Safety Data Sheet. Datasheet No. L 334. Date of issue: Revision date: Version No.: 3 page 1/ Product identifier

Transcription

1 Version No.: 3 page 1/12 SECTION 1: Identification of the substance/mixture and of the company 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against. Identified uses: Multiseasonal long life engine coolant. Designed for all vehicles with liquid cooling system of any type. Also recommended for aluminium radiators. Uses advised against: Not specified Details of the supplier of the safety data sheet Supplier: ZAKŁADY CHEMICZNE ORGANIKA Spółka Akcyjna Address: Łódź, ul. Ciasna 21 a, Poland Tel.: Fax: of the person responsible for the safety data sheet: bbrzezinska@mail.organika.com.pl 1.4. Emergency telephone number (8:00 a.m. 4:00 p.m.) Police (24/24) National Fire Service (24/24) Emergency Care (24/24) emergency telephone number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification of the mixture according to Directive 1999/45/EC. Mixture classified as dangerous. Human health hazards: Environmental hazards: Physical and chemical hazards: Harmful product. (Xn) Harmful if swallowed. (R22) Mixture not classified as dangerous for the environment. Mixture not classified as dangerous due to physicochemical properties.

2 Version No.: 3 page 2/ Label elements Labelling of the mixture according to Directive 1999/45/EC: Xn Harmful R22 Harmful if swallowed. S(2-) Keep out of reach of children. S24/25 Avoid skin and eye contamination. S46 If swallowed, seek medical advice immediately and show this container or label. Contains: ethylene glycol Other hazards No data available SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable Mixtures The mixture is a water solution of ethylene glycol with the addition of corrosion inhibitors and other conditioners. Dangerous substances present in the mixture: Substance name Substance identifiers 2-ethylhexanoic acid potassium salt Index No.: - EC No.: CAS No.: Registration No. Ethylene glycol Index No.: EC No.: CAS No.: not registered yet Concentration Classification % (m/m) in accordance with Council Directive 67/548/EEC Classification in accordance with Regulation (EC) No. 1272/2008 (CLP) Hazard class and category codes Hazard statement codes Acute Tox. 4 H302 STOT RE. 2 H Repr. 2 H361d

3 Version No.: 3 page 3/12 Letter symbols and hazard type phrases (R and H) are given in full in Section 16 of the safety data sheet. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Bring the exposed person to the fresh air. If unconscious, ensure airways are clear and provide breathing. In case of difficulties in breathing provide a medical assistance. Contact with skin: In case of a spill on the skin remove the contaminated clothes. Immediately wash the contaminated skin with plenty of water with soap. Call a doctor in case of skin irritation. Contact with eyes: In case of eye contact remove the contact lenses immediately and rinse the eye with a continuous jet of water for about 15 minutes, holding the eyelids open. If one eye is contaminated, protect the other eye during the rinsing against contamination. If irritation persists, provide an ophthalmologic consultation. Digestive tract: Wash mouth thoroughly with water, and then, drink ml of water. Never give any water to unconscious person. Immediately get medical attention Most important symptoms and effects, both acute and delayed Acute exposure effects (data for ethylene glycol): Ingestion is the most frequent way of poisoning. At the first stage of poisoning, which occurs right after the substance is swallowed, symptoms are similar to the effects of alcohol consumption: state of excitation, speech disorders, balance disorders, abnormal coordination, headaches and dizziness, somnolence, etc.; the following stage includes retching and vomits, diarrhoea; possibly breathing disorders; in case of heavy poisonings also circulation disorders, tachycardia, decreased blood pressure, coma, loss of consciousness with seizures, collapse; possible death as a result of respiratory arrest. Lethal dose for human is about 100 ml. In case of skin contact the substance causes light irritation. Prolonged eye contamination results in medium eye irritation. Chronic exposure effects (data for ethylene glycol): The substance can intensify existing skin, eye and respiratory tract ailments. It can also cause kidney and liver disorders and damages; possible brain damage Indication of immediate medical attention and special treatment needed Do not induce vomiting or give anything by mouth to an unconscious person. Show this Safety Data Sheet, label or container to medical personnel. Notice to physician (data for ethylene glycol): Treatment of ethylene glycol poisoning should include the following actions dependent on patient s condition: stomach lavage within 2 hours from swallowing, controlling circular and respiratory disorders, administration of ethyl alcohol (intravenous drop infusion 5 15 % ethyl alcohol solution in 5 % glucose); in case of severe poisonings apply haemodialysis, diuresis. SECTION 5: Fire-fighting measures Non-flammable mixture. In case of fire close to the mixture follow these recommendations: 5.1. Extinguishing media

4 Version No.: 3 page 4/12 Appropriate extinguishing media: Alcohol-resistant foam, water dispersed flow, carbon dioxide, extinguishing powders. Inappropriate extinguishing media: Do not use a strong jet of water Special hazards arising from the substance or mixture May produce carbon oxides if burning Advice for firefighters Use full protective clothing and a breathing apparatus. Cool packages exposed to fire or high temperature with a dispersed flow of water; if possible remove from the hazard area. SECTION 6: Accidental release measures 6.1. Emergency precautions, personal protective equipment and procedures Avoid contact with the mixture. When collecting spills wear protective clothing, protective gloves, safety glasses (goggles) Environmental precautions Collect or pump the spill to separate containers for elimination or further processing. Prevent the mixture to enter sever system or groundwater using prisms of sand Methods and means of preventing spread of the contamination and removing contamination Sprinkle sand over small spills and then collect, with a shovel, the sand impregnated with the spilled mixture to containers for further elimination. Wash contaminated areas with a large amount of water. If the situation goes out of control, call the Chemical Rescue Service. Notify relevant authorities if the mixture enters groundwater Reference to other sections Refer to Section 8 for information on personal protective equipment. Eliminate in accordance with recommendations listed in Section 13. SECTION 7: Handling and storage of substances and mixtures 7.1. Precautions for safe handling Follow general rules concerning health and safety at work when using the mixture. Use personal protective equipment (Subsection 8.2). Avoid contact with skin and eyes. Do not eat, drink or smoke in the workplace. Always wash your hands after handling the mixture Conditions for safe storage, including any incompatibilities The mixture should be stored in warehouse premises whose maximum temperature is 40 C. Drums and IBC containers with the mixture can be stored in a storage yard, too. Keep containers tightly closed. Shelf life 5 years from the date of production Specific end use(s) Designed for all vehicles with liquid cooling system of any type. No information on particular end uses.

5 Version No.: 3 page 5/12 SECTION 8: Exposure control/personal protection 8.1. Control parameters According to the Minister of Work and Social Policy Regulation of on threshold limit concentrations and intensities of health-hazardous factors in the working environment (Dz. U. [Journal of Laws], No. 217, item 1833; of 2005, Dz. U. No. 212, item 1769; of 2007, Dz. U. No. 161, item 1142; of 2009, Dz. U. No. 105, item 873; of 2010, Dz. U. No. 141, item 950), the values of maximum allowable concentrations for the substances contained in the mixture are: Hazardous component name CAS NDS (TLV-TWA) NDSCh mg/m 3 (TLV- STEL) mg/m 3 Ethylene glycol DNEL and PNEC values (data for ethylene glycol): DNEL value for workers for long-term dermal exposure (systemic effect): 106 mg/kg b.w. DNEL value for workers for long-term exposure by inhalation (local effect): 35 mg/kg b.w. DNEL value for general population, including consumers, under prolonged exposure to skin contact (systemic effect): 53 mg/kg b.w. DNEL value for general population, including consumers, under prolonged exposure to inhalation (local effect): 7 mg/kg b.w. PNEC value for fresh water environment: 10 mg/l PNEC value for sea water environment: 1 mg/l PNEC value for mixed water environment: 10 mg/l PNEC value for deposit environment (fresh water): 20.9 mg/kg PNEC value for soil environment: 1.53 mg/kg PNEC value for sewage treatment plants environment: 199 mg/l 8.2. Exposure controls Applicable technical control measures: Industrial use (product confectioning into single containers): A local exhaust ventilation and general ventilation should be provided in the work area. Professional application (filling cooling systems with coolant): Short-term exposition ventilation is not required. Consumer application (filling cooling systems with coolant): Short-term exposition ventilation is not required Individual protection measures, such as personal protective equipment Eye/face protection: Skin protection: Hand protection: Respiratory tract protection: protective air-tight cover goggles. protective clothing. natural rubber, neoprene or PCV gloves resistant to chemicals, compliant to PN-EN 374-1:2005 standard. not required under normal conditions of use. NDSP (TLV- CL) mg/m Environmental exposure controls Prevent the mixture from penetrating into the underground waters, waste waters, sewage systems or soil.

