Vegetable Oils for Industrial Applications
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1 Vegetable Oils for Industrial Applications Archer Daniels Midland Company - Industrial Oils 4666 Faries Parkway Decatur, Illinois t (217) / f (217) Toll free (800)
2 ADM S Industrial Products History ARCHER DANIELS MIDLAND COMPANY 2
3 ADM Overview $80+ Billion in Revenues Ranked No. 27 on the Fortune ,000 Global Employees 140 countries 6 continents Ag Processor & Food Ingredient Provider 470 crop procurement facilities 285 ingredient processing plants 40 innovation centers Premier Transportation Network 1,900 trucks & trailers 27,400 railcar fleet 2,500 barges 52 deepwater vessels ARCHER DANIELS MIDLAND COMPANY 3
4 World s Most Diversified Assets 4 Oilseeds Processing Corn Processing Wild Flavors & Specialty Ing. Ag Services GrainCorp Wilmar International Sourcing distribution Processing distribution
5 Fatty Acid Profile of Common Oils & Fats 5 Vistive Gold Hi Oleic Soybean Oil High Oleic / Low Lin Canola Oil Canola Oil High Oleic Sunflower Oil Nusun (Mid Oleic Sunflower Oil) Safflower Oil Linseed Oil Traditional Sunflower Oil Plenish Hi Oleic Soybean Oil Corn Oil Olive Oil Soybean Oil Peanut Oil Cottonseed Oil EIE Soy Lard EIE Soy Palm Olein Beef Tallow Palm Oil Palm Stearine Palm Kernel Oil Coconut Oil Saturates Monunsaturates Linoleic Acid Linolenic Acid
6 Stability The Need for Stable Oils 6 Corn Oil Cottonseed Oil High Oleic Soybean High Oleic Canola Nusun Peanut Oil High Oleic Peanut High Oleic Palm
7 Triglycerides Oils and fats are made up of triglycerides. Triglycerides are made up of various fatty acids. Fatty acids can vary in chain length and degree of unsaturation.
8 Fatty Acids Butyric C4:0 Caproic C6:0 Caprylic C8:0 Capric C10:0 Lauric C12:0 Myristic C14:0 Palmitic C16:0 Palmitoleic C16:1 Stearic C18:0 Oleic C18:1 Linoleic C18:2 Linolenic C18:3 Arachidic C20:0 Behenic C22:0 Lignoceric C24:0
9 Today s Presence in Industrial Markets ADM Oils Long/Medium Fatty Acid Chain Short Soybean - Commodity - High Oleic Canola - Commodity - High Oleic Corn Cottonseed Sunflower Peanut Linseed Palm Oil Palm Olein Palm Sterin Coconut Palm Kernel Modification Options Blending Hydrogenation Enzymatic Interesterification Heat Bodied (LSO) Micro-Emulsions Evolution Chemicals Industrial Ethanol (USP, Industrial) Glycols (USP PG, PGI) Glycerin (USP) Sorbitol (USP) Vegetable Oils Lecithin Products Xanthan Gum Citric Acid Dispersants Envirostrip Solvents Ethyl lactate FAMEs Starch Portfolio Proteins Biobased SAPs (BioSAP) 9
10 Multiple Options 10 Vegetable Oils Polymerized Oils Blends
11 Cutting and Forming Operations ARCHER DANIELS MIDLAND COMPANY 11
12 Vegetable Oils vs. Esters Each additive is 10 parts in 90 parts 100 SUS naphthenic oil 140 % Efficiency on 1018 CRS with a Forming Tap Canola Soybean Cl-Paraffin PE Ester TMP Ester ARCHER DANIELS MIDLAND COMPANY 12
13 Polymerized Oils Each additive is 10 parts in 90 parts 100 SUS naphthenic oil. 112 % Efficiency on 1018 CRS with Forming Tap Canola Ox Canola K HB Soybean Z2 Ox Soybean Z2 Ox Rape Z2 ARCHER DANIELS MIDLAND COMPANY 13
14 Effect of Blends Each additive is 10 parts in 90 parts naphthenic oil 104 % Efficiency on 1018 CRS with a Forming Tap Canola HB Soybean Z2 Ox Canola K Ox Rapeseed Z2 TG + FA PE TMP ARCHER DANIELS MIDLAND COMPANY 14
15 Aluminum presents an advantage Polar additives are more effective on polar surfaces Oxide layer Al ARCHER DANIELS MIDLAND COMPANY 15
16 Polymerized Oils on Aluminum Each additive is 10 parts in 90 parts 100 SUS naphthenic oil. 120 % Efficiency on 6061 Aluminum with a Forming Tap SUS Naphthenic w/canola w/hz Soy woz Soy w/oz Canola w/oz Rape w/ PE Tallate w/ Cl P 50/55 ARCHER DANIELS MIDLAND COMPANY 16
17 SUMMARY There are powerful alternatives to current lubricity additives Polymers can be tailored to the application by changing molecular weight and polarity Blends have a high potential Polymerized oils are especially effective on aluminum ARCHER DANIELS MIDLAND COMPANY 17
18 18 ADM Oils Industrial Oils Solutions: Diverse product portfolio for off the shelf items or customized products. Technical Support: R&D, technical sales and support for product development. Innovation: The ADM Industrial Oils and Evolution Chemicals specialty ingredients fosters innovation.
19 PRODUCT RBD SOY OIL RBD HIGH OLEIC SOY OIL RBD CANOLA OIL RBD HIGH OLEIC CANOLA OIL DESCRIPTION TYPICAL ANALYSIS APPLICATIONS REFINED BLEACHED AND DEODORIZED SOY OIL OIL MUDS, ALKYD RESINS, METAL WORKING FLUIDS REFINED, BLEACHED AND DEODORIZED HIGH OLEIC SOY OIL OIL MUDS, LUBRICANTS, AG SPRAYS, METAL WORKING FLUIDS REFINED, BLEACHED, DEODORIZED CANOLA OIL OIL MUDS, LUBRICANTS, METAL WORKING FLUIDS REFINED, BLEACHED, DEODORIZED HIGH OLEIC CANOLA OIL OIL MUDS, LUBRICANTS, AG SPRAYS, METAL WORKING FLUIDS ACID VALUE, KOH/g (Typical) VISCOSITY, ASTM D C (Typical) VISCOSITY, ASTM D C (Typical) VISCOSITY INDEX (Typical) FLASH POINT OPEN CUP CLEVELAND (Typical) >300 C >300 C >300 C >300 C IODINE VALUE SPECIFIC GRAVITY, ASTM 4052 (Typical) c, HRS C 18:1 (Typical_ MIN MIN SATURATES % (Typical) MOISTURE % 0.05 MAX 0.05 MAX 0.05 MAX 0.05 MAX PRODUCT FORM LIQUID LIQUID LIQUID LIQUID PACKAGING ISO, BULK ISO, BULK ISO, BULK ISO, BULK ISO = 20 MT ISOTAINER For more details please contact us at evolution@adm.com 19
