Print date: 12.04.2011 MSDS: Page 1 of 5 1. Identification of the substance/preparation and of the company/undertaking MSDS-ID: Company/undertaking identification Company name: Street: Place: Fahltskamp 5 D-25421 Pinneberg Telephone: +49 (0) 41 01 86 86 8-0 Telefax: +49 (0) 41 01 86 86 7-0 Internet: www.indigodental.com e-mail: info@indigodental.com 2. Hazards identification Classification Indications of danger : Highly flammable, Irritant R-phrases: Highly flammable. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact.. Composition/information on ingredients Chemical characterization ( Mixture ) chemical characterization (preparation): Acrylate.-resin. Hazardous components EC-No. CAS-No. Chemical name Quantity Classification 201-297-1 80-62-6 methyl 2-methylprop-2-enoate, methyl 40-50 % F, Xi R11-7/8-4 2-methylpropenoate, methyl methacrylate Full text of each relevant R phrase can be found in heading 16. 4. First aid measures After inhalation Move victim to fresh air. Put victim at rest and keep warm. After contact with skin After contact with skin, wash immediately with: Water and soap. After contact with eyes In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After ingestion Consult physician. 5. Fire-fighting measures Suitable extinguishing media Extinguishing powder. Sand. Foam. Carbon dioxide (CO2). Extinguishing media which must not be used for safety reasons High power water jet. 6. Accidental release measures
Print date: 12.04.2011 MSDS: Page 2 of 5 Personal precautions Provide adequate ventilation. Environmental precautions Do not empty into drains or the aquatic environment. Methods for cleaning up/taking up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). 7. Handling and storage Handling Advice on safe handling Wear suitable gloves. Avoid contact with eyes. Advice on protection against fire and explosion Keep away from sources of ignition - No smoking. Use explosion-protected machinery, apparatus, suction equipment, appliances etc. Storage Requirements for storage rooms and vessels Keep container tightly closed in a cool, well-ventilated place. 8. Exposure controls/personal protection Exposure limit values Additional advice on limit values exposure limit values: (MMA): 210 mg/m³; 50 ml/m³ Exposure controls Occupational exposure controls Ensure adequate ventilation of the storage area. Protective and hygiene measures When using do not eat or drink. Respiratory protection Filter respirator (full mask or mouth-piece) with filter: A Hand protection Tested protective gloves are to be worn: Suitable material: NBR (Nitrile rubber). Eye protection Tightly sealed safety glasses. 9. Physical and chemical properties General information Physical state: Colour: Odour: liquid yellow ester Important health, safety and environmental information ph-value: Changes in the physical state not applicable Test method
Print date: