SAFETY DATA SHEET according to Regulation (EC) No. 453/2010

Transcription

1 SAFETY DATA SHEET according to Regulation (EC) No. 453/2010 Mida CHRIOX 5 Page: 1/8 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Chemical type : Mixture Trade name : Mida CHRIOX 5 Product code : Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Description/Application Industrial/Professional use spec Uses advised against No uses adviced against 1.3. Details of the supplier of the safety data sheet Christeyns NV Afrikalaan GENT België T +32 (0)9/ F +32 (0)9/ info@christeyns.be Emergency telephone number National Poisons Information Service worldwide: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture : Stabilised mixture of peracetic acid, hydrogen peroxide, acetic acid and water. Oxygenbased bleaching agents. Disinfectant. : For professional use only Industrial Classification according to Regulation (EC) No. 1272/2008 [CLP] Ox. Liq. 2 Met. Corr. 1 Acute Tox. 4 (Oral) Acute Tox. 4 (Inhalation:dust,mist) Skin Corr. 1B STOT SE 3 Aquatic Chronic 1 Full text of hazard classes and Hstatements : see section 16 H272 H290 H302 H332 H314 H335 H Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] O; R7 Xn; R22 C; R34 Full text of Rphrases: see section Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : CLP Signal word Hazardous ingredients Hazard statements (CLP) : Danger GHS03 GHS05 GHS07 GHS09 : Peracetic acid; Hydrogen peroxide : H272 May intensify fire; oxidiser H290 May be corrosive to metals H302+H332 Harmful if swallowed or if inhaled H314 Causes severe skin burns and eye damage

2 Page: 2/8 Precautionary statements (CLP) EUHstatements 2.3. Other hazards H335 May cause respiratory irritation H410 Very toxic to aquatic life with long lasting effects : P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking P234 Keep only in original container P260 Do not breathe vapours, mist, spray P280 Wear protective gloves, protective clothing, eye protection, face protection P284 [In case of inadequate ventilation] wear respiratory protection P303+P361+P353+P310 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician P305+P351+P338+P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician P403+P235 Store in a wellventilated place. Keep cool : EUH071 Corrosive to the respiratory tract Substance meets the criteria for PBT according to regulation (EG) n. 1907/2006, annex XIII : Not applicable P : no B : no T : no Substance meets the criteria for vpbt according to regualtion (EG) n. 1907/2006, annex XIII : vp : not vb : not SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC Hydrogen peroxide (CASno) (Einecs nr) (EG annex nr) (REACHno) R5 O; R8 C; R35 Xn; R20/22 Acetic acid (CASno) (Einecs nr) (EG annex nr) (REACHno) Peracetic acid (CASno) (Einecs nr) (EG annex nr) (REACHno) R10 C; R R10 O; R7 Xn; R20/21/22 C; R35 N; R50 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Hydrogen peroxide (CASno) (Einecs nr) (EG annex nr) (REACHno) Acetic acid (CASno) (Einecs nr) (EG annex nr) (REACHno) Peracetic acid (CASno) (Einecs nr) (EG annex nr) (REACHno) Full text of R and Hstatements: see section Ox. Liq. 1, H271 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Corr. 1A, H314 STOT SE 3, H335 Aquatic Chronic 3, H Flam. Liq. 3, H226 Skin Corr. 1A, H Flam. Liq. 3, H226 Org. Perox. D, H242 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Skin Corr. 1A, H314 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 (M=10) SECTION 4: First aid measures 4.1. Description of first aid measures General advice Inhalation : In case of doubt or persistent symptoms, consult always a physician. : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If necessary administer pulmonary resuscitation or oxygen, and keep warm.

