Safety Data Sheet LOCTITE SI 5699 GY known as 5699 GREY 300ML DE FR GB NL Page 1 of 10 SDS No. : 152852 V001.12 Revision: 04.01.2018 printing date: 10.01.2019 Section 1. Identification of the substance/prepaion and of the company/undertaking Product name: LOCTITE SI 5699 GY known as 5699 GREY 300ML DE Other means of identification: LOCTITE SI 5699 GY CR300ML EGFD Product code: IDH142480 Recommended use of the chemical and restrictions on use Intended use: Silicone sealant Identification of manufacturer, importer or distributor Importer: Henkel Singapore Pte Ltd 401 Commonwealth Drive, #03-01/02, Haw Par Technocentre, Singapore. 149598 Phone : +65 62660100 Fax : +65 62661161 E-mail address of person responsible for Safety Data Sheet: Emergency information: ap-ua-psra.sea@henkel.com FOR EMERGENCIES ONLY (Spill, major leak, Fire, Exposure, or Accident). Call CHEMTREC: +1 703-741-5970 Section 2. Hazards identification GHS Classification: Hazard Class Hazard Category Serious eye damage/eye irritation Category 1 Skin sensitizer Category 1 GHS label elements: Hazard pictogram: Signal word: Danger
Page 2 of 10 Hazard statement: H317 May cause an allergic skin reaction. H318 Causes serious eye damage. Precaution: Prevention: Response: Disposal: P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Section 3. Composition / information on ingredients Substance or Mixture: Mixture Declaion of hazardous chemical: Hazard component CAS-No. Content GHS Classification 10-30 % 1-10 % Serious eye damage/eye irritation 1 H318 Skin Sensitization 1; Dermal H317 Target Organ Systemic Toxicant - Repeated exposure 2 H373 0.1-1 % Flammable solids 1 H228 Serious eye damage/eye irritation 2 H319 Skin Sensitization 1 H317 Target Organ Systemic Toxicant - Repeated exposure 2 H373 Section 4. First aid measures Inhalation: Skin contact: Move to fresh air. If symptoms persist, seek medical advice. Rinse with running water and soap. Obtain medical attention if irritation persists.
Page 3 of 10 Eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical advice. Ingestion: Do not induce vomiting. Seek medical advice. Indication of immediate medical attention and special treatment needed: See section: Description of first aid measures Section 5. Fire fighting measures Suitable extinguishing media: Specific hazards arising from the chemical: Special protection equipment and precautions for firefighters: Additional fire fighting advice: Carbon dioxide, foam, powder Do not expose to direct heat. Wear self-contained breathing appaus. In case of fire, keep containers cool with water spray. Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Avoid contact with skin and eyes. Wear protective equipment. Ensure adequate ventilation. Do not let product enter drains. Scrape up as much material as possible. Sweep up spilled material. Avoid creating dust. Store in a partly filled, closed container until disposal. Section 7. Handling and storage Handling: Storage: Use only in well-ventilated areas. Vapours should be extracted to avoid inhalation. Avoid skin and eye contact. See advice in section 8 Store in a cool, well-ventilated place.never allow product to get in contact with water during storage
Page 4 of 10 Components with specific control parameters for workplace: Section 8. Exposure controls / personal protection CALCIUM CARBONATE (LIMESTONE, MARBLE) Time Weighted Average (TWA): mg/m 3 10 Remarks SG PEL Time Weighted Average (TWA): mg/m 3 10 Respiory protection: Ensure adequate ventilation. An approved mask or respior fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A (EN 14387) Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on liteure references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. tempeure). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Body protection: Engineering controls: Hygienic measures: Wear protective glasses. Protective eye equipment should conform to EN166. Wear suitable protective clothing. Protective clothing should conform to EN 14605 for liquid splashes or to EN 13982 for dusts. Ensure good ventilation/extraction. Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Section 9. Physical and chemical properties Appearance: grey paste Odor: odourless Odor threshold (CA): ph: Not applicablenot applicable Melting point / freezing point: Not available. Specific gravity: 1.5 Boiling point: > 200 C (> 392 F) Flash point: > 93 C (> 199.4 F) Evapoion e:
Page 5 of 10 Flammability (solid, gas): Lower explosive limit: Upper explosive limit: Vapor pressure: (; 50 C (122 F)) Vapor density: Density: Solubility: Partition coefficient: n- octanol/water: Auto ignition: Decomposition tempeure: Viscosity: VOC content: (2010/75/EC) < 5 mm hg 1.5 g/cm3 < 5 % Section 10. Stability and reactivity Reactivity/Incompatible materials: Chemical stability: Conditions to avoid: Hazardous decomposition products: Polymerises in presence of water. Stable under recommended storage conditions. Stable Exposure to air or moisture over prolonged periods. Methyl ethyl ketoxime formed during cure. Methanol is libeed slowly upon exposure to moisture. Section 11. Toxicological information Symptoms of Overexposure: EYE: Irritation, conjunctivitis. SKIN: Rash, Urticaria. Acute oral toxicity: > 2,000 mg/kg OECD Guideline 420 (Acute Oral Toxicity) > 2,000 mg/kg OECD Guideline 425 (Acute Oral Toxicity: Up-and-Down Procedure) 2,463 mg/kg OECD Guideline 401 (Acute Oral Toxicity)