20 PRODUCT DESCRIPTION TYPICAL ANALYSIS APPEARANCE APPLICATIONS ADM LINSEED OIL MICROEMULSION LINSEED OIL MICROEMULSION ADM BOILED LINSEED MICROEMULSION BOILED LINSEED OIL MICROEMULSION ADM 2X BOILED LINSEED MICROEMULSION DOUBLE BOILED LINSEED OIL MICROEMULSION ADM CME MICROEMULSION CANOLA METHYL ESTERS MICROEMULSION TRANSLUCENT AMBER TRANSLUCENT AMBER TRANSLUCENT AMBER TRANSLUCENT STRAW COLOR COATINGS, STAINS, COLORANTS COATINGS, STAINS, COLORANTS COATINGS, STAINS, COLORANTS DEGREASER, ADHESIVE & PAINT REMOVER, LUBRICANTS METAL WORKING ADM SME MICROEMULSION SOY METHYL ESTER MICROEMULSION TRANSLUCENT STRAW COLOR DEGREASER, ADHESIVE & PAINT REMOVER, LUBRICANTS, METAL WORKING OIL / ESTER CONTENT % MICROEMULSION FORM O/W O/W O/W O/W O/W 25 C 150 cps, Brookfield, 30 rpm 150 cps, Brookfield, 30 rpm 150 cps, Brookfield, 30 rpm 250 cps, Brookfield, 30 rpm 40 cps, Brookfield, 30 rpm MOISTURE % DENSITY LBS. / US GAL DRIERS N/A COBALT / MANGANESE COBALT / MANGANESE N/A N/A SOLIDS% PRODUCT FORM LIQUID LIQUID LIQUID LIQUID LIQUID PACKAGING PA, DR, IBC, ISO, BULK PA, DR, IBC, ISO, BULK PA, DM, IBC, ISO, BULK PA, DM, IBC, ISO, BULK PA, DM, IBC, ISO, BULK PA=20 KG STEEL PAIL DR = 180 KG STEEL DRUM, IBC = 1000 KG HDPE IBC, ISO = 20 MT ISOTAINER For more details please contact us at evolution@adm.com 20
21 TYPICAL ANALYSIS APPLICATIONS PRODUCT ADM SME ADM CME ADM HIGH STABILITY ESTER DESCRIPTION SOY METHYL ESTERS CAS CANOLA METHYL ESTERS CAS MODIFIED METHYL ESTERS LOW VOC SOLVENTS, SOAPS, CHLORINATED LUBRICANTS, CUTTING OILS, GEAR OILS, INK SOLVENTS, PLASTICIZERS, PAINT AND GRAFFITI REMOVERS ACID VALUE mg KOH/g 0.30, IODINE VALUE g I 2 /100 g KINEMATIC VISCOSTIY 40 C 4.06 cst 4.50 cst cst KINEMATIC VISCOSITY 100 C 1.65 cst 1.77 cst 2.96 cst VISCOSITY INDEX MOISTURE <250 ppm <400 ppm 800 ppm OSI (Hours) > 6 > 9 >30 FLASH POINT >93 C >130 C >190 C SPECIFIC GRAVITY PRODUCT FORM Liquid Liquid Liquid PACKAGING DR, IBC, ISO, BULK DR, IBC, ISO, BULK DM, IBC, ISO, BULK DM = 420 lb. STEEL DRUM,DR = 180 KG STEEL DRUM, IBC = 1000 KG HDPE IBC, ISO = 20 MT ISOTAINER, BULK For more details please contact us at evolution@adm.com 21
22 PRODUCT NON-BREAK REFINED & BLEACHED SUPERB VARNISH DESCRIPTION ALKALI REFINED LINSEED OIL FULLY ALKALI REFINED LINSEED OIL TYPICAL ANALYSIS APPLICATIONS ALKYDS, VARNISHES VEHICLES,DRIERS VARNISHES, ENAMELS, DRIERS, GRINDING OILS FULLY ALKALI REFINED, BLEACHED AND DEWAXED LINSEED OIL FAST DRYING RESINGS, VARNISHES, ENAMEL VEHICLES, PRINTING INKS BREAK FREE LINSEED OIL RESINS, VARNISHES, ENAMELS, DRIERS, GRINDING OILS ACID VALUE 0.5 max 0.3 max 0.3 max 2-4 COLOR, GARDNER 1953 (MAX.) 11 max 6 max 6 max 6 max VISCOSITY (GARDNER-HOLDT) A 1 -A A 1 -A A 1 -A A 1 -A IODINE VALUE SAPONIFICATION VALUE DENSITY (LBS. / US GAL) PRODUCT FORM Liquid Liquid Liquid Liquid PACKAGING DR, IBC, BULK DR, IBC, BULK DR, IBC, BULK DR, IBC, BULK DR = 180 KG STEEL DRUM, ISO = 20 MT ISOTAINER For more details please contact us at evolution@adm.com 22
