other information 10. STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical stability Product is stable under normal use conditions Possibility of hazardous reactions Polymerises in contact with moisture, strong oxidizing agents, acids, iron Conditions to avoid Exposure to moisture Incompatible materials Polymerises in contact with moisture, strong oxidizing agents, acids, iron Hazardous decomposition products Carbon oxides, nitrogen oxides, methylethyl ketone; possible even methyl ethyl ketoxime, silica fume, formaldehyde. 11. TOXICOLOGICAL INFORMATION (a) Acute toxicity (b) Irritation (c) Corrosivity (d) Sensitisation (e) Repeat dose toxicity (f) Carcinogenicity (g) Mutagenicity (h) Toxicity for reproduction Causes serious eye irritation. May cause an allergic skin reaction.

6 Page: 6 / ECOLOGICAL INFORMATION 12.1 Toxicity 12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects 13. DISPOSAL CONSIDERATIONS 13.1 Waste management methods Contaminated packaging: Packaging is not reusable. Packaging must be disposed at an authorised collector and disposer of hazardous waste. National regulations regarding waste: Decree on waste Decree on the management of packaging and packaging waste 14. TRANSPORT INFORMATION The product is not classified as dangerous goods according to regulations on transport of hazardous substances. 15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture European Union Regulation 1907/2006 (REACH), Directive 67/548/EEC and 1999/45/EC Regulations in Slovenia Chemicals Act Rules on the classification, packaging and labelling of dangerous substances Rules on the classification, packaging and labelling of dangerous preparations Decree on waste Decree on the management of packaging and packaging waste Rules on the protection of workers from the risks related to exposure to chemical substances at work Rules on personal protective equipment used by workers at work 15.2 Chemical safety assessment Chemical safety assessment has not been made. 16. OTHER INFORMATION 16.1 Source of the : Composition of the product, manufacturer's safety

7 Page: 7 / 7 data sheet (10/09/2010) and additional information List of relevant hazard statements and/or precautionary statements H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H373 May cause damage to organs (state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) Date of previous issue: 16.4 Abbreviations: TWA (timeweighted average): daily exposure limit value (8 h) STEL (shortterm exposure limits): limit value for shortterm exposure REACH Registration, Evaluation, Authorisation and Restriction of Chemicals MV: occupational exposure limit value 8 h The above information is based on our present knowledge and experience and relates to the product in the state in which it has been delivered. The information is to describe our product regarding safety requirements. Entries do not constitute a guarantee of the product properties in the legal sense. It is the consumer's responsibility to know and take into account the legal provisions relating to the transport and use of the product. End of the