QUIK FILL 86 D-LIMONENE DEGREASER. Use only for the purpose on the product label.

Transcription

1 SAFETY DATA SHEET QUIK FILL 86 D-LIMONENE DEGREASER Section 1. Chemical product and company identification Product name Recommended use and restrictions QUIK FILL 86 D-LIMONENE DEGREASER Cleaning product Use only for the purpose on the product label. Product dilution information Up to 16.6 oz/gal or 13 ml/l in water Supplier's information Code Date of issue Section 2. Hazards identification GHS Classification GHS label elements Ecolab Inc. Institutional Division 37 N. Wabasha Street St. Paul, MN Oct 213 EMERGENCY HEALTH INFORMATION Outside United States and Canada CALL (in USA) SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 Signal word Symbol Warning Warning Hazard statements Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction. Precautionary statements Prevention Response Storage Disposal Wear protective gloves. Wear eye or face protection. Avoid breathing vapor. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. IF ON SKIN Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation or rash occurs Get medical attention. IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists Get medical attention. No other specific measures identified. May cause an allergic skin reaction. Wear protective gloves. Avoid breathing vapor. Contaminated work clothing should not be allowed out of the workplace. IF ON SKIN Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation or rash occurs Get medical attention. No other specific measures identified. Page 1/7

2 QUIK FILL 86 D-LIMONENE DEGREASER 11 Oct 213 Section 2. Hazards identification Other hazards See section 13 for waste disposal information. None known. See section 13 for waste disposal information. None known. Section 3. Composition/information on ingredients Substance/mixture Hazardous ingredients Mixture Concentration Range (%) CAS number POTASSIUM HYDROXIDE < alcohols, c12-16, ethoxylated cyclohexene-1-octanoic acid, 5(or 6)-carboxy-4-hexyl-, potassium salt Limonene TRIETHANOLAMINE Hazardous ingredients Concentration Range (%) CAS number Limonene < Section 4. First aid measures Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation persists. Skin contact Take off contaminated clothing. Wash with plenty of soap and water. If skin irritation or rash occurs Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Inhalation No special measures required. Treat symptomatically. Ingestion Get medical attention if symptoms occur. No known effect after eye contact. Rinse with water for a few minutes. Wash with plenty of soap and water. If skin irritation or rash occurs Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. No special measures required. Treat symptomatically. Get medical attention if symptoms occur. Protection of firstaiders No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. See toxicological information (section 11) Section 5. Fire-fighting measures Suitable fire extinguishing media Specific hazards arising from the chemical Hazardous thermal decomposition products Use water spray, fog or foam. In a fire or if heated, a pressure increase will occur and the container may burst. Page 2/7

3 QUIK FILL 86 D-LIMONENE DEGREASER 11 Oct 213 Section 5. Fire-fighting measures Specific fire-fighting methods Special protective equipment for fire-fighters Personal precautions Environmental precautions Methods for cleaning up Section 6. Accidental release measures Handling Storage Decomposition products may include the following materials carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Use personal protective equipment as required. Avoid contact of large amounts of spilled material and runoff with soil and surface waterways. Use a water rinse for final clean-up. Section 7. Handling and storage Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep out of reach of children. Keep container tightly closed. Store between the following temperatures 1 and 3 C Section 8. Exposure controls/personal protection Control parameters Ingredient name Use personal protective equipment as required. Avoid contact of large amounts of spilled material and runoff with soil and surface waterways. Use a water rinse for final clean-up. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep out of reach of children. Exposure limits Limonene AIHA WEEL (United States, 5/21). TWA 3 ppm 8 hours. TRIETHANOLAMINE ACGIH TLV (United States, 3/212). TWA 5 mg/m³ 8 hours. POTASSIUM HYDROXIDE ACGIH TLV (United States, 3/212). C 2 mg/m³ NIOSH REL (United States, 6/29). TWA 2 mg/m³ 1 hours. Appropriate engineering controls Personal protection Eye protection Hand protection Skin protection Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wear eye protection. Use chemical-resistant, impervious gloves. Use suitable protective equipment. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. No protective equipment is needed under normal use conditions. Use chemical-resistant, impervious gloves. Use suitable protective equipment. Page 3/7