6 Version No.: 3 page 6/12 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties. a) Appearance: Physical state homogeneous, clear liquid, free from deposits and mechanical contaminations Colour fluorescence pink b) Odour: little c) Odour threshold: no data available d) ph of the mixture at 20 C e) Freezing point: -35 C f) Initial boiling point and the range of boiling points: > C g) Flash point: non-flammable h) Evaporation rate: no data available i) Flammability (solid, gas) not applicable the mixture is liquid j) Upper/lower flammability or explosive limits: lower limit 3.2 % (V/V) (for ethylene glycol), upper limit 15.3 % (V/V) (for ethylene glycol), k) Vapour pressure at 25 C: hpa (for ethylene glycol) l) Vapour density: no data available m) Density at 20 C: g/ml n) Solubility: easily soluble in water, soluble also in ethanol, acetone, acetic acid, pyridine o) Partition coefficient n-octanol/water: log K (o/w) (for ethylene glycol) p) Auto-ignition temperature: no data available q) Decomposition temperature: no data available r) Viscosity (20 C): no data available s) Explosive properties: no data available t) Oxidising properties: not applicable 9.2. Other information no data available SECTION 10: Stability and reactivity Reactivity Particular hazards due to product reactivity not found Chemical stability The mixture is stable in standard conditions Possibility of hazardous reactions No data Conditions to avoid Temperature over 40 C Incompatible materials Strong acids (chrolosulphonic acid, sulphuric acid, oleum, perchloric acid), strong alkalies (sodium hydroxide), dimethyl terephthalate, phosphorus pentasulphide, strong oxidisers.

7 Version No.: 3 page 7/ Hazardous decomposition products No hazardous decomposition products formed as a result of use, storage or spilling of the mixture are known. Combustion products in case of fire are listed in Section 5. Section 11: Toxicological information Information on toxicological effects a) acute toxicity: Data for ethylene glycol Acute toxicity ingestion: LD 50 = 7112 mg/kg, rat Acute toxicity skin: LD 50 > 3500 mg/kg, rat Acute toxicity inhalation: LC 50 > 2.5 mg/l (6 h), rat b) irritation: Assessment of product s irritating effects indicates that (because of no irritating ingredients contained) it is non-irritant for eyes and skin. c) corrosivity: Corrosivity assessment (due to the lack of corrosive components) indicates that the product is not corrosive. d) repeated dose toxicity: The product contains ethylene glycol which consumed repeatedly in large doses can cause a kidney damage as shown in the tests on rats. e) sensitisation: Sensitisation assessment (due to the lack of sensitising components) indicates that the product is not sensitising for the respiratory tract and skin. f) carcinogenicity: Assessment of product s carcinogenicity indicates that (because of no carcinogenic ingredients contained) it is not carcinogenic. g) mutagenicity: Mutagenicity assessment (due to the lack of mutagenic components) indicates that the product does not affect germ cells. h) toxicity for reproduction: Product contains 2-ethylhexanoic acid sodium salt which entails risk of harm to the unborn child. Assessment of product s adverse effects on reproduction indicates that (because of the amount of the aforementioned ingredient) it should have no adverse effects on reproduction. Probable ways of exposure: Skin, eyes, respiratory tract, gastrointestinal tract. Effects and symptoms of exposure: Skin: Light skin irritation. Eyes: Prolonged contact results in medium eye irritation Respiratory tract: Long-term exposure or high concentration of vapours or mist may result in light irritation of respiratory tract, headaches and dizziness. Can cause depression and have effects similar to drugs. Symptoms can be similar to food poisoning. Ingestion: Harmful product. Harmful if swallowed. At the first stage symptoms are similar to the effects of alcohol consumption: state of excitation, speech disorders, balance disorders, abnormal coordination, headaches and dizziness, somnolence. Later retching and vomits occur. After a few or more hours from ingestion of a large amount of substance occur loss of consciousness with circular disorders, tachycardia, arrhythmia, increase and sudden drop of blood pressure, collapse, breathing disorders or damages to kidneys. In severe cases lesions in the nervous system may occur.