3 Skin contact Eye contact Ingestion Mida CHRIOX 5 Page: 3/8 : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. : Rinse mouth out with water. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician Most important symptoms and effects, both acute and delayed Acute effects inhalation Acute effects skin Acute effects eyes Acute effects oral route : May cause respiratory irritation. : Causes severe burns. : Corrosive to eyes. : Harmful if swallowed. Burns of the upper digestive and respiratory tracts Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : water in large amounts Special hazards arising from the substance or mixture Fire hazard Explosion hazard : Heating may cause a fire. : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries Advice for firefighters Special protective equipment for firefighters Firefighting instructions Protection during firefighting : Use selfcontained breathing apparatus and chemically protective clothing. : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent firefighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For nonemergency personnel Wear protective clothing. Evacuate personnel to a safe area For emergency responders 6.2. Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Absorb spilled material with sand or earth. Do NOT absorb in sawdust, paper, cloth or other combustible absorbents Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not eat, drink or smoke in areas where product is used. Shower, eyes shower and water point in proximity. Wear personal protective equipment (see item 8). Ventilation, local exhaust, or breathing protection. Avoid aerosolbuilding. Never return unused material to original container. Handle and open container with care. When handling product, avoid contact with eyes, skin and clothing. Keep container tightly closed in a cool place Conditions for safe storage, including any incompatibilities Protect material from direct sunlight. Keep away from open flames, hot surfaces and sources of ignition. Keep away from incompatible products/materials (see section 10). Recommended storage temperature: between 20 C and 30 C. Keep only in the original container Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Hydrogen peroxide ( ) United Kingdom WEL TWA (mg/m³) 1,4 mg/m³ United Kingdom WEL TWA (ppm) 1 ppm United Kingdom WEL STEL (mg/m³) 2,8 mg/m³ United Kingdom WEL STEL (ppm) 2 ppm

4 Page: 4/ Exposure controls Hand protection Eye protection : Safety glasses with sideshields (EN 166). Protective equipment Respiratory protection SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Physical state/form Colour Odour Odour threshold : Chemical resistant PVC/Nitrilrubber gloves (to European standard EN 374 or equivalent). Thickness: 0,4 mm. Penetration time: >480 min (level 6). The selection of specific gloves for a specific application and time of use in a working area, should also take into account other factors on the working space, such as (but not limited to): other chemicals that are possibly used, physical requirements (protection against cutting/drilling, skill, thermal protection), and the instructions/specification of the supplier of gloves. : Wear suitable protective clothing (EN 14605). Long sleeved protective clothing. : In case of insufficient ventilation wear suitable respiratory equipment. Extra personal protection: A/P2 filter respirator for organic vapour and harmful dust. : Liquid : Liquid. : clear and colourless. : acrid and pungent. ph : 3.4 ± 0.5 ( aqueous solution of 0.3% ) ; 0.5 ± 0.2(100%) Melting point/range Freezing point Boiling point/boiling range : >= 100 C Flash point : > 80 C Relative evaporation rate (butylacetate=1) Flammability (solid, gas) Explosive limits Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow : 1115 kg/m3 Autoignition temperature : > 250 C Decomposition temperature Viscosity : >= 60 C (SADT for <=1000L and 26m3 noninsulated tank) : < 30 mpa.s dynamic: < 30 mpa.s 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable in use and storage conditions as recommended in item 7. Avoid contamination with organic substances. Contact with alcaline products gives exothermic reaction. Heating may cause a fire Possibility of hazardous reactions Conditions to avoid Direct sunlight. Heating. Heat. Sparks. Open flame Incompatible materials Iron or steel. Copper and copper alloys. Galvanized steel. Strong acids. Strong bases. metals. Never mix with other materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Specific target organ toxicity (single exposure) : Harmful if swallowed. Harmful if inhaled. : Causes severe skin burns and eye damage. : May cause respiratory irritation.