4 QUIK FILL 86 D-LIMONENE DEGREASER 11 Oct 213 Section 8. Exposure controls/personal protection Respiratory protection Hygiene measures Physical state Color Odor ph Flash point Melting point Boiling point Evaporation rate (butyl acetate = 1) Vapor pressure Vapor density Relative density Solubility Partition coefficient n-octanol/water Auto-ignition temperature A respirator is not needed under normal and intended conditions of product use. A respirator is not needed under normal and intended conditions of product use. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Section 9. Physical and chemical properties Explosion limits (solid, gas) Liquid. Yellow citrus 9 to 1 (1%) > 1 C Product does not support combustion. 1.4 to 1.24 (Water = 1) Decomposition temperature Odor threshold Viscosity Dynamic (room temperature) 1 mpa s (1 cp) Section 1. Stability and reactivity Stability Possibility of hazardous reactions Hazardous decomposition products Liquid. Colorless to light yellow citrus 8 to 9.5 > 1 C Conditions to avoid No specific data. Materials to avoid Reactive or incompatible with the following materials acids. The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Page 4/7

5 QUIK FILL 86 D-LIMONENE DEGREASER 11 Oct 213 Section 11. Toxicological information Route of exposure Skin contact Inhalation Ingestion Toxicity data Product/ingredient name alcohols, c12-16, ethoxylated LD5 Dermal Rabbit >2 mg/kg LD5 Oral Rat 11 mg/kg 2-cyclohexene-1-octanoic acid, 5(or 6)- LD5 Oral Rat >6 mg/kg carboxy-4-hexyl-, potassium salt (r)-p-mentha-1,8-diene LD5 Dermal Rabbit >5 mg/kg LD5 Oral Rat 44 mg/kg triethanolamine LD5 Dermal Rabbit >2 mg/kg LD5 Oral Rat 64 mg/kg Chronic toxicity Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Skin contact, Eye contact, Inhalation, Ingestion Symptoms Eye contact Adverse symptoms may include the following pain or irritation watering redness Skin contact Adverse symptoms may include the following irritation redness Inhalation No specific data. Ingestion No specific data. Acute toxicity Eye contact Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction. Section 12. Ecological information No specific data. Adverse symptoms may include the following irritation redness No specific data. No specific data. No known significant effects or critical hazards. May cause an allergic skin reaction. No known significant effects or critical hazards. No known significant effects or critical hazards. Ecotoxicity This material is toxic to aquatic life. This material is harmful to aquatic life with long lasting effects. Aquatic and terrestrial toxicity Product/ingredient name Result Species Exposure alcohols, c12-16, ethoxylated Acute LC5 1.5 mg/l Fish 96 hours 2-cyclohexene-1-octanoic acid, 5(or 6)- Acute LC5 15 mg/l Fish 96 hours carboxy-4-hexyl-, potassium salt triethanolamine Acute LC5 118 mg/l Fish 96 hours potassium hydroxide Acute LC5 8 mg/l Fish 96 hours Other adverse effects Page 5/7

6 QUIK FILL 86 D-LIMONENE DEGREASER 11 Oct 213 Section 13. Disposal considerations Disposal methods Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Section 14. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. DOT DOT Classification IMO/IMDG IMO/IMDG Classification IMO/IMDG Proper shipping name Class Packing group Not intended for transport. Not regulated. UN382 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ((r)-pmentha-1,8-diene). Marine pollutant 9 III For transport in bulk, see shipping documents for specific transportation information. Section 15. Regulatory information U.S. Federal regulations TSCA 8(b) inventory All components are listed or exempted. SARA 32/34/311/312 extremely hazardous substances No listed substance SARA 32/34 emergency planning and notification No listed substance SARA 313 Product name CAS number Concentration Form R - Reporting requirements California Prop. 65 No listed substance No listed substance Section 16. Other information Hazardous Material Information System (U.S.A.) Health Physical hazards * 2 Health Physical hazards 2 National Fire Protection Association (U.S.A.) Page 6/7

7 QUIK FILL 86 D-LIMONENE DEGREASER 11 Oct 213 Section 16. Other information Health 2 Instability/Reactivity Health 2 Instability/Reactivity Special Special Date of issue Prepared by 11 Oct 213 Regulatory Affairs Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Page 7/7