SAFETY DATA SHEET UV LAMINATION ADHESIVE

Transcription

1 Revision Date 06/12/2012 Revision 1 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. 40UC Relevant identified uses of the substance or mixture and uses advised against Identified uses UV Curing Varnish 1.3. Details of the supplier of the safety data sheet Supplier STEHLIN HOSTAG INK UK LTD UNIT D4 LINKMEL CLOSE QUEENS DRIVE INDUSTRIAL ESTATE NOTTINGHAM NG2 1NA Tel : Fax : sds@stehlin.co.uk 1.4. Emergency telephone number SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Physical and Chemical Hazards Human health Environment Classification (1999/45/EEC) Xi;R36/37/38. R43. Not classified. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section Label elements Label In Accordance With (EC) No. 1272/2008 Skin Irrit. 2 - H315;;Skin Sens. 1 - H317;STOT SE 3 - H335 Not classified. Signal Word Warning Hazard Statements H315 H317 H319 H335 Supplementary Precautionary Statements P261 P271 Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. 1 / 6

2 2.3. Other hazards P280 Wear protective gloves/protective clothing/eye protection/face protection. P IF ON SKIN: Gently wash with plenty of soap and water. P IF ON SKIN: Wash with plenty of soap and water. P IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P313 Get medical advice/attention. P If skin irritation occurs: Get medical advice/attention. P337 If eye irritation persists: P362 Take off contaminated clothing and wash before reuse. P Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container to SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 2,2-BIS(ACRYLOYLOXYMETHYL)BUTYL ACRYLATE <80% CAS-No.: EC No.: Skin Irrit. 2 - H315 Skin Sens. 1 - H317 R43 Xi;R36/38 Polyester Acrylate 10-15% Skin Irrit. 2 - H315 STOT SE 3 - H335 Xi;R36/37/38. Acrylated Oligomer 7-10% CAS-No.: EC No.: Skin Irrit. 2 - H315 STOT SE 3 - H335 Xi;R36/37/38. 2 / 6

3 1-Hydroxycyclohexylphenylketone 7-10% CAS-No.: EC No.: Xi;R36. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General information Get medical attention if any discomfort continues. Inhalation Remove victim to fresh air. Ingestion Immediately rinse mouth and drink plenty of water ( ml). Skin contact Remove contaminated clothing and shoes. Wash skin thoroughly with mild soap and water. Seek medical advice. Get medical attention if irritation persists after washing. Eye contact In case of contact with eyes, rinse immediately with plenty of water and seek medical advice Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous combustion products In case of fire, toxic gases (CO, CO2, NOx) may be formed Advice for firefighters Protective equipment for fire-fighters Use pressurised air mask if product is involved in fire. Water spray should be used to cool containers. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Do not smoke, use open fire or other sources of ignition Environmental precautions Do not discharge onto the ground or into water courses Methods and material for containment and cleaning up Absorb spillage with suitable absorbent material. Transfer to a container for disposal Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. SECTION 7: HANDLING AND STORAGE 3 / 6

4 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry and cool place. Protect from freezing and direct sunlight. Keep away from heat, sparks and open flame. Keep away from food, drink and animal feeding stuffs. <+35C 7.3. Specific end use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters 8.2. Exposure controls Engineering measures Provide adequate ventilation. Respiratory equipment Wear suitable respiratory protection. Hand protection Nitrile gloves are recommended. Eye protection Wear tight-fitting goggles or face shield. Skin protection Wear suitable protective clothing where prolonged contact is likely. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Liquid Colour Clear Pale yellow Odour Characteristic. Solubility Insoluble in water Relative density 25 Viscosity mpas 32 Flash point > P/M Pensky-Martens Other information SECTION 10: STABILITY AND REACTIVITY Reactivity Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Hazardous Polymerisation May polymerise Conditions to avoid Avoid radical forming substances (metal-ions), peroxides Incompatible materials Materials To Avoid Strong acids. Strong alkalis. Amines. Organic peroxides/hydroperoxides Hazardous decomposition products SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects 4 / 6

5 Toxic Dose 1 - LD 50 >2000mg/kg bodyweight Toxicological information on ingredients. 2,2-BIS(ACRYLOYLOXYMETHYL)BUTYL ACRYLATE (CAS: ) Acrylated Oligomer (CAS: ) SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity There are no data on the ecotoxicity of this product Toxicity Not applicable Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment The components in this formulation do not meet the criteria for classification as PBT or vpvb Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION General Not classified according to transport regulations for dangerous goods UN number UN proper shipping name Not applicable Transport hazard class(es) No information required Packing group Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture 5 / 6

6 Water hazard classification WGK Chemical Safety Assessment SECTION 16: OTHER INFORMATION Revision Comments This is first issue. Issued By Revision Date 06/12/2012 Revision 1 Safety Data Sheet Status B.A Hayden (CMIOSH) Chartered Safety & Health Practitioner Approved. Date issued: Risk Phrases In Full R36/38 R36/37/38 R36 R43 Hazard Statements In Full H319 H315 H317 H335 Irritating to eyes and skin. Irritating to eyes, respiratory system and skin. Irritating to eyes. May cause sensitisation by skin contact. Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction. May cause respiratory irritation. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6 / 6