23 PRODUCT OKO S-37 OKO S-70 OKO M-2 1/2 OKO M-71/2 OKO M-17 OKO M-25 OKO M-37 DESCRIPTION TYPICAL ANALYSIS APPLICATIONS OKO SERIES LINSEED OIL PRODUCTS ARE HEAT POLYMERIZED OILS PRODUCED USING A SPECIAL VACUUM PROCESS. THEY POSESS LOW ACID NUMBERS AND ARE EXCEPTIONALLY LIGHT IN COLOR OKO PRODUCTS MEET THE REQUIREMENTS OF TT-L-201 OKO SERIES PRODUCTS ARE RECOMMENDED FOR PAINTS, ENAMELS, PRINTING INKS, AND MASTICS ACID VALUE COLOR, GARDNER 1953 (MAX.) 6 max 6 max 6 max 6 max 6 max 6 max 6 max VISCOSITY (GARDNER-HOLDT) Z- : Z+ Z 2 + : Z 3 - Z 4 - : Z 4 + Z 6 + : Z 7 - Z 7 + : Z 7 - Z 8 - : Z 8 + Z 9 - : Z 9 + IODINE VALUE SAPONIFICATION VALUE DENSITY (LBS. / US GAL) PRODUCT FORM Liquid Liquid Liquid Liquid Liquid Liquid Liquid PACKAGING DR, BULK DR, BULK DR, BULK DR, BULK DR, BULK DR, BULK DR, BULK DR = 180 KG STEEL DRUM, ISO = 20 MT ISOTAINER For more details please contact us at evolution@adm.com 23
24 PRODUCT ALINCO Q ALINCO X ALINCO Y ALINCO Z ALINCO Z-1 ALINCO Z-2 ALINCO Z-2/Z-3 ALINCO Z-3 DESCRIPTION TYPICAL ANALYSIS APPLICATIONS ALINCO LINSEED OILS ARE CLOSED KETTLE HEAT BODIED OILS OF MEDIUM ACID RANGE. ALINCO PRODUCTS MEET THE REQUIREMENTS OF TT-L-201 ALINCO SERIES PRODUCTS ARE USED IN PAINTS, VARNISHES AND PRINTING INKS ACID VALUE COLOR, GARDNER 1953 (MAX.) VISCOSITY 25 C VISCOSITY (GARDNER-HOLDT) P-S X+1/2 Y+1/2 Z+1/2 Z1+1/2 Z2+1/2 Z2-Z3 Z3+1/2 IODINE VALUE SAPONIFICATION VALUE DENSITY (LBS. / US GAL) PRODUCT FORM LIQUIID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID PACKAGING DR, BULK DR, BULK DR, BULK DR, BULK DR, BULK DR, BULK DR, BULK DR, BULK DR = 180 KG STEEL DRUM, ISO = 20 MT ISOTAINER For more details please contact us at evolution@adm.com 24
25 PRODUCT ALINCO Z-4 ALINCO Z-5 ALINCO Z-6 ALINCO M25 DESCRIPTION TYPICAL ANALYSIS APPLICATIONS ALINCO LINSEED OILS ARE CLOSED KETTLE HEAT BODIED OILS OF MEDIUM ACID RANGE. ALINCO PRODUCTS MEET THE REQUIREMENTS OF TT-L-201 ALINCO SERIES PRODUCTS ARE USED IN PAINTS, VARNISHES AND PRINTING INKS ACID VALUE COLOR, GARDNER 1953 (MAX.) VISCOSITY 25 C VISCOSITY (GARDNER-HOLDT) Z4+1/2 Z5+1/2 Z6+1/2-Z6+1/4 Z8-Z8+ IODINE VALUE SAPONIFICATION VALUE DENSITY (LBS. / US GAL) PRODUCT FORM Liquid Liquid Liquid Liquid PACKAGING DR, BULK DR, BULK DR, BULK DR, BULK DR = 180 KG STEEL DRUM, ISO = 20 MT ISOTAINER For more details please contact us at evolution@adm.com 25
26 Please Contact Archer Daniels Midland Company - Industrial Oils 4666 Faries Parkway Decatur, Illinois t (217) / f (217) Toll free (800) For more details please contact us at evolution@adm.com 26
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