PRODUCT INFORMATION SHEET

Transcription

1 PRODUCT INFORMATION SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name or designation of the mixture Registration number Synonyms Brand Code Issue date Version number 01 HORIZON DC None. 405C, 731B 12October Relevant identified uses of the substance or mixture and uses advised against Identified uses For Industrial Use Only Uses advised against None known Details of the supplier of the safety data sheet Supplier Company name Address Division HarbisonWalker International 1305 Cherrington Parkway, Suite 100 Moon Township, PA 15108, USA United States Telephone General Phone: CHEMTREC 24 HOUR EMERGENCY # INTERNATIONAL # Contact person 1.4. Emergency telephone number REACH@thinkHWI.com HWI USA SECTION 2: Hazards identification 2.1. Classification of the substance or mixture The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Directive 67/548/EEC or 1999/45/EC as amended This item is defined as an article per OSHA and REACH and is therefore exempt from labeling. A Safety Data Sheet is available This item is not Classified as hazardous per CLP Regulations. However, individual customer processes (such as grinding, sawing, or blasting) may result in the formation of dust that may present health hazards. Limit skin contact. Wash hands after handling. Wear protective gloves/protective clothing/eye protection. Classification according to Regulation (EC) No 1272/2008 as amended This item is defined as an article per OSHA and REACH and is therefore exempt from labeling. A Safety Data Sheet is available This item is not Classified as hazardous per CLP Regulations. However, individual customer processes (such as grinding, sawing, or blasting) may result in the formation of dust that may present health hazards. Limit skin contact. Wash hands after handling. Wear protective gloves/protective clothing/eye protection Label elements Label according to Regulation (EC) No. 1272/2008 as amended This item is defined as an article per OSHA and REACH and is therefore exempt from labeling. A Safety Data Sheet is available This item is not Classified as hazardous per CLP Regulations. However, individual customer processes (such as grinding, sawing, or blasting) may result in the formation of dust that may present health hazards. Limit skin contact. Wash hands after handling. Wear protective gloves/protective clothing/eye protection Other hazards None known. SECTION 3: Composition/information on ingredients 3.2. Mixtures Issue date: 12October / 7

2 General information Chemical name % CASNo. / EC No. REACH Registration No. INDEX No. Notes Mullite 40 < Classification: DSD: Zircon 20 < Classification: DSD: Aluminium Oxide (NonFibrous) 10 < Classification: DSD: Cement, Alumina, Chemicals 1 < Classification: DSD: Other components below reportable levels 10 < 20 List of abbreviations and symbols that may be used above Regulation No. 1272/2008. DSD: Directive 67/548/EEC. M: Mfactor vpvb: very persistent and very bioaccumulative substance. PBT: persistent, bioaccumulative and toxic substance. #: This substance has been assigned Community workplace exposure limit(s). SECTION 4: First aid measures General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Description of first aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Eye contact Ingestion 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Wash off with soap and water. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. Direct contact with eyes may cause temporary irritation. Treat symptomatically. SECTION 5: Firefighting measures General fire hazards 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Special hazards arising from the substance or mixture Use fireextinguishing media appropriate for surrounding materials. Issue date: 12October / 7

3 5.3. Advice for firefighters Special protective equipment for firefighters Special fire fighting procedures SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For nonemergency Keep unnecessary personnel away. For personal protection, see section 8. personnel For emergency responders 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the SDS. Avoid discharge into drains, water courses or onto the ground. Stop the flow of material, if this is without risk. Following product recovery, flush area with water. SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Avoid prolonged exposure. Observe good industrial hygiene practices. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). France. Threshold Limit Values (VLEP) for Occupational Exposure to Chemicals in France, INRS ED 984 Components Type Value Aluminium Oxide (NonFibrous) (CAS ) Biological limit values Recommended monitoring procedures Derived noeffect level (DNEL) Predicted no effect concentrations (PNECs) VME 10 mg/m3 No biological exposure limits noted for the ingredient(s). Follow standard monitoring procedures. Exposure guidelines 8.2. Exposure controls Appropriate engineering controls Zirconium silicates (zircon sands) contain trace amounts ( pci/g) of naturally occurring radioactive uranium and thorium. Overexposure by inhalation to respirable dust containing uranium and thorium may cause lung cancer. Eye contact with the dust may cause eye irritation. Measurements made by Dupont during the use of a similar mineral sand indicated the observance of the 5 mg/m3 OSHA PEL for respirable dust and/or the PEL for quartz ensures the user is below the exposure limits established for uranium and thorium. No LD50 or LC50 can be found for zircon sand. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment General information Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Eye/face protection Skin protection Wear safety glasses with side shields (or goggles). Hand protection Wear appropriate chemical resistant gloves. Issue date: 12October / 7