8 Version No.: 3 page 8/12 Symptoms of chronic intoxication: The substance can intensify existing skin, eye and respiratory tract ailments. It may cause kidney and liver disorders and damages; possible damage to central nervous system. SECTION 12: Ecological information Toxicity Data for ethylene glycol: Acute toxicity to aquatic organisms fish Pimephales promelas LC 50 /96 h: 72,860 mg/l daphnia Daphnia magna EC 50 /48 h: 13,900 57,600 mg/l algae Pseudokirchnerella subcapitata EC 50 (96 h): ,000 mg/l Long-term toxicity to aquatic organisms fish Pimephales promelas NOEC (7 d): 15,380 mg/l daphnia Ceriodaphnia sp NOEC (7 d): 8590 mg/l Microorganism toxicity bacteria Pseudomonas putida TTC (EC 5 (16 h)): > 10,000 mg/l activated sludge in waste treatment plant EC20 (30 min): > 1995 mg/l Data concerning acute and chronic ecotoxicity to water organisms show that ethylene glycol poses no threat to water environment and biological sewage treatment plants Persistence and biodegradability Data for ethylene glycol: No data on hydrolysis. Similar to other ethers and glycols, ethylene glycol i considered as stable to hydrolysis and easily biodegradable. Biodegradability within 10 days is % (DOC test) and according to OECD s criteria it is considered as a biodegradable substance. In the air after evaporation the substance decomposes slowly (by means of indirect photodegradation) by reacting with free radicals (DT 50 is about 46.3 h) Bioaccumulative potential The mixture should not be expected to be bioaccumulative Data for ethylene glycol: Accumulation of the substance in organism is not expected, based on the estimated value of adsorption coefficient (log Koc = 0) and the values of partition coefficient octanol/water (log Kow = -1.36) Mobility in soil If the mixture enters soil, it will migrate and may contaminate groundwater.

9 Version No.: 3 page 9/ Results of PBT and vpvb assessment Data for ethylene glycol Ethylene glycol does not meet the PBT and vpvb criteria. According to review of available data it can be assessed that the other mixture ingredients are not considered to be PBT and vpvb substances Other adverse effects No environmental hazard is expected provided that the mixture is handled correctly. SECTION 13: Disposal considerations Waste treatment methods Mixture waste: mixture waste should be first recycled; if it is not possible, it should be neutralised by biological, physical or chemical treatment. Mixture waste must not enter the sewer system. Pass to an approved company with an authorisation for waste collection and elimination. Packaging waste: If an elimination is needed, empty the contaminated packagings and pass to special companies with an authorisation of the relevant institutions for management of packaging waste. Waste classification: relevant for the production site based on the criteria from the applicable regulations. In case of using product for any further operations/processes the final user shall identify produced waste and assign it respective code on his own. Act from 27 April 2001 on waste. (Dz. U. [Journal of Laws] No. 62, item 628 of 20 June 2001) with further amendments. Minister of Environment Regulation of 27 September 2001 on waste catalogue (Dz. U. [Journal of Laws] No. 112, item 1206) with further amendments. SECTION 14: Transport information The mixture is not subject to the regulations concerning the transport of dangerous goods. The mixture can be transported by any means of transport, according to the applicable transport regulations UN number - not applicable UN proper shipping name - not applicable Transport hazard class(es) class classification code: hazard identification number: - not applicable - not applicable - not applicable Packing group - not applicable Environmental hazards - not applicable Special precautions for users - no particular recommendations Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code - not applicable

