: Tartrazine (C.I ) MIC

Transcription

1 Date of issue: 16/01/2013 Revision date: 03/10/2016 Supersedes: 16/01/2013 Version: 2.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Trade name : Tartrazine (C.I ) MIC CAS No : Product code : TART-00D Formula : C16H9N4O9S2Na Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category : Laboratory use Uses advised against 1.3. Details of the supplier of the safety data sheet labbox labware s.l. Joan Peiró i Belis, Vilassar de Dalt - ES T F info@labkem.com Emergency telephone number Emergency number : ( Office Hours) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Serious eye damage/eye irritation, Category 2 H319 Sensitisation Respiratory, Category 1 Sensitisation Skin, Category 1 Full text of H statements : see section 16 H334 H317 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) : Danger GHS08 : H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled : P280 - Wear protective gloves/protective clothing/eye protection/face protection P302+P352 - IF ON SKIN: Wash with plenty of soap and water P304+P340 - IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention 03/10/2016 EN (English) 1/6

2 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Name Product identifier % Tartrazine for microscopy, C.I (CAS No) Full text of H-statements: see section Mixtures Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Get medical advice/attention if you feel unwell. : Remove person to fresh air and keep comfortable for breathing. : Gently wash with plenty of soap and water. : Rinse eyes with water as a precaution. If eye irritation persists: Get medical advice/attention. Remove contact lenses, if present and easy to do. Continue rinsing. : Rinse mouth. Do not induce vomiting. Get medical advice/attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/injuries after skin contact : May cause an allergic skin reaction. Symptoms/injuries after eye contact : Causes serious eye irritation Indication of any immediate medical attention and special treatment needed Never give anything by mouth to an unconscious person. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Sand. Carbon dioxide. Foam. Dry powder. Unsuitable extinguishing media : Strong water jet Special hazards arising from the substance or mixture 5.3. Advice for firefighters Precautionary measures fire Firefighting instructions Protection during firefighting : Stop leak if safe to do so. : Exercise caution when fighting any chemical fire. : Do not attempt to take action without suitable protective equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures For non-emergency personnel For emergency responders 6.2. Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections : Absorb spillage to prevent material damage. : Collect spillage. For further information refer to section 8: "Exposure controls/personal protection". : Collect spillage. Mechanically recover the product. On land, sweep or shovel into suitable containers. 03/10/2016 EN (English) 2/6

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Hygiene measures : Do not eat, drink or smoke when using this product. Separate working clothes from town clothes. Launder separately Conditions for safe storage, including any incompatibilities Special rules on packaging : Keep only in original container. Store in a closed container Specific end use(s) Laboratory chemicals. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment: Gloves. Hand protection: protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment Environmental exposure controls: Avoid release to the environment. Other information: Do not eat, drink or smoke when using this product. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Colour : orange. Odour : odourless. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density : g/cm3 a 20 C 03/10/2016 EN (English) 3/6

4 Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight Incompatible materials Strong acids. Strong bases Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard : Causes serious eye irritation. : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. SECTION 12: Ecological information Toxicity Persistence and degradability Tartrazine (C.I ) MIC ( ) Persistence and degradability Product is biodegradable Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects 03/10/2016 EN (English) 4/6

5 SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Disposal must be done according to official regulations UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport 03/10/2016 EN (English) 5/6

6 - Rail transport Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Tartrazine (C.I ) MIC is not on the REACH Candidate List Tartrazine (C.I ) MIC is not on the REACH Annex XIV List National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Recommendations Danish Regulation : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 3; ID No. 3249) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) : Young people below the age of 18 years are not allowed to use the product Chemical safety assessment SECTION 16: Other information Full text of H- and EUH-statements: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Resp. Sens. 1 Sensitisation Respiratory, Category 1 Skin Sens. 1 Sensitisation Skin, Category 1 H317 H319 H334 May cause an allergic skin reaction Causes serious eye irritation May cause allergy or asthma symptoms or breathing difficulties if inhaled SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 03/10/2016 EN (English) 6/6