4 Other Wear suitable protective clothing. Respiratory protection Thermal hazards Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. Wear appropriate thermal protective clothing, when necessary. Hygiene measures Environmental exposure controls Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental manager must be informed of all major releases. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Odour Physical state Form Colour Odour threshold ph Solid. Solid. Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit lower (%) Flammability limit upper (%) Vapour pressure Vapour density Relative density Solubility(ies) Solubility (water) Solubility (other) Partition coefficient (noctanol/water) Autoignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties 9.2. Other information No relevant additional information available. SECTION 10: Stability and reactivity Reactivity The product is stable and nonreactive under normal conditions of use, storage and transport Chemical stability Material is stable under normal conditions Possibility of hazardous reactions No dangerous reaction known under conditions of normal use Conditions to avoid Contact with incompatible materials. Issue date: 12October / 7

5 10.5. Incompatible materials Strong oxidising agents. Incompatibility is based strictly upon potential theoretical reactions between chemicals and may not be specific to industrial application exposure Hazardous decomposition products SECTION 11: Toxicological information General information Information on likely routes of exposure Inhalation Skin contact Eye contact Ingestion Symptoms Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitisation Skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Mixture versus substance information Other information No hazardous decomposition products are known. Occupational exposure to the substance or mixture may cause adverse effects. Prolonged inhalation may be harmful. No adverse effects due to skin contact are expected. Direct contact with eyes may cause temporary irritation. May cause discomfort if swallowed. However, ingestion is not likely to be a primary route of occupational exposure. Exposure may cause temporary irritation, redness, or discomfort. No data available. No information available. SECTION 12: Ecological information Toxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment Persistence and degradability Bioaccumulative potential Partition coefficient noctanol/water (log Kow) No data is available on the degradability of this product. No data available. Bioconcentration factor (BCF) Mobility in soil No data available Results of PBT and vpvb assessment Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: Disposal considerations Waste treatment methods Residual waste Contaminated packaging EU waste code Issue date: 12October / 7

6 SECTION 14: Transport information ADR RID ADN IATA IMDG Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Regulation (EC) No. 2037/2000 on substances that deplete the ozone layer, Annex I Regulation (EC) No. 2037/2000 on substances that deplete the ozone layer, Annex II Regulation (EC) No. 850/2004 on persistent organic pollutants, Annex I Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1 Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 2 Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 3 Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA Authorisations Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended Restrictions on use Regulation (EC) No. 1907/2006 Annex XVII Substances subject to restriction on marketing and use Not regulated. Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding Other EU regulations Directive 96/82/EC (Seveso II) on the control of majoraccident hazards involving dangerous substances Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work Directive 94/33/EC on the protection of young people at work Other regulations The product is classified and labelled in accordance with EC directives or respective national laws. Issue date: 12October / 7

7 National regulations Chemical safety assessment Follow national regulation for work with chemical agents. No Chemical Safety Assessment has been carried out. SECTION 16: Other information References Information on evaluation method leading to the classification of mixture Full text of any statements or Rphrases and Hstatements under Sections 2 to 15 Revision information Training information Disclaimer None. Product and Company Identification: Product and Company Identification Composition / Information on Ingredients: After Reaction Composition This information is based on our present knowledge on creation date. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Issue date: 12October / 7