: Catalytic Converter & Oxygen Sensor Cleaner

Transcription

1 MSDS Version: E01.00 Date of issue: 13/08/2015 Blend Version: 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : Catalytic Converter & Oxygen Sensor Cleaner Product code : W Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : Petrol additive Uses advised against 1.3. Details of the supplier of the safety data sheet Wynn's Belgium Industriepark-West Sint-Niklaas - Belgium T F msds@wynns.eu Emergency telephone number Emergency number : BIG: +32(0)14/ SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 3 Org. Perox. E Acute Tox. 4 (Dermal) Acute Tox. 4 (Inhalation:dust,mist) Skin Irrit. 2 Eye Irrit. 2 Muta. 2 STOT RE 1 Asp. Tox. 1 Aquatic Chronic 3 H226 H242 H312 H332 H315 H319 H341 H372 H304 H412 Full text of classification categories and H statements : see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Muta.Cat.3; R68 O; R7 Xn; R20/21 Xn; R65 Xn; R48/20 Xi; R36/38 R10 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) : Danger GHS02 GHS07 GHS08 02/09/2015 EN (English) 1/10

2 Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) : 2-butoxyethanol, xylene, Di-tert-butyl peroxide, 2-ethylhexan-1-ol, hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, aromatics (2-25%) : H226 - Flammable liquid and vapour H242 - Heating may cause a fire H304 - May be fatal if swallowed and enters airways H312+H332 - Harmful in contact with skin or if inhaled H315 - Causes skin irritation H319 - Causes serious eye irritation H341 - Suspected of causing genetic defects H372 - Causes damage to organs (central nervous system) through prolonged or repeated exposure H412 - Harmful to aquatic life with long lasting effects : P102 - Keep out of reach of children P405 - Store locked up P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P260 - Do not breathe vapours P280 - Wear face protection, protective gloves, protective clothing P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER, a doctor P331 - Do NOT induce vomiting P337+P313 - If eye irritation persists: Get medical advice/attention 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % w Classification according to Directive 67/548/EEC hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, aromatics (2-25%) (EC no) (REACH-no) butoxyethanol (CAS No) (EC no) (EC index no) (REACH-no) ethylhexan-1-ol (CAS No) (EC no) (REACH-no) xylene (CAS No) (EC no) (EC index no) (REACH-no) Xn; R48/20 Xn; R65 R Xn; R20/21/22 Xi; R36/ Xn; R20 Xi; R36/37/ R10 Xn; R20/21 Xi; R38 polyetheramine (CAS No) Xi; R38 R52/53 Di-tert-butyl peroxide (CAS No) (EC no) (EC index no) (REACH-no) ,5-5 O; R7 F; R11 Muta.Cat.3; R68 R52/53 Kerosine (petroleum), hydrodesulfurized (CAS No) (EC no) (EC index no) (REACH-no) ,1-1 Xn; R65 Xi; R38 N; R51/53 Name Product identifier Specific concentration limits xylene (CAS No) (EC no) (EC index no) (REACH-no) (C >= 12,5) Xn;R20/21 Name Product identifier % w Classification according to Regulation (EC) No. 1272/2008 [CLP] hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, aromatics (2-25%) (EC no) (REACH-no) STOT RE 1, H372 Asp. Tox. 1, H304 Aquatic Chronic 3, H412 02/09/2015 EN (English) 2/10

3 Name Product identifier % w Classification according to Regulation (EC) No. 1272/2008 [CLP] 2-butoxyethanol (CAS No) (EC no) (EC index no) (REACH-no) ethylhexan-1-ol (CAS No) (EC no) (REACH-no) xylene (CAS No) (EC no) (EC index no) (REACH-no) Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 STOT SE 3, H Flam. Liq. 3, H226 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 polyetheramine (CAS No) Skin Irrit. 2, H315 Aquatic Chronic 3, H412 Di-tert-butyl peroxide (CAS No) (EC no) (EC index no) (REACH-no) Kerosine (petroleum), hydrodesulfurized (CAS No) (EC no) (EC index no) (REACH-no) Full text of R- and H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 2,5-5 Flam. Liq. 2, H225 Org. Perox. E, H242 Muta. 2, H341 Aquatic Chronic 3, H412 0,1-1 Skin Irrit. 2, H315 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 : Check the vital functions. Victim conscious with laboured breathing: half-seated. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Vomiting: prevent asphyxia/aspiration pneumonia. Victim in shock: on his back with legs slightly raised. Keep watching the victim. Give psychological aid. Prevent cooling by covering the victim (no warming up). Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. If skin irritation or rash occurs: Get medical advice/attention. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell. Ingestion of large quantities: immediately to hospital Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Suspected of causing genetic defects. : Harmful if inhaled. : Harmful in contact with skin. Causes skin irritation. Repeated or prolonged skin contact may cause dermatitis and defatting. : Causes serious eye irritation. : Harmful if swallowed. Headache. Abdominal pain. Risk of aspiration pneumonia. May be fatal if swallowed and enters airways Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray. AFFF foam. ABC-powder. : Do not use a heavy water stream. 02/09/2015 EN (English) 3/10

