*** SAFETY DATA SHEET ***

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Transcription:

*** SAFETY DATA SHEET *** 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME ABLEBOND FS849-TI RECOMMENDED USE SUPPLIER Adhesive Henkel Limited Station Road Linton Cambridge CB1 6NW United Kingdom EMERGENCY TELEPHONE: +44 (0)1223 893771 (UK business hours) +1 310 764 4600 (USA business hours) ua-productsafety.uk@uk.henkel.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW SKIN CONTACT PHYSICO-CHEMICAL ENVIRONMENTAL SENSITIZER Contact with eyes causes redness and discomfort which is transient. Repeated and/or prolonged contact may cause skin sensitisation. Vapour may be irritant to the respiratory tract. If cured material is sanded resulting powder would be considered hazardous. No hazard in normal industrial use. No unusual hazards are expected. PAGE 1 OF 5

3. COMPOSITION/INFORMATION ON INGREDIENTS COMPONENT EC NUMBER CONCENTRATION % EC SYMBOL/ RISK PHRASES 231-131-3 >50 IOELV Oxybis(methyl-2,1-ethanediyl) 260-754-3 1-5 XI R38 R41 R43 diacrylate Organic peroxide <0.5 O XI N R7 R36/38 R51/53 For full text of risk phrases, please refer to Section 16. 4. FIRST-AID MEASURES SKIN CONTACT Immediate medical attention is not required. Irrigate with eyewash solution or clean water until pain is relieved. Immediate medical attention is not required. Wash skin with soap and water. If symptoms develop, obtain medical attention. Immediate medical attention is not required. Remove patient from exposure. Immediate medical attention is not required. Treat symptomatically and supportively. If symptoms develop, obtain medical attention. 5. FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA CO2; Dry Chemical; Foam; Water Fog SPECIAL FIREFIGHTING Fire fighters should be equipped with self-contained breathing apparatus to PROCEDURES protect against potentially toxic and irritating fumes. FIRE & EXPLOSION HAZARDS Combustion may release noxious or toxic vapours. See below. HAZARDOUS COMBUSTION Carbon monoxide, carbon dioxide, unknown hydrocarbons. PRODUCTS LOWER EXPLOSION LIMIT (%) UPPER EXPLOSION LIMIT (%) AUTOFLAMMABILITY Not available FLASH POINT 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK PROCEDURES Adsorb spillages onto sand, earth or any suitable adsorbent material. Scrape up and place in suitably labelled container for disposal. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. PAGE 2 OF 5

7. HANDLING AND STORAGE STORAGE TEMPERATURE -40 C HANDLING/STORAGE Product can ONLY be used for thin bond line applications or rapid exothermic curing reaction may result. SENSITIVE TO STATIC No ELECTRICITY SENSITIVITY TO No MECHANICAL IMPACT 8. EXPOSURE CONTROLS/PERSONAL PROTECTION COMPONENT COMPONENT EXPOSURE LIMITS 0.1 mg/m3 TWA EC INDICATIVE OCCUPATIONAL EXPOSURE LIMIT VALUES 0.1 mg/m3 TWA OCCUPATIONAL EXPOSURE CONTROLS VENTILATION General. Vent curing oven to outdoors. PROTECTION Safety glasses, goggles or face shield to protect against splashing. Personal eye protection should conform to EN 166. GLOVE Employee must wear appropriate protective gloves to prevent contact with this substance. Gloves should conform to EN 374. Nitrile rubber or Viton gloves are recommended. Cotton or other absorbent gloves should not be worn. CLOTHING Employee must wear appropriate protective clothing and equipment to prevent any possibility of skin contact with this substance. WASH Wash before eating, drinking, or using toilet facilities. RESPIRATORY None required under normal handling conditions. PAGE 3 OF 5

9. PHYSICAL AND CHEMICAL PROPERTIES PURE SUBSTANCE OR PREPARATION Preparation. PHYSICAL FORM Paste COLOUR ODOUR Slight ODOUR THRESHOLD Not available OXIDIZING PROPERTIES SOLUBILITY IN WATER Insoluble PARTITION COEFFICIENT (noctanol/water) VISCOSITY 12500 mpa.s RELATIVE DENSITY 4.5 EVAPORATION RATE VAPOUR PRESSURE (mmhg) VAPOUR DENSITY (air=1) VOLATILES None VOLATILE ORGANIC COMPOUNDS Not available AUTOFLAMMABILITY Not available FLASH POINT 10. STABILITY AND REACTIVITY STABILITY MATERIALS TO AVOID HAZARDOUS DECOMPOSITION PRODUCTS Stable Bases., Amines., Acids., Oxidizers. Carbon monoxide, carbon dioxide, unknown hydrocarbons. 11. TOXICOLOGICAL INFORMATION SKIN EFFECTS OF CHRONIC EXPOSURE SKIN SENSITIZATION Contact with eyes causes redness and discomfort which is transient. Repeated and/or prolonged contact may cause skin sensitisation. Vapour may be irritant to the respiratory tract. If cured material is sanded resulting powder would be considered hazardous. No hazard in normal industrial use. The toxicological properties of this product have not been fully evaluated. Use of good industrial hygiene practices is required. Avoid direct contact with skin or eyes. Do not ingest or inhale. Sensitizer. 12. ECOLOGICAL INFORMATION POTENTIAL EFFECT ON ENVIRONMENT AQUATIC TOXICITY POTENTIAL TO BIOACCUMULATE None Established PAGE 4 OF 5

13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHODS EMPTY CONTAINER WARNINGS Waste disposal should be in accordance with existing Community,National and local regulations. Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. 14. TRANSPORT INFORMATION (See also section 9) IATA CLASSIFICATION IMDG CLASSIFICATION ADR/RID 15. REGULATORY INFORMATION EC INDICATION OF DANGER EC SYMBOL IRRITANT RISK PHRASES SAFETY PHRASES CONTAINS EINECS R43 - May cause sensitisation by skin contact. S24 - Avoid contact with skin. S37 - Wear suitable gloves. Oxybis(methyl-2,1-ethanediyl) diacrylate All components of this product are listed in EINECS or ELINCS, or are otherwise exempt from EU notification requirements. 16. OTHER INFORMATION REPLACES VERSION DATED 20/03/2009 ORIGINAL DOCUMENT DATED 07/04/2008 FULL TEXT OF RISK PHRASES FOR INGREDIENTS INDICATED IN SECTION 3: Oxybis(methyl-2,1-ethanediyl) diacrylate Organic peroxide R38 - Irritating to skin. R41 - Risk of serious damage to eyes. R43 - May cause sensitisation by skin contact. R7 - May cause fire. R36/38 - Irritating to eyes and skin. R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. This information is provided for health and safety assessment by an industrial user. Reference should be made to any relevent local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. PAGE 5 OF 5