Page 6 of 10 Acute inhalative toxicity: Acute dermal toxicity: Skin corrosion/irritation: Serious eye damage/irritation: Acute toxicity estimate (ATE) 5.1 mg/l Expert judgement LC0 0.0812 mg/l 90 min > 2,000 mg/kg OECD Guideline 402 (Acute Dermal Toxicity) > 2,009 mg/kg OECD Guideline 402 (Acute Dermal Toxicity) > 2,000 mg/kg OECD Guideline 402 (Acute Dermal Toxicity) not irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) irritating 1 h rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiory or skin sensitization: Test type Test type Test type not sensitising Mouse local lymphnode assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) Sensitizing Guinea pig maximisation test guinea pig OECD Guideline 406 (Skin Sensitisation) sensitising Guinea pig maximisation test guinea pig OECD Guideline 406 (Skin Sensitisation)
Page 7 of 10 Germ cell mutagenicity: Repeated dose toxicity: Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Route of application / Frequency of treatment Route of application / Frequency of treatment Route of application / Frequency of treatment negative bacterial reverse mutation assay (e.g Ames test) with and without OECD Guideline 471 (Bacterial Reverse Mutation Assay) negative in vitro mammalian chromosome aberion test with and without OECD Guideline 473 (In vitro Mammalian Chromosome Aberion Test) negative mammalian cell gene mutation assay with and without OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test) negative bacterial reverse mutation assay (e.g Ames test) with and without OECD Guideline 471 (Bacterial Reverse Mutation Assay) negative intraperitoneal mouse OECD Guideline 474 (Mammalian Erythrocyte Micronucleus Test) NOAEL=1,000 mg/kg oral: gavage 48 ddaily OECD Guideline 422 (Combined Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening Test) NOAEL=10 mg/kg oral: gavage OECD Guideline 422 (Combined Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening Test) NOAEL=25 mg/kg oral: drinking water 90 ddaily: ad libitum OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity in Rodents) Section 12. Ecological information General ecological information: Ecotoxicity: Cured Loctite products are typical polymers and do not pose any immediate environmental hazards., Precautions required with respect to Environmental Hazards of articles in which this product is used should be considered. Do not empty into drains / surface water / ground water. Toxicity: NOEC 14 mg/l Algae 72 h Desmodesmus subspicatus OECD Guideline 201 (Alga, Growth Inhibition Test)
Page 8 of 10 LC50 > 560 mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) OECD Guideline 203 (Fish, Acute Toxicity Test) NOEC 50 mg/l Fish 14 d Oryzias latipes OECD Guideline 204 (Fish, Prolonged Toxicity Test: 14-day Study) EC50 201 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 94 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchneriella subcapitata) OECD Guideline 201 (Alga, Growth Inhibition Test) NOEC 30 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchneriella subcapitata) OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 843 mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) NOEC 50 mg/l Fish 14 d Oryzias latipes OECD Guideline 204 (Fish, Prolonged Toxicity Test: 14-day Study) EC50 201 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 16 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchneriella subcapitata) OECD Guideline 201 (Alga, Growth Inhibition Test) NOEC 2.6 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchneriella subcapitata) OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability: not readily biodegradable. Route of application aerobic Degradability 26 % OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I))
Page 9 of 10 not readily biodegradable. Route of application aerobic Degradability 28 % OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I)) Bioaccumulative potential / Mobility in soil: LogPow -2.12 Tempeure QSAR (Quantitative Structure Activity Relationship) Section 13. Disposal consideions Product of disposal: Dispose of in accordance with local and national regulations. Contribution of this product to waste is very insignificant in comparison to article in which it is used Packaging Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incineed. Section 14. Transport information General information: Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR. Section 15. Regulatory information Regulatory Information: Workplace Safety And Health Act (Chapter 354A) Workplace Safety And Health (Approved Codes of Practice) Notification 2013 SS586 Specification for Hazard Communication for hazardous chemicals and dangerous good Part 1,2,3 Global inventory status: Regulatory list AICS KECI (KR) PICCS (PH) IECSC Notification yes yes yes yes Section 16. Other information Disclaimer: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.
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