4 5.2. Special hazards arising from the substance or mixture Fire hazard Explosion hazard : Flammable liquid and vapour. This material can accumulate static charge by flow or agitation and can be ignited by static discharge. : Product is not explosive Advice for firefighters Firefighting instructions Protection during firefighting : Contain the extinguishing fluids by bunding. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use special care to avoid static electric charges. No open flames. No smoking For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment : Wear suitable gloves and eye/face protection. protective clothing. : Mark the danger area. Seal off low-lying areas. Large spills/in enclosed spaces: compressed air apparatus. Take off contaminated clothing and wash before reuse. : Equip cleanup crew with proper protection Environmental precautions Prevent entry to sewers and public waters. Avoid release to the environment Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Storage temperature : < 45 C Storage area Special rules on packaging 7.3. Specific end use(s) : Collect spillage. Contain leaking substance, pump over in suitable containers. : Small quantities of liquid spill: take up in non-combustible absorbent material and shovel into container for disposal. Small quantities of liquid spill: take up in noncombustible absorbent material and shovel into container for disposal. Clean with detergents. Avoid solvent cleaners. : meet the legal requirements. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin. Presents no particular risk when handled in accordance with good occupational hygiene practice. Provide good ventilation in process area to prevent formation of vapour. : Use good personal hygiene practices. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. : Take precautionary measures against static discharge. : Meet the legal requirements. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Protect from sunlight. Store in a well-ventilated place. : Meet the legal requirements. Protect from heat and direct sunlight. Keep container tightly closed in a cool, well-ventilated place. Ventilation along the floor. : Keep only in original container. correctly labelled. SECTION 8: Exposure controls/personal protection 8.1. Control parameters hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, aromatics (2-25%) Italy - Portugal - USA ACGIH ACGIH TWA (ppm) 100 ppm 02/09/2015 EN (English) 4/10

5 2-ethylhexan-1-ol ( ) Germany Germany 2-butoxyethanol ( ) TRGS 900 Occupational exposure limit value (mg/m³) TRGS 900 Occupational exposure limit value (ppm) 110 mg/m³ 20 ppm EU IOELV TWA (mg/m³) 98 mg/m³ EU IOELV TWA (ppm) 20 ppm EU IOELV STEL (mg/m³) 246 mg/m³ EU IOELV STEL (ppm) 50 ppm Belgium Limit value (mg/m³) 98 mg/m³ Belgium Limit value (ppm) 20 ppm Belgium Short time value (mg/m³) 246 mg/m³ Belgium Short time value (ppm) 50 ppm Belgium Remark (BE) D Netherlands Grenswaarde TGG 8H (mg/m³) 100 mg/m³ Netherlands Grenswaarde TGG 8H (ppm) 20 ppm Netherlands Grenswaarde TGG 15MIN (mg/m³) 246 mg/m³ Netherlands Grenswaarde TGG 15MIN (ppm) 50 ppm EU IOELV TWA (mg/m³) 221 mg/m³ EU IOELV TWA (ppm) 50 ppm EU IOELV STEL (mg/m³) 442 mg/m³ EU IOELV STEL (ppm) 100 ppm Belgium Limit value (mg/m³) 221 mg/m³ Belgium Limit value (ppm) 50 ppm Belgium Short time value (mg/m³) 442 mg/m³ Belgium Short time value (ppm) 100 ppm Belgium Remark (BE) D United Kingdom WEL STEL (ppm) 100 ppm 8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Provide good ventilation in process area to prevent formation of vapour. Does not require any specific or particular technical measures. : Gloves. Safety glasses. Hand protection Other information : Neoprene. Nitrile rubber. Choosing the proper glove is a decision that depends not only on the type of material, but also on other quality features, which differ for each manufacturer. Time of penetration is to be checked with the glove producer. : Breakthrough time : >30'. Thickness of the glove material >0,1 mm. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Odour threshold ph : Relative evaporation rate (butylacetate=1) : Liquid : Clear. : Colourless. refraction index : 1,44 Melting point : characteristic. 02/09/2015 EN (English) 5/10

6 Freezing point Boiling point Flash point : 40 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density C Solubility Log Pow Log Kow Viscosity, C Viscosity, C Viscosity : Viscosity Index : Explosive properties Oxidising properties Explosive limits 9.2. Other information : 833 kg/m³ : 1,8 mm²/s VOC content : 90,46 % Additional information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions. Heating may cause a fire Possibility of hazardous reactions Conditions to avoid : The physical and chemical data in this section are typical values for this product and are not intended as product specifications. Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. Keep away from strong acids and strong oxidizers Incompatible materials Hazardous decomposition products On burning: release of harmful/irritant gases/vapours. Carbon dioxide. Carbon monoxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Catalytic Converter & Oxygen Sensor Cleaner ATE CLP (dermal) ATE CLP (dust,mist) 2-ethylhexan-1-ol ( ) ATE CLP (dust,mist) 2-butoxyethanol ( ) ATE CLP (oral) ATE CLP (dermal) ATE CLP (dust,mist) ATE CLP (dermal) : Harmful: may cause lung damage if swallowed 1100,000 mg/kg bodyweight 4,167 mg/l/4h 1,500 mg/l/4h 500,000 mg/kg bodyweight 1100,000 mg/kg bodyweight 1,500 mg/l/4h 1100,000 mg/kg bodyweight 02/09/2015 EN (English) 6/10

7 ATE CLP (dust,mist) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard 1,500 mg/l/4h : Causes skin irritation. : Causes serious eye irritation. : Not classified : Suspected of causing genetic defects. : Not classified : Not classified : Not classified : Causes damage to organs (central nervous system) through prolonged or repeated exposure. : May be fatal if swallowed and enters airways. SECTION 12: Ecological information Toxicity Ecology - general Ecology - water : This product contains hazardous components for the aquatic environment. May cause long lasting harmful effects to aquatic life. : Harmful to aquatic life with long lasting effects Persistence and degradability 2-ethylhexan-1-ol ( ) Persistence and degradability Persistence and degradability Bioaccumulative potential Readily biodegradable in water. Biodegradable in the soil. Readily biodegradable in water. Biodegradable in the soil. Photolysis in the air. 2-ethylhexan-1-ol ( ) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Bioaccumulative potential Low potential for bioaccumulation (BCF < 500) Mobility in soil Ecology - soil Results of PBT and vpvb assessment May be harmful to plant growth, blooming and fruit formation. hydrocarbons, C10-C13, n-alkanes, isoalkanes, cyclics, aromatics (2-25%) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations European List of Waste (LoW) code SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) : 1993 : Dispose in a safe manner in accordance with local/national regulations. Remove to an authorized waste treatment plant. Avoid release to the environment. : * - chemicals consisting of or containing dangerous substances * - packaging containing residues of or contaminated by dangerous substances 02/09/2015 EN (English) 7/10

8 14.2. UN proper shipping name Proper Shipping Name (ADR) Transport document description (ADR) : FLAMMABLE LIQUID, N.O.S. : UN 1993 FLAMMABLE LIQUID, N.O.S. (xylene, di-tert-butylperoxide), 3, III, (D/E) Transport hazard class(es) Class (ADR) : 3 Danger labels (ADR) : Packing group Packing group (ADR) Environmental hazards Other information : III : No supplementary information available Special precautions for user Overland transport Hazard identification number (Kemler No.) : 30 Classification code (ADR) : F1 Orange plates : Special provisions (ADR) : 274, 601, 640E Transport category (ADR) : 3 Tunnel restriction code (ADR) : D/E Limited quantities (ADR) : 5l Excepted quantities (ADR) : E1 EAC code : 3YE Transport by sea EmS-No. (1) : F-E, S-E Air transport Instruction "cargo" (ICAO) : 366 Instruction "passenger" (ICAO) : 355 Instruction "passenger" - Limited quantities (ICAO) : Y Transport in bulk according to Annex II of MARPOL and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances VOC content : 90,46 % National regulations Water hazard class (WGK) : 2 - hazard to waters 02/09/2015 EN (English) 8/10

9 15.2. Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Full text of R-, H- and EUH-statements: Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Asp. Tox. 1 Aspiration hazard, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Muta. 2 Germ cell mutagenicity, Category 2 Org. Perox. E Organic Peroxides, Type E Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 1 Specific target organ toxicity Repeated exposure, Category 1 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H225 Highly flammable liquid and vapour H226 Flammable liquid and vapour H242 Heating may cause a fire H302 Harmful if swallowed H304 May be fatal if swallowed and enters airways H312 Harmful in contact with skin H315 Causes skin irritation H319 Causes serious eye irritation H332 Harmful if inhaled H335 May cause respiratory irritation H341 Suspected of causing genetic defects H372 Causes damage to organs through prolonged or repeated exposure H411 Toxic to aquatic life with long lasting effects H412 Harmful to aquatic life with long lasting effects R10 Flammable R11 Highly flammable R20 Harmful by inhalation R20/21 Harmful by inhalation and in contact with skin R20/21/22 Harmful by inhalation, in contact with skin and if swallowed R36/37/38 Irritating to eyes, respiratory system and skin R36/38 Irritating to eyes and skin R38 Irritating to skin R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment R65 Harmful: may cause lung damage if swallowed R66 Repeated exposure may cause skin dryness or cracking R68 Possible risk of irreversible effects R7 May cause fire F Highly flammable N Dangerous for the environment O Oxidising Xi Irritant Xn Harmful 02/09/2015 EN (English) 9/10

10 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 02/09/2015 EN (English) 10/10