1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING 2. HAZARD IDENTIFICATION WARNING

Transcription

1 SAFETY DATA SHEET Preparation Date: 27-Jan-2009 Revision Date: 28-Mar-2017 Next Revision Date: 28-Mar IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Name Item#: Recommended use Uses advised against Supplier NZ20754 Teat Dip Restricted to professional users DeLaval Manufacturing PO Box Kells Place Hamilton New Zealand Telephone Number (8am - 4:30pm Mon-Fri) Emergency Telephone Number (National Poisons Centre) CHEMCALL 2. HAZARD IDENTIFICATION WARNING HAZARDOUS SUBSTANCE NON-DANGEROUS GOODS Causes skin and serious eye irritation May cause an allergic skin reaction May cause thyroid damage Harmful to aquatic life with long lasting effects Potential Health Effects Principal Routes of Exposure Eye contact Skin contact Ingestion Inhalation Major effects of exposure EYES SKIN INGESTION INHALATION May cause severe irritation May irritate or cause burns Can cause burns to the lining of the throat and stomach May irritate nose, throat, and respiratory tracts Read Safety Data Sheet before use Page 1 / 7

2 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No Weight % Iodine <1 4. FIRST AID MEASURES Workplace Facilities Eye contact Skin contact Inhalation Ingestion Eyewash bottle with clean water Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes Get medical attention if irritation develops and persists Remove contaminated clothing and shoes Wash off immediately with plenty of water for at least 15 minutes Get medical attention if irritation develops and persists Move to fresh air Oxygen or artificial respiration if needed Seek medical attention if the patient shows any sign of respiratory difficulties Do not induce vomiting. Drink 1 or 2 glasses of water. Call a physician or Poison Control Centre immediately. Never give anything by mouth to an unconscious person. 5. FIRE-FIGHTING MEASURES Hazchem Code Flammable Properties Suitable Extinguishing Media No Hazchem Code allocated The product is not flammable. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Specific hazards arising from the chemical Protective Equipment and Precautions for Firefighters Product will decompose at high temperatures releasing poisonous fumes of iodine vapor. As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental Precautions Methods for cleaning up Avoid contact with skin, eyes and clothing. Use personal protective equipment. Prevent further leakage or spillage if safe to do so. Avoid dispersal of spilt material into waterways, drains, and sewers. Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Page 2 / 7

3 7. HANDLING AND STORAGE Handling Storage Type of Container/Package Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Keep container tightly closed in a dry and well-ventilated place. Keep in properly labelled containers. Store in original container Handle and store according to AS/NZS Standards and the Responsible Care Management Systems: Managers Handbook. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical name OSH (New Zealand, 1/2002) Iodine Ceiling: 0.1 ppm Ceiling: 1 mg/m 3 Engineering Controls Personal Protective Equipment Eye/face Protection Skin Protection Respiratory Protection Ensure adequate ventilation, especially in confined areas. Safety glasses with side-shields. Wear overalls, rubber gloves, gumboots, and PVC apron No special protective equipment required. General Hygiene Considerations Keep away from food, drink, and animal feeding stuffs. When using, do not eat, drink, or smoke. Contaminated work clothing should not be allowed out of the work place. Avoid contact with skin, eyes, and clothing. Wear suitable gloves and eye/face protection. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Brown Clear Physical state Liquid Odor Iodine ph 5 Vapor Pressure No data available Vapor Density No data available Flash Point The product is not flammable Autoignition Temperature No data available Upper flammability limit: No data available Lower flammability limit: No data available Boiling Point/Range No data available Freezing Point/Range No data available Water Solubility Soluble in water Solubility No information available Solubility in other solvents No data available Specific Gravity 1.03 Page 3 / 7

4 10. STABILITY AND REACTIVITY Chemical Stability Conditions to Avoid Incompatible Materials Hazardous decomposition products Stable under normal conditions. Heat, flames and sparks. oxidizing agents Thermal decomposition can lead to release of poisonous fumes. (. Iodine. ). 11. TOXICOLOGICAL INFORMATION Acute Toxicity Inhalation Eye contact Skin contact Ingestion May irritate nose, throat, and respiratory tracts. May cause eye irritation. May cause skin irritation. May cause allergic skin reaction. Ingestion may cause irritation to mucous membranes. Component Information Chemical name LD50 Oral LD50 Dermal LC50 Inhalation Iodine mg/kg 137 ppm mg/l Irritation Corrosivity Sensitization Mutagenic effects Carcinogenicity Reproductive Effects Developmental Effects STOT - single exposure STOT - repeated exposure Irritating to skin Irritating to eyes May cause an allergic skin reaction. There are no known carcinogenic chemicals in this product. May cause thyroid damage No information available 12. ECOLOGICAL INFORMATION Ecotoxicity Ecotoxicity effects Harmful to aquatic life with long lasting effects Chemical name Algae/aquatic plants Fish Microtox Waterflea Iodine LC50 (96 h) 0.53 mg/l LC50 (48 h) 0.16 mg/l Persistence and degradability No information available Bioaccumulation/Accumulation Mobility No information available Page 4 / 7

5 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Contaminated Packaging Dispose of in accordance with local regulations. Should not be released into the environment. Empty containers should be taken for local recycling, recovery or waste disposal. 14. TRANSPORT INFORMATION Not regulated Hazchem Code No Hazchem Code allocated 15. REGULATORY INFORMATION ERMA NZ Registration Number HSR ERMA Group Standard Hazardous Substances (Veterinary Medicines) Transfer Notice 2005 HSNO Classifications HSNO Conditions ERMA Reference 6.3A Substances that are irritating to the skin 6.4A Substances that are irritating to the eye 6.5B Substances that are contact sensitizers 6.9B Substances that are harmful to target organs 9.1C Sustances that are harmful to the aquatic environment Hazardous Substances Location trigger quantiy: N/A Approved Handler trigger quantiy: N/A Secondary containment trigger quantity: 1000L or 1000kg Signage trigger quantity: 1000L or 1000kg Response Plan trigger quantity: 1000L or 1000kg ERMA User Guide to the HSNO Controls, which links to the Hazardous Substances Regulations 2001 Page 5 / 7

6 16. OTHER INFORMATION Prepared By Preparation Date: Revision Date: DeLaval NV Industriepark-Drongen Gent Belgium 27-Jan Mar-2017 References NZS 5433:2007 Transport of Dangerous Goods on Land Land Transport (Dangerous Goods) Rule 45001:2005 Hazardous Substances Regulations 2001: - Minimum Degrees of Hazard - Classification - Classes 1 to 5 Controls - Classes 6, 8 and 9 Controls - Packaging Regulations - Dispoal Regulations - Emergency Management - Disposal Regulations Health and Safety in Employment Regulations 1995 User Guide to the HSNO Thresholds and Classifications OSH Workplace Exposure Standards January 2002 NZCIC Approved Code of Practice - Preparation of Safety Data Sheets Signage for premises storing hazardous substances and dangerous goods Land Transport (Dangerous Goods) Rule 45001:2005 Hazardous Substances Regulations 2001: - Minimum Degrees of Hazard - Classification - Classes 1 to 5 Controls - Classes 6, 8 and 9 Controls - Packaging Regulations - Dispoal Regulations - Emergency Management - Disposal Regulations Health and Safety in Employment Regulations 1995 User Guide to the HSNO Thresholds and Classifications OSH Workplace Exposure Standards January 2002 NZCIC Approved Code of Practice - Preparation of Safety Data Sheets Signage for premises storing hazardous substances and dangerous goods Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text Page 6 / 7

7 End of SDS Page 7 / 7