10 Version No.: 3 page 10/12 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Regulation (EC) No. 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No. 793/93 and Commission Regulation (EC) No. 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC (OJ EU L 396 of , page 1, OJ EU L 136 of , page 3 as amended). Commission Regulation (EU) No. 453/2010 of 20 May 2010 amending Regulation (EC) No. 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (OJ EU L 133 of p. 1). Act of 25 February 2011 on chemical substances and their mixtures (Dz. U. [Journal of Laws] of 2011, No. 63, item 322). Minister of Health Regulation of 8 February 2010 on the list of dangerous substances, their classification and labelling (Dz. U. [Journal of Laws] No. 27, item 140). Regulation (EC) No. 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No. 1907/2006 (OJ EU L 353 of , p. 1). Commission Regulation (EC) No 790/2009 of 10 August 2009 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No. 1272/2008 of 16 December 2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures (OJ EU L 235 of , p. 1). Minister of Health Regulation of 2 September 2003 on criteria and methods of classification of chemical products and preparations (Dz. U. [Journal of Laws] No. 171, item 1666; of 2004, Dz. U. No. 243, item 2440; of 2007, Dz. U. No. 174, item 1222 and of 2009, Dz. U. No. 43, item 353). Minister of Health Regulation of 5 March 2009 on the labelling of packages of dangerous substances and dangerous preparations and some preparations (Dz. U. [Journal of Laws] No. 53, item 439). Minister of Health Regulation of 29 April 2010 on categories of dangerous substances whose packagings are supplied with children access limiting closures and touch-sensed danger warning (Dz. U. [Journal of Laws] No. 83, item 544). Act of 12 December 2003 on general safety of products (Dz. U. [Journal of Laws] No. 229, item 2275) with further amendments. Act of 28 October 2002 on road transport of dangerous goods (Dz. U. [Journal of Laws] No. 199, item 1671) with further amendments Chemical safety assessment Safety assessment was prepared for ethylene glycol. The safety assessment of the remaining components of the product has not been carried out.

11 Version No.: 3 page 11/12 SECTION 16: Other information Changes to the safety data sheet: The safety data sheet has been updated for formal reasons and for the need of consideration of new versions of safety data sheets for raw materials provided by suppliers. The update concerns all 16 sections. Meaning of hazard symbols and full text of the risk phrases (R phrases), listed in Section 3 of the safety data sheet: Xn R22 R63 Harmful product. Harmful if swallowed. Possible risk of harm to the unborn child. Explanation of acronyms and abbreviations: Acute Tox. 4 Acute toxicity, hazard category 4 Repr. 2 Harmful for reproduction, hazard category 2 STOT RE. 2 Specific target organ toxicity repeated exposure; STOT repeated exposure, hazard category 2 NDS (TLV-TWA) Maximum allowable concentration NDSCh (TLV- Maximum allowable momentary concentration STEL) NDSP (TLV-CL) Maximum allowable limit concentration vpvb Very persistent and very bioaccumulative substance PBT Persistent, bioaccumulative and toxic substance DNEL Derived no-effect level PNEC Predicted environmental no-effect concentration LD 50 The dose observed to kill 50 % of the tested population of animals EC 50 The concentration observed to kill 50 % of the tested population of animals OECD Organisation for Economic Co-operation and Development Full text of the hazard phrases (H phrases), listed in Section 3 of the safety data sheet: H302 H361d H373 Data sources: Components safety data sheets. Harmful if swallowed. Suspected of damaging the unborn child. May cause damage to kidneys through prolonged or repeated exposure. Necessary trainings: The workers should be trained for correct handling of the mixture. Read the safety data sheet before using the product. Use: For professional use. Possibility to obtain further information: Contact the supplier in order to obtain further information. Additional information on mixture ingredients: Classification for not yet registered substances listed in Section 3.2 was converted from the one introduced by Directive 67/548/EEC into classification assumed in accordance with Regulation (EC) No. 1272/2008 by use of Conversion table listed in Annex VII thereto.

12 Version No.: 3 page 12/12 The safety data sheet has been designed based on the safety data sheets of raw materials contained in the mixture and on the own current knowledge. The safety data sheet provides the data relevant for the safety and health protection of human and environment. None of the information included herein shall be considered as a guaranty of mixture properties.