Section 1. Chemical Product and Company Identification Material Safety Data Sheet Product Name: Trisodium Phosphate 12 H2O Version: 3 Effective Date: June 27, 2014 Supplier/ Manufacturer: Chemfax Products Ltd. 11444 42 Street SE Calgary, AB T2C 5C4 Tel: 403-287-2055 Material Uses Degreaser / cleaner 24 Hour Emergency Canutec (613) 996-6666 WHMIS This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR HMIS Ratings for this product are: Health 2, Flammability 0, Reactivity 0 Section 2. Composition and Information on Ingredients Name CAS# % by weight Trisodium phosphate dodecahydrate 10101-89-0 95-100 See Section 8 for information on permissible exposure limits and threshold limit values Section 3. Hazards Identification Physical State and Appearance Hazard Summary Routes of Exposure Potential Acute Health Effects White powder with no odour Irritant Skin & eye contact, inhalation, ingestion Skin: Irritant. May cause severe irritation. Eyes: Irritant. May cause severe irritation and mild burns to the cornea. Can cause permanent damage to the cornea. Inhalation: Inhalation of aerosols may cause irritation of the Chemfax Products Ltd. Page 1 of 5 June 27, 2014
upper respiratory tract. Ingestion: May cause irritation or mild burns to the mouth, throat and stomach. Aspiration in to the lungs may occur during ingestion or vomiting, resulting in lung injury. Medical Conditions known Aggravated by Exposure See Toxicological Information Section 11 Additional Hazard Ingestion of phosphate salts can hypothetically lead to Identification Remarks hypocalcemia or hypernatremia Section 4. First Aid Measures Eye Contact Skin Contact Inhalation Ingestion Notes to Physician Additional First Aid Remarks Flush eyes with water for 15 minutes. Seek medical attention. Flush area with water. If irritation persists seek medical attention. Launder clothing before reuse. Remove victim to fresh air. If there is difficulty breathing, seek immediate medical attention. Give two glasses of water. Do not induce vomiting. Lay victim on left side to prevent aspiration of any vomit. Seek immediate medical attention. Treat symptoms Section 5. Fire Fighting Measures Flammability of the Product Flash Point Explosive Limits Auto Ignition Temperature Static Discharge Suitable Extinguishing Media Hazardous Combustion Products Precautions for Fire Fighting Non flammable No Does not burn. Use extinguishing media appropriate for surrounding conditions Oxides of sodium and phosphorus. Fire fighters should wear self contained breathing apparatus and full protective clothing. Use water spray to cool containers and structures exposed to fire. Chemfax Products Ltd. Page 2 of 5 June 27, 2014
Section 6. Accidental Release Measures Personal Precautions Environmental Precautions Methods for Clean Up Gloves, chemical resistant footwear, coverall, safety glasses Prevent entry into waterways, sewers or low areas Sweep up spilt material into a container suitable for disposal. Wash area with water to remove trace materials Section 7. Handling and Storage Handling Handle with care, irritant Storage Store in a cool well ventilated area. Keep containers closed when not in use. Section 8. Exposure Controls and Personal Protection Exposure Guidelines Trisodium phosphate dodecahydrate Exposure Controls Personal Protection Respiratory Skin Eyes Other TWA: 8 Hr STEL: 15 min Ceiling Not established for this product Local exhaust ventilation Air purifying respirator fitted with HEPA dust cartridges Gloves, coveralls, boots Safety glasses Section 9. Physical and Chemical Properties Physical State and Appearance White powder with no odour Odour Threshold ph 13 14 (10 % solution) Boiling Point Melting Point / Freezing point 75 o C Evaporation Rate Vapour Density Vapour Pressure Relative Density Solubility in Water Soluble % Volatile Other Data Chemfax Products Ltd. Page 3 of 5 June 27, 2014
Section 10. Stability and Reactivity Chemical Stability Hazardous Polymerisation Conditions to Avoid Materials to Avoid Hazardous Decomposition Products Stable Will not occur known Magnesium metal. Strong acids Oxides of phosphorus and sodium. Decomposition temperature 77 o C Section 11. Toxicological Information Principle Routes of Exposure Skin: Eyes: Inhalation: Ingestion: Additional Information Acute Toxicity Trisodium phosphate dodecahydrate Irritant. May cause severe irritation. Irritant. May cause severe irritation and mild burns to the cornea. Can cause permanent damage to the cornea. Inhalation of aerosols may cause irritation of the upper respiratory tract. May cause irritation or mild burns to the mouth, throat and stomach. Aspiration in to the lungs may occur during ingestion or vomiting, resulting in lung injury. LD50: 7400 mg/kg (Rat, oral) Chronic Toxic Effects known Carcinogenicity Not listed Reproductive Toxicity / Teratogenicity / Embryotoxicity / Mutagenicity known Section 12. Ecological Information Ecotoxicity BOD and COD Biodegradability / OECD Toxicity of the Products of Biodegradation Special Remarks Trisodium phosphate dodecahydrate EC50: 151 mg/l/96 hr (Mosquito fish) Section 13. Disposal Considerations Dispose of in accordance with local, provincial and federal regulations Chemfax Products Ltd. Page 4 of 5 June 27, 2014
Section 14. Transport Information TDG Classification Emergency Response Guide # Marine Pollutant Special Precautions Not regulated under TDG No Section 15. Regulatory Information Canada DSL Inventory TSCA WHMIS Hazard Class Additional Information All components of this product are either on the Domestic Substances List (DSL) or Non-Domestic Substances List (NDSL) or exempt All components of this product are either on the Toxic Substances Control Act (TSCA) Inventory List or exempt E Section 16. Other Information Prepared by: Chemfax Products Ltd., Technical Department Date Prepared: 03 November, 2011 Revision Date: 27 June, 2014 Disclaimer Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Chemfax Products Ltd. expressly disclaims all expressed or implied warranties of merchantability and fitness for a particular purpose with respect to the product provided. Chemfax Products Ltd. Page 5 of 5 June 27, 2014