SAFETY DATA SHEET. SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name or designation of the mixture Registration number Synonyms - None. Product code Issue date Version number 00 Revision date Supersedes date - 30-April April Relevant identified uses of the substance or mixture and uses advised against Identified uses Uses advised against Industrial Leak Sealant. None known Details of the supplier of the safety data sheet Manufacturer/Supplier Team Industrial Services, Inc. Address Postbus AA Vlissingen 3237 The Netherlands Telephone +31 (0) Fax +31 (0) Contact person 1.4. Emergency telephone +(61) , number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Directive 67/548/EEC or 1999/45/EC as amended This preparation does not meet the criteria for classification according to Directive 1999/45/EC as amended. Classification according to Regulation (EC) No 1272/2008 as amended Health hazards Skin corrosion/irritation Serious eye damage/eye irritation Category 2 Category 2 H315 - Causes skin irritation. H319 - Causes serious eye irritation. Hazard summary Physical hazards hazards Environmental hazards Specific hazards Main symptoms 2.2. Label elements Not classified for physical hazards. Health Not classified for health hazards. Not classified for hazards to the environment. During curing/hydrolysis the product may release methanol. Label according to Regulation (EC) No. 1272/2008 as amended Hazard pictograms Irritation of eyes and mucous membranes. Contact may cause irritation with redness, tearing and pain. Irritation of nose and throat. Signal word Hazard statements Warning H315 - Causes skin irritation. H319 - Causes serious eye irritation. 1 / 6

2 Precautionary statements Prevention Response Storage Disposal Supplemental label information P280 - Wear protective gloves/protective clothing/eye protection/face protection. P264 - Wash thoroughly after handling. P302 + P352 - IF ON SKIN: Wash with plenty of soap and water. P362 - Take off contaminated clothing and wash before reuse. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical advice/attention. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. Not applicable Other hazards Not a PBT or vpvb substance or mixture. SECTION 3: Composition/information on ingredients 3.2. Mixtures General information Chemical name % CAS-No. / EC No. REACH Registration No. INDEX No. Notes Methyltrimethoxysilane 7-13 Classification: DSD: F;R11, Xi;R36/38 DSD: Directive 67/548/EEC. CLP: Regulation No. 1272/2008. Composition comments SECTION 4: First aid measures General information 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures CLP: Flam. Liq. 2;H225, Skin Irrit. 2;H315, Eye Irrit. 2;H319 All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. The full text for all R- and H-phrases is displayed in section 16. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately. Immediately remove contaminated clothing and shoes and wash skin with soap and plenty of water. Get medical attention if irritation develops and persists. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists. Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious. Get medical attention if any discomfort occurs. Irritation of eyes and mucous membranes. Contact may cause irritation with redness, tearing and pain. Irritation of nose and throat. Treat symptomatically. General fire hazards 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Special protective equipment for firefighters Special fire fighting procedures No unusual fire or explosion hazards noted. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Use standard firefighting procedures and consider the hazards of other involved materials. Cool material exposed to heat with water spray and remove it if no risk is involved. 2 / 6

3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel For emergency responders Avoid inhalation of vapors/dust and contact with skin and eyes. Wear appropriate protective equipment and clothing during clean-up. See Section 8 for personal protective equipment. Keep unnecessary personnel away. Avoid inhalation of vapours or mists. Use personal protection recommended in section 8 of the SDS Environmental precautions Avoid discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) Industrial Leak Sealant. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Scrape up spillage or absorb with absorbing material. After removal flush contaminated area thoroughly with water. This material and its container must be disposed of as hazardous waste. For personal protection, see section 8 of the SDS. For waste disposal, see section 13 of the SDS. Provide adequate ventilation. Avoid inhalation of vapors/dust and contact with skin and eyes. Wear appropriate personal protective equipment. Wash thoroughly after handling. Observe good industrial hygiene practices. Store in original tightly closed container. Store away from incompatible materials. Store in a dry place. Occupational exposure limits Biological limit values Recommended monitoring procedures Derived no-effect level (DNEL) Predicted no effect concentrations (PNECs) No exposure limits noted for ingredient(s). No biological exposure limits noted for the ingredient(s). Follow standard monitoring procedures. Exposure guidelines 8.2. Exposure controls Appropriate engineering controls Use personal protective equipment as required. Keep working clothes separately. Personal protective equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Ensure adequate ventilation, especially in confined areas. Individual protection measures, such as personal protective equipment General information Eye/face protection Skin protection Personal protective equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Wear approved safety glasses or goggles. - Hand protection Wear protective gloves. Suitable gloves can be recommended by the glove supplier. - Other Wear suitable protective clothing. Respiratory protection Thermal hazards Hygiene measures Environmental exposure controls SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Form Colour In case of inadequate ventilation or when the product is heated, use suitable respiratory equipment with gas filter (type A2). Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Private clothes and working clothes should be kept separately. Environmental manager must be informed of all major releases. Gray pliable semi-solid with acetic odor. Solid. Pliable semi-solid. Grey. 3 / 6

4 Odour ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Acetic. Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Vapour pressure Vapour density Relative density 1,12 Solubility(ies) Auto-ignition temperature Viscosity Slightly soluble in water. Explosive properties Oxidizing properties 9.2. Other information No relevant additional information available. SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Material is stable under normal conditions Possibility of hazardous reactions Conditions to avoid Contact with incompatible materials Incompatible materials Oxidizing agents. Water. Moisture Hazardous decomposition products SECTION 11: Toxicological information Hazardous polymerisation does not occur. Product in contact with water evolves methanol. Silicon dioxide. Carbon oxides. Metal oxides. Fluorine compounds. Traces of formaldehyde. Methanol. Information on likely routes of exposure Ingestion Inhalation Skin contact Eye contact Symptoms Information on toxicological effects May cause discomfort if swallowed. Vapour may be irritant to nose, throat and respiratory tract. Causes skin irritation. Causes eye irritation. Irritation of eyes and mucous membranes. Contact may cause irritation with redness, tearing and pain. Irritation of nose and throat. Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitisation Skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure May cause discomfort if swallowed. Causes skin irritation. Causes eye irritation. Not a skin sensitiser. 4 / 6

5 Specific target organ toxicity - repeated exposure Aspiration hazard Mixture versus substance information Other information During curing/hydrolysis the product may release methanol. In serious cases absorption of methanol in the body may lead to damage to the eyesight. SECTION 12: Ecological information Toxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol/water (log Kow) Bioconcentration factor (BCF) Mobility in soil Mobility in general Results of PBT and vpvb assessment Not a PBT or vpvb substance or mixture Other adverse effects The product is not expected to be hazardous to the environment. SECTION 13: Disposal considerations Waste treatment methods Residual waste Contaminated packaging Dispose of in accordance with local regulations. Dispose product packaging in accordance with local authority requirements taking into account characteristics of the packaging material. EU waste code * The Waste code should be assigned in discussion between the user, the producer and the waste disposal company. Disposal methods/information SECTION 14: Transport information ADR RID ADN IATA IMDG Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. This substance/mixture is not intended to be transported in bulk Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex II Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended 5 / 6

6 Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 2 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 3 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V as amended Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Regulation (EC) No. 1907/2006, REACH Article 59(1) Candidate List as currently published by ECHA Authorisations Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended Restrictions on use Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Not regulated. Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding Not regulated. Other EU regulations Directive 96/82/EC (Seveso II) on the control of major-accident hazards involving dangerous substances Not regulated. Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work Directive 94/33/EC on the protection of young people at work Other regulations National regulations Chemical safety assessment SECTION 16: Other information The product is classified and labelled in accordance with Regulation (EC) 1272/2008 (CLP Regulation) as amended and respective national laws implementing EC directives. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006 as amended. Follow national regulation for work with chemical agents. No Chemical Safety Assessment has been carried out. List of abbreviations References Information on evaluation method leading to the classification of mixture Full text of any statements or R-phrases and H-statements under Sections 2 to 15 Training information Disclaimer DNEL: Derived No-Effect Level. PNEC: Predicted No-Effect Concentration. PBT: Persistent, bioaccumulative and toxic. vpvb: Very Persistent and very Bioaccumulative. ESIS (European chemical Substances Information System) RTECS HSDB IARC Monographs. Overall Evaluation of Carcinogenicity The classification for health and environmental hazards is derived by a combination of calculation methods and test data, if available. R11 Highly flammable. R36/38 Irritating to eyes and skin. H225 Highly flammable liquid and vapour. H315 Causes skin irritation. H319 Causes serious eye irritation. Follow training instructions when handling this material. The information in the sheet was written based on the best knowledge and experience currently available. 6 / 6