DENTSPLY International Safety Data Sheet [SDS] Form 0280-FM Rev 6

Transcription

1 DENTSPLY International Safety Data Sheet [SDS] Form 0280-FM Rev 6 Date Issued: 9/15/14 Date Revised: 9/15/14 Revision Number: 1 Product Identifier [Part/Item Number(s)]: , , , Trade Name (as labeled): 1. PRODUCT IDENTIFICATION NEOBOND Adhesive Syringe IDEAL 1 Adhesive Chemical Name/Classification: U.N. Number: U.N. Dangerous Goods Classification: Recommended Use: Restrictions on Use: Manufacturer/Supplier Name: Urethane Diacrylate Oligomer Polymerization accelerators Triethylenglycoldimethacrylate 2-Hydroxyethylmethacrylate Photoinitiators Barium aluminoborosilicate glass Fumed Silica None None Professional Dental Use None DENTSPLY GAC Manufacturer/Supplier Address: One CA Plaza, Suite 100 Islandia, NY Manufacturer/Supplier Telephone Number: Emergency Contact Telephone Number: address: gac.info@dentsply.com 2. HAZARD(s) IDENTIFICATION Hazard/Danger Classification: Health Environmental Physical Irritant Not considered hazardous Irritant Associated Hazards: Hazard Statements Irritating to eyes, Irritating to skin, Irritating to respiratory system Signal Word Irritant Precautionary Statements Signs and Symptoms of Exposure: High concentrations can cause eye and respiratory irritation. Prolonged skin exposure can cause dryness.

2 EU Classification: EU Risk (R) and Safety (S) Phrases: 3. COMPOSITION AND INFORMATION ON INGREDIENTS 4. FIRST-AID MEASURES Routes of Exposure Eye Skin Inhalation First Aid Instructions Flush with large quantities of water for 15 minutes. Consult a physician. Wash with soap and water. If irritation occurs, take victim to open air. Ingestion Most important symptoms of exposure Other Consult a physician Irritation If irritation occurs, take victim to open air. Note to Physicians (Treatment, Testing, and Monitoring) 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Fire Fighting Procedures: Carbon dioxide, water spray, dry chemical. Avoid a direct jet of water.

3 Specific Hazards Arising from the Chemical: Precautions for Fire Fighters: None. None. Recommended Protective Equipment for Fire Fighters: EYES/FACE SKIN RESPRIATORY THERMAL 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, PPE and Emergency Procedures: Avoid unnecessary skin contact. Wear latex gloves when handling. Remove spilled material from skin and clothing. Do not eat or drink when handling this material. Environmental Precautions: Avoid seepage into sewers and water supplies. Methods and Materials for Containment and Clean-up: Contain spill and pick up material with a suitable absorbent material. Place absorbent into a container for later disposal. Clean spill area with detergent and water. Recommended Personal Protective Equipment for Containment and Clean-up: EYES/FACE SKIN RESPRIATORY THERMAL 7. HANDLING AND STORAGE Precautions for Safe Handing: No special measures necessary if handled according to instructions. Conditions for Safe Storage: Keep container tightly closed when not in use. Store in a cool, dry location, away from light, open flames, contamination. Keep material in original packaging. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: Biological Exposure Limits:

4 Appropriate Engineering Controls: Individual Protection Measures (PPE) Specific Eye/face Protection: Avoid unnecessary skin contact. Specific Skin Protection: Avoid unnecessary skin contact. Wear latex gloves when handling. Specific Respiratory Protection:. Specific Thermal Hazards: unknown Recommended Personal Protective Equipment EYES/FACE SKIN RESPRIATORY THERMAL Environmental Exposure Controls: Use only in well ventilated areas. General Hygiene Considerations and Work Practices: Remove spilled material from skin and clothing. Do not eat or drink when handling this material. Protective Measures During Repair and Maintenance of Contaminated Equipment: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Light yellow paste. Explosive limits: Odor: Specific odor Vapor pressure: Odor threshold: Vapor density: ph: Relative density: Melting/freezing point: Solubility: Insoluble Initial boiling point and range: Flash point: Evaporation rate: Flammability: Partition coefficient: n- octanol/water: Auto-ignition temperature: Decomposition temperature: Viscosity: Explosive Properties: Oxidizing Properties: 10. Stability and Reactivity Reactivity::