5 Page: 5/8 Mida CHRIOX 5 ATE CLP (oral) ATE CLP (dust,mist) Acetic acid (64197) LD50 oral rat Hydrogen peroxide ( ) LD50 dermal rabbit ATE CLP (oral) ATE CLP (dust,mist) Peracetic acid (79210) ATE CLP (oral) ATE CLP (dermal) ATE CLP (gases) ATE CLP (vapours) ATE CLP (dust,mist) SECTION 12: Ecological information Toxicity Ecology water Acetic acid (64197) LC50 fish 1 EC50 Daphnia 1 EC50 other aquatic organisms 1 ErC50 (algae) Hydrogen peroxide ( ) LC50 fish 1 EC50 Daphnia 1 ErC50 (algae) 500,000 mg/kg bodyweight 1,500 mg/l/4h 3310 mg/kg > 2000 mg/kg 1,193 mg/kg bodyweight 1,500 mg/l/4h 500,000 mg/kg bodyweight 1100,000 mg/kg bodyweight 4500,000 ppmv/4h 11,000 mg/l/4h 1,500 mg/l/4h : Very toxic to aquatic life with long lasting effects. > 300 mg/l > 300 mg/l > 300 mg/l > 300 mg/l 16,4 mg/l 2,4 mg/l 1,38 mg/l Persistence and degradability Peracetic acid (79210) Persistence and degradability Bioaccumulative potential Mobility in soil Biodegradable. OECD 301E method (Ready biodegradability: Modified OECD Screening Test) Results of PBT and vpvb assessment Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste / unused products European List of Waste (LoW) code SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UNNo. (ADR) : UN proper shipping name Proper shipping name : Collect all waste in suitable and labelled containers and dispose according to local legislation. : * aqueous washing liquids and mother liquors : HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE STABILIZED Transport document description (ADR) : UN 3149 HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE STABILIZED, 5.1 (8), II, (E), ENVIRONMENTALLY HAZARDOUS Transport hazard class(es) Class (ADR) : 5.1 Subsidiary risk (ADR) : 8

6 Danger labels (ADR) : 5.1, 8 Page: 6/ Packing group Packing group (UN) : II Environmental hazards Other information : No supplementary information available Special precautions for user Overland transport Hazard identification number (Kemler No.) : 58 Classification code (ADR) : OC1 Special provisions (ADR) : 196, 553 Transport category (ADR) : 2 Tunnel code Limited quantities (ADR) LQ Excepted quantities (ADR) EAC code Transport by sea Air transport : E : 1l : LQ10 : E2 : 2P Instruction "cargo" (ICAO) : 554 Instruction "passenger" (ICAO) : 550 Instruction "passenger" Limited quantities (ICAO) : Y Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EURegulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances Detergent Regulation : Labelling of contents: Component % Oxygenbased bleaching agents 1530% Phosphonates <5% National regulations Chemical safety assessment For the following substances of this mixture a chemical safety assessment has been carried out Peracetic acid SECTION 16: Other information It is recommended to pass the information of this safety data sheet in an appropriate form to the users. Such information is actually the best of our knowledge and believes accurate as reliable. This information relates to the specific material designated and may not be valid in combination with other products. This safety data sheet is in compliance with 1907/2006/EEC. It is user's liabilities to take all necessary measures to meet local required laws and regulations. The producer is not responsable for any damage and loss due to the use of information mentioned in this safety data sheet.

7 Page: 7/8 HISTORY PREVIOUS REVISION DATE : 01/11/2015 REVIEW CHAPTER(S) N : 2,9 Full text of R, H and EUHstatements: Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Flam. Liq. 3 Flammable liquids, Category 3 Met. Corr. 1 Corrosive to metals, Category 1 Org. Perox. D Organic Peroxides, Type D Ox. Liq. 1 Oxidising Liquids, Category 1 Ox. Liq. 2 Oxidising Liquids, Category 2 Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Corr. 1B Skin corrosion/irritation, Category 1B STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H226 Flammable liquid and vapour H242 Heating may cause a fire H271 May cause fire or explosion; strong oxidiser H272 May intensify fire; oxidiser H290 May be corrosive to metals H302 Harmful if swallowed H312 Harmful in contact with skin H314 Causes severe skin burns and eye damage H332 Harmful if inhaled H335 May cause respiratory irritation H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects H412 Harmful to aquatic life with long lasting effects EUH071 Corrosive to the respiratory tract R10 Flammable R20/21/22 Harmful by inhalation, in contact with skin and if swallowed R20/22 Harmful by inhalation and if swallowed. R22 Harmful if swallowed

8 R34 R35 R5 R50 R7 R8 C N O Xn Mida CHRIOX 5 Causes burns Causes severe burns Heating may cause an explosion. Very toxic to aquatic organisms. May cause fire Page: 8/8 Contact with combustible material may cause fire. Corrosive Dangerous for the environment Oxidising Harmful