SAFETY DATA SHEET NEWV LAC FOIL BLOCKABLE GLOSS VARNISH
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1 Revision Date 24/02/12 Revision 2 Supersedes date issued 26/10/09 no SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. UC Relevant identified uses of the substance or mixture and uses advised against Identified uses UV Curing Lacquer 1.3. Details of the supplier of the safety data sheet Supplier 1.4. Emergency telephone number SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture STEHLIN HOSTAG INK UK LTD UNIT D4 LINKMEL CLOSE QUEENS DRIVE INDUSTRIAL ESTATE NOTTINGHAM NG2 1NA Tel : Fax : sds@stehlin.co.uk Classification (EC 1272/2008) Classification (1999/45/EEC) Physical and Chemical Hazards Human health Environment Xi;R36/38. R43. R52/53. Not classified. Skin Irrit. 2 - H315;Eye Irrit. 2 - H319;Skin Sens. 1 - H317 Aquatic Chronic 3 - H412 Human health The product is irritating to eyes and skin. May cause sensitisation by skin contact Environment The product contains a substance which is harmful to aquatic organisms and which may cause long term adverse effects in the aquatic environment Label elements Contains TPGDA Label In Accordance With (EC) No. 1272/2008 Signal Word Hazard Statements Warning H315 H317 H319 H412 Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Harmful to aquatic life with long lasting effects. 1 / 6
2 Precautionary Statements P280 Supplementary Precautionary Statements 2.3. Other hazards Wear protective gloves/protective clothing/eye protection/face protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P IF ON SKIN: Wash with plenty of soap and water. P IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P313 Get medical advice/attention. P321 Specific treatment (see on this label). P If skin irritation occurs: Get medical advice/attention. P If skin irritation or rash occurs: Get medical advice/attention. P337 If eye irritation persists: P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P501 Dispose of contents/container to SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures Glycerol Propoxy Triacrylate <80% CAS-No.: EC No.: Classification (EC 1272/2008) Eye Irrit. 2 - H319 Classification (67/548/EEC) Xi;R36. TPGDA <30% CAS-No.: EC No.: Classification (EC 1272/2008) Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 STOT Single 3 - H335 Aquatic Chronic 2 - H411 Classification (67/548/EEC) Xi;R36/37/38. N;R51/53. R43. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor Ingestion Wash out mouth with water Consult a doctor. Skin contact Remove all contaminated clothes and footwear immediately, unless stuck to skin. Wash immediately with plenty of water and soap and rinse thoroughly. Eye contact Bathe the eye with running water for 15 minutes Consult a doctor Most important symptoms and effects, both acute and delayed General information Immediate effects can be expected after short-term exposure. 2 / 6
3 Inhalation. There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing. Ingestion There may be soreness and redness of the mouth and throat. Skin contact There may be irritation and redness at the site of contact. Eye contact There may be irritation and redness. The eyes may water profusely Indication of any immediate medical attention and special treatment needed Eye bathing equipment should be available on the premises. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers Special hazards arising from the substance or mixture Hazardous combustion products In combustion emits toxic fumes Advice for firefighters Protective equipment for fire-figthers Wear self contained breathing apparatus. Wear Protective clothing to prevent contact with skin and eyes. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Refer to section 8 of SDS for personal protection details. If outside do not approach from downwind. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised peronnel. Turn leaking containers leak side up to prevent the escape of liquid Environmental precautions Do not discharge into drains or rivers. Contain the spillage using bunding Methods and material for containment and cleaning up Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method Reference to other sections See section 7 for information on safe Handling. See section 8 for information on personal protective equipment. See section 13 for disposal information. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air Conditions for safe storage, including any incompatibilities Store in cool, well ventilated area. Keep container tightly closed. It is recommended to store in original packaging Specific end use(s) UV light curing varnish for professional use in pressrooms only. STD SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Not Applicable 8.1. Control parameters 8.2. Exposure controls Engineering measures Ensure thers is sufficient ventilation of the area. Respiratory equipment Self-contained breathing apparatus must be available in case of emergency. 3 / 6
4 Hand protection Wear Nitrile gloves of minimum thickness 0.5mm. Gloves should be replaced regularly or if any change in appearance is noticed. Ensure gloves are manufactured in accordance with BS EN 374. Penetration times carried out according to EN 34 part III are not always practicable, therefore maximum wearing time of 50% of penetration time is recommended. Eye protection Safety glasses with side-shields. Ensure eye bath is to hand. Skin protection Protective clothing should be worn. Environmental Exposure Controls An environmental assessment must be made to ensure compliance with local environmental legislation. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Colour Odour Solubility Flash point ( C) 9.2. Other information Liquid Pale yellow Typical Acrylate Insoluble in water >100 CC (Closed cup). Not applicable SECTION 10: STABILITY AND REACTIVITY Reactivity Stable under recommended transport or storage conditions Chemical stability Stable under normal conditions Possibility of hazardous reactions Hazardous reactions will not occur under normal transport or storage conditions Conditions to avoid Avoid heat. Direct sunlight Incompatible materials Materials To Avoid Strong oxidising agents, strong acids Hazardous decomposition products In combustions emits toxic fumes SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Inhalation Effect: Irritation Route: OPT DRM Basis: Hazardous:Calculated Route: DRM Basis: Hazardous: Calculated There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing. Ingestion There may be soreness and redness of the mouth and throat. Skin contact There may be irritation and redness at the site of contact Eye contact There may be irritation and redness The eyes may water profusely. Specific effects Immediate effects can be expected after short-term exposure SECTION 12: ECOLOGICAL INFORMATION Toxicity Persistence and degradability 4 / 6
5 Degradability There are no data on the degradability of this product Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation Mobility in soil Mobility: Heavier than water Results of PBT and vpvb assessment This substance is not identified at a PBT substance Other adverse effects Harmful to aquatic organisms. Harmful to soil organisms. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Transfer to a suitable container and arrange for collection by specialised disposal company. NB: The user's attention is drawn to the possible existence of regional and antional regulations regarding disposal. SECTION 14: TRANSPORT INFORMATION General UN number This product is not classified for transport UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments Chemical Safety Assessment A chemical safety assessment has not been carried out for the substance or the mixure by the supplier SECTION 16: OTHER INFORMATION General information This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010 Revision Comments Converted to GHS format Issued By Revision Date 24/02/12 Revision 2 B.A Hayden HSQE Manager Supersedes date issued 26/10/09 no SDS No Safety Data Sheet Status Approved. 5 / 6
6 Date 28/02/12 Risk Phrases In Full R36/37/38 R36 R43 R51/53 Hazard Statements In Full H319 H315 H317 H335 H411 Irritating to eyes, respiratory system and skin. Irritating to eyes. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction. May cause respiratory irritation. Toxic to aquatic life with long lasting effects. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6 / 6
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