5 Chemical Stability: This material is stable Possibility of Hazardous Reactions: None if handled according to directions Conditions to Avoid: Heat; UV-light Incompatible materials: Free radicals, reducing agents, heavy metal ions. Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, acrylic decomposition products, depending on 11. TOXICOLOGICAL INFORMATION Potential Health Effects: Eyes: Irritation Skin: Dryness and Irritation possible upon prolonged exposure. Ingestion: Inhalation: Irritation Chronic Health Effects: Carcinogenicity: Mutagenicity: Medical Conditions Aggravated by Exposure: Methacrylate sensitive individuals may exhibit an allergic reaction. Acute Toxicity Data: LD50 (rat) > 5000 mg/kg Reproductive Toxicity Data: Specific Target Organ Toxicity (STOT): Single Exposure: Repeated Exposure: 12. ECOLOGICAL INFORMATION Toxicity: No data available. Persistence and Degradability: No data available. Bio-accumulative Potential: Mobility in Soil: Other Adverse Effects: Do not discharge into suvers or water supplies. Results of PBT/vPvB Assessment:

6 13. DISPOSAL CONSIDERATIONS Regulations: May be disposed of in landfill or incinerator In accordance with local, state and federal regulations. Properties (Physical/Chemical) Affecting Disposal: Waste Treatment Recommendations: May be disposed of in landfill or incinerator In accordance with local, state and federal regulations. 14. TRANSPORT INFORMATION UN Identification Number: Not Regulated UN Proper Shipping Name: Not Regulated Transport hazard class(es): N/A Packing Group: None Special precautions for user: Not considered hazardous cargo U.S. Federal Regulations 15. REGULATORY INFORMATION Comprehensive Environmental Response and Liability Act of 1980 (CERCLA): This material is not hazardous under the criteria of the U.S. Federal Hazard Communication Standard Toxic Substances Control Act (TSCA): Clean Water Act (CWA): Clean Air Act (CAA): Superfund Amendments and Reauthorization Act (SARA) Title III Information: SARA Section 311/312 (40 CFR 370) Hazard Categories: T Immediate Hazard: Pressure Hazard: Delayed Hazard: Reactivity Hazard: Fire Hazard: This product contains the following toxic chemical(s) subject to reporting requirements of SARA Section 313 (40 CFR 372): Components C.A.S. # WT % Other Information: Risk phases: R: 36,37/38, Harmful if swallowed. 36 Irritating to eyes. 37/38 Irritating to respiratory system and skin. 43 may cause sensitization by skin contact. Safety phases: S:2,9,16,23,26,28,24/25,37/39 2 Keep out of the reach of children. 9 Keep container in a well-ventilated place. 16 Keep away from sources of ignition- no smoking. 23 Do not breathe vapour. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 28 After contact with skin, wash immediately with plenty of water and soap. 24/25 Avoid contact with skin and eyes. 37/39 Wear suitable gloves and eyes/face protection.

7 State Regulations California Proposition 65: This product contains the following chemicals(s) known to the State of California to cause cancer, birth defects or reproductive harm (if blank, the product does not contain Proposition 65 regulated chemicals): This product does not contain any chemicals, which are on the California Proposition 65 list. Components C.A.S. # WT % International Regulations Canadian Environmental Protection Act: Canadian Workplace Hazardous Materials Information System (WHMIS): European Inventory of Existing Chemicals (EINECS): European Chemical Agency (ECHA) REACH (Registration, Evaluation, Authorization and Restriction of Chemicals): 16. OTHER INFORMATION These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall establish a legally valid contractual relationship. Relevant R-phrases 36/37/38 Irritating to eyes, respiratory system and skin. 43 May cause sensitization by skin contact. Xi Irritant. Material should be maintained in original containers. Empty containers should not be reused. Date of SDS Preparation/Revision: 9/15/14 Data Sources: Supplier s MSDS Specification