GC Multiresidue Pesticide Std #6 -SPP

Transcription

1 Analytical Reference Materials GC Multiresidue Pesticide Std #6 -SPP Catalog # Lot # A & A Benner Circle Bellefonte, PA FOR LABORATORY USE ONLY. READ MSDS PRIOR TO USE. RAW MATERIAL TEST INFORMATION AVAILABLE UPON REQUEST MANUFACTURED UNDER RESTEK'S ISO 9001 REGISTERED QUALITY SYSTEM Page 1 of 12

2 CERTIFIED REFERENCE MATERIAL 110 Benner Circle Bellefonte, PA Tel: (800) Fax: (814) Certificate of Analysis FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE. This Reference Material is intended for Laboratory Use Only as a standard for the qualitative and/or quantitative determination of the analyte(s) listed. Catalog No. : Lot No.: A Description : GC Multiresidue Pesticide Std #6 -SPP Container Size : GC Multiresidue Pesticide Std #6 -SPP 100µg/mL,Toluene, 1mL/ampul 2 ml > 1 ml Pkg Amt: Expiration Date : April 30, 2016 Storage: 10 C or colder Handling: This product is photosensitive. C E R T I F I E D V A L U E S Elution Order Compound Grav. Conc. (weight/volume) 1 Tefluthrin CAS # (Lot 11017) 2 Transfluthrin CAS # (Lot ) 3 Anthraquinone µg/ml CAS # (Lot 07222DC) 4 Bioallethrin 99.5 µg/ml CAS # (Lot 00610) Purity 93% 51% Isomer 2; 49% Isomer 1 5 Resmethrin CAS # (Lot B) 90% trans Isomer; 10% cis Isomer 6 Tetramethrin CAS # (Lot SZBA110XV) Purity 98% 23% Isomer 1; 77% Isomer 2 7 Bifenthrin µg/ml CAS # (Lot ) 8 Phenothrin (cis & trans) 99.8 µg/ml CAS # (Lot SZBD221XV) Purity 96% 19% cis isomer; 81% trans isomer Expanded Uncertainty (95% C.L.; K=2) +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml Page 2 of 12

3 9 lambda-cyhalothrin CAS # (Lot ) Purity 98% 10 Acrinathrin CAS # (Lot 21212) 11 cis-permethrin CAS # (Lot ) 12 trans-permethrin CAS # (Lot 00908) 13 Cyfluthrin µg/ml CAS # (Lot ) Purity 98% 25% Isomer 1; 33% Isomer 2; 24% Isomer 3; 18% Isomer 4 14 Cypermethrin CAS # (Lot ) 32% Isomer 1; 29% Isomer 2; 24% Isomer 3; 15% Isomer 4 15 Flucythrinate µg/ml CAS # (Lot A) Purity 92% 62% Isomer 1; 38% Isomer 2 16 Fenvalerate µg/ml CAS # (Lot ) 68% R Isomer; 32% S Isomer 17 tau-fluvalinate CAS # (Lot ) 53% Isomer 1; 47% Isomer 2 18 Deltamethrin CAS # (Lot ) +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml Solvent: Toluene CAS # Purity % Page 3 of 12

4 Column: 30m x 0.25mm x 0.25µm Rtx-5 (cat.#10223) Carrier Gas: hydrogen-constant pressure 10 psi. Temp. Program: 100 C (hold 1 min.) to C/min. (hold 5 min.) Inj. Temp: 250 C Det. Temp: 330 C Det. Type: FID This chromatogram represents a general set of testing conditions chosen for product acceptance. For optimal results in your lab, conditions should be adjusted for your specific instrument, method, and application. Date Mixed: 17-Apr-2014 Balance: Date Passed: 06-May-2014 Manufactured under Restek's ISO 9001:2008 Registered Quality System Certificate #FM Page 4 of 12

5 General Certified Reference Material Notes Expiration Notes: Expiration date valid for unopened ampul stored in compliance with the recommended conditions. Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the recommended condition found in the storage field. Purity Notes: Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD, GC/MS, LC/MS, RI, and/or melting point. Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the parent compound in solution. Purity of isomeric compounds is reported as the sum of the isomers. Purity values are rounded to the nearest whole number. Certified Uncertainty Value Notes: The uncertainties are determined in accordance with ISO Guides 34 and 35. The certified combined stressed uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty and were combined using the following formula: k is a coverage factor of 2, which gives a level of confidence of approximately 95%. It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at for use recommendations if your shipment was in-transit for more than 7 days at nonstandard temperature conditions. Apply the certified combined unstressed uncertainty value if the product was received under standard shipping conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard conditions as specified below. Label Conditions 25 C Nominal (Room Temperature) 10 C or colder (Refrigerate) 0 C or colder (Freezer) Standard Conditions < 60 C < 40 C < 25 C Non-Standard Conditions 60 C up to 7 days 40 C up to 7 days 25 C up to 7 days Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed, separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values are available by contacting Restek Technical Service at The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure that the minimum packaged amount can be sufficiently transferred. Manufacturing Notes: Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily using NIST traceable weights, and/or dilutions with Class A glassware. Handling Notes: Samples should be transferred into deactivated vials for handling and storage. Restek supplies deactivated vials along with most standards packed in 2 ml ampules. Due to space constraints, Restek does not supply vials for larger volume ampules. Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31840, which includes complete instructions. Restek will also deactivate larger volume vials from our inventory as a custom ordered item. Contact your Restek sales or customer service representative for details. If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely dissolved. Page 5 of 12

6 Catalog #: Target: 100 ug/ml Description: GC Multiresidue Pesticide Std #6 -SPP Solvent: Toluene Solvent Lot: DJ460 Chemical Standard Batch Sheet Lot #:A Final Volume: 100 ml Made by: Rebecca Lauver Date: 4/17/2014 1:31:56PM Tested by: Diane Shaffer Pass Date: 5/6/2014 2:40:52PM By: Diane Shaffer Date: 5/6/2014 2:40:58PM Packaged by: Cheryl Graham / Cheryl Graham Date: 4/17/2014 7:18:51PM No. Units: 71 Pkg Size: 1 ml Balance Used: BEDEARMBALPC3 XP205 Serial #: Compound CAS Cypermethrin Cyfluthrin lambda-cyhalothrin Deltamethrin Fenvalerate Bifenthrin cis-permethrin trans-permethrin Tetramethrin tau-fluvalinate Resmethrin Tefluthrin Phenothrin (cis & trans) Bioallethrin Anthraquinone Flucythrinate Acrinathrin Transfluthrin Storage Target Location Lot # Purity Conc(ug/mL) Target Actual Calc Conc(ug/mL) R mg mg R mg mg R mg mg R mg mg R mg mg R mg mg R mg mg R mg mg R0888 SZBA110XV mg mg R mg mg R B mg mg R mg mg R1232 SZBD221XV mg mg 99.8 R mg mg 99.5 R DC mg mg R A mg mg R mg mg R mg mg Page 6 of 12

7 CERTIFIED REFERENCE MATERIAL 110 Benner Circle Bellefonte, PA Tel: (800) Fax: (814) Certificate of Analysis FOR LABORATORY USE ONLY-READ SDS PRIOR TO USE. This Reference Material is intended for Laboratory Use Only as a standard for the qualitative and/or quantitative determination of the analyte(s) listed. Catalog No. : Lot No.: A Description : GC Multiresidue Pesticide Std #6 -SPP Container Size : GC Multiresidue Pesticide Std #6 -SPP 100µg/mL,Toluene, 1mL/ampul 2 ml > 1 ml Pkg Amt: Expiration Date : December 31, 2015 Storage: 10 C or colder Handling: This product is photosensitive. C E R T I F I E D V A L U E S Elution Order Compound Grav. Conc. (weight/volume) 1 Tefluthrin CAS # (Lot 11017) 2 Transfluthrin CAS # (Lot ) 3 Anthraquinone CAS # (Lot 07222DC) 4 Bioallethrin 99.5 µg/ml CAS # (Lot 00610) Purity 93% 51% Isomer 2; 49% Isomer 1 5 Resmethrin CAS # (Lot A) 97% trans Isomer; 3% cis Isomer 6 Tetramethrin CAS # (Lot SZBA110XV) Purity 98% 23% Isomer 1; 77% Isomer 2 7 Bifenthrin CAS # (Lot ) 8 Phenothrin (cis & trans) 99.6 µg/ml CAS # (Lot 01115) Purity 94% 77% trans Isomer; 23% cis Isomer Expanded Uncertainty (95% C.L.; K=2) +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml Page 7 of 12

8 9 lambda-cyhalothrin CAS # (Lot ) Purity 98% 10 Acrinathrin CAS # (Lot 70830) 11 cis-permethrin CAS # (Lot ) 12 trans-permethrin CAS # (Lot 00908) 13 Cyfluthrin (baythroid) CAS # (Lot ) Purity 98% 25% Isomer 1; 33% Isomer 2; 24% Isomer 3; 18% Isomer 4 14 Cypermethrin CAS # (Lot ) 32% Isomer 1; 29% Isomer 2; 24% Isomer 3; 15% Isomer 4 15 Flucythrinate µg/ml CAS # (Lot A) Purity 92% 62% Isomer 1; 38% Isomer 2 16 Fenvalerate CAS # (Lot ) 68% R Isomer; 32% S Isomer 17 tau-fluvalinate (Mavrik) CAS # (Lot ) 53% Isomer 1; 47% Isomer 2 18 Deltamethrin CAS # (Lot ) +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml +/ µg/ml Solvent: Toluene CAS # Purity % Page 8 of 12

9 Column: 30m x 0.25mm x 0.25µm Rtx-5 (cat.#10223) Carrier Gas: hydrogen-constant pressure 10 psi. Temp. Program: 100 C (hold 1 min.) to C/min. (hold 5 min.) Inj. Temp: 250 C Det. Temp: 330 C Det. Type: FID This chromatogram represents a general set of testing conditions chosen for product acceptance. For optimal results in your lab, conditions should be adjusted for your specific instrument, method, and application. Date Mixed: 04-Dec-2013 Balance: B Date Passed: 06-May-2014 Manufactured under Restek's ISO 9001:2008 Registered Quality System Certificate #FM Page 9 of 12

10 General Certified Reference Material Notes Expiration Notes: Expiration date valid for unopened ampul stored in compliance with the recommended conditions. Uncertainty, concentration, and expiration of the CRM are based on the unopened product being stored according to the recommended condition found in the storage field. Purity Notes: Purity and/or chemical identity are determined by one or more of the following techniques: GC/FID, HPLC, GC/µECD, GC/MS, LC/MS, RI, and/or melting point. Compounds with a listed purity of less than 99% have been weight corrected to compensate for impurities and/or salts. A correction factor is used to calculate the amount of compound necessary to achieve the desired concentration of the parent compound in solution. Purity of isomeric compounds is reported as the sum of the isomers. Purity values are rounded to the nearest whole number. Certified Uncertainty Value Notes: The uncertainties are determined in accordance with ISO Guides 34 and 35. The certified combined stressed uncertainty value ( includes gravimetric uncertainty, homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty and were combined using the following formula: k is a coverage factor of 2, which gives a level of confidence of approximately 95%. It is important to note that the shipping stability uncertainty was obtained under temperature extremes for specific time intervals; therefore, the certified combined stressed uncertainty value should only be applied to the product if it was stored at non-standard temperature conditions up to and including 7 days. Contact Restek Technical Service at for use recommendations if your shipment was in-transit for more than 7 days at nonstandard temperature conditions. Apply the certified combined unstressed uncertainty value if the product was received under standard shipping conditions. Apply the certified combined stressed uncertainty value if the product was received under non-standard conditions as specified below. Label Conditions 25 C Nominal (Room Temperature) 10 C or colder (Refrigerate) 0 C or colder (Freezer) Standard Conditions < 60 C < 40 C < 25 C Non-Standard Conditions 60 C up to 7 days 40 C up to 7 days 25 C up to 7 days Separate (not combined) uncertainty values for gravimetric uncertainty are also displayed on the certificate, if needed, separate homogeneity between-ampul uncertainty, storage stability uncertainty and shipping stability uncertainty values are available by contacting Restek Technical Service at The packaged amount is the minimum sample size for which uncertainty is valid. The ampules are over-filled to ensure that the minimum packaged amount can be sufficiently transferred. Manufacturing Notes: Concentration is based upon gravimetric preparation using either a balance whose calibration has been verified daily using NIST traceable weights, and/or dilutions with Class A glassware. Handling Notes: Samples should be transferred into deactivated vials for handling and storage. Restek supplies deactivated vials along with most standards packed in 2 ml ampules. Due to space constraints, Restek does not supply vials for larger volume ampules. Restek sells DMDCS for the purpose of glassware deactivation as catalog number 31840, which includes complete instructions. Restek will also deactivate larger volume vials from our inventory as a custom ordered item. Contact your Restek sales or customer service representative for details. If any undissolved material is visible inside the ampul, sonicate the unopened ampul until the material is completely dissolved. Page 10 of 12

11 Catalog #: Target: 100 ug/ml Description: GC Multiresidue Pesticide Std #6 -SPP Solvent: Toluene Solvent Lot: DI125 Chemical Standard Batch Sheet Lot #:A Final Volume: 100 ml Made by: Joe Tallon Date: 12/26/2013 4:03:14PM Tested by: Diane Shaffer Pass Date: 5/6/2014 2:41:46PM By: Diane Shaffer Date: 5/6/2014 2:41:49PM Packaged by: Alexandria Pavkovich / Alexandria Pavkovi Date: 12/4/2013 9:22:15PM No. Units: 73 Pkg Size: 1 ml Balance Used: BEDEARMBALPC6 XP205 Serial #: B Compound CAS Cypermethrin Cyfluthrin (baythroid) lambda-cyhalothrin Deltamethrin Fenvalerate Bifenthrin cis-permethrin trans-permethrin Tetramethrin tau-fluvalinate (Mavrik) Resmethrin Tefluthrin Phenothrin (cis & trans) Bioallethrin Anthraquinone Flucythrinate Acrinathrin Transfluthrin Storage Target Location Lot # Purity Conc(ug/mL) Target Actual Calc Conc(ug/mL) R mg mg R mg mg R mg mg R mg mg R mg mg R mg mg R mg mg R mg mg R0888 SZBA110XV mg mg R mg mg R A mg mg R mg mg R mg mg 99.6 R mg mg 99.5 R DC mg mg R A mg mg R mg mg R mg mg Page 11 of 12

12 QA Report: GC Multiresidue Pesticide Std #6 -SPP (Cat.#32568) Runs of Lot # A Runs of Lot # A COMPONENT Run #1 Run #2 Run #3 AVG STD DEV % RSD Run #1 Run #2 Run #3 AVG STD DEV % RSD %D MEAN P/F Tefluthrin PASS Transfluthrin PASS Anthraquinone PASS Bioallethrin PASS Bioallethrin PASS Total Bioallethrin PASS Resmethrin PASS Tetramethrin PASS Bifenthrin & Tetramethrin PASS Phenothrin FAILED! Phenothrin PASS Total Phenothrin PASS lambda-cyhalothrin PASS Acrinathrin PASS cis-permethrin PASS trans-permethrin PASS Cyfluthrin PASS Cyfluthrin PASS Cyfluthrin PASS Cyfluthrin PASS Total Cylfluthrin PASS Cypermethrin PASS Cypermethrin PASS Cypermethrin PASS Total Cypermethrin PASS Flucythrinate 1 1& Cypermethrin PASS Flucythrinate PASS Total Flucythrinate PASS Fenvalerate PASS tau-fluvalinate 1 & Fenvalerate PASS tau-fluvalinate PASS Deltamethrin PASS Page 12 of 12 5/6/2014 2:39:55 PM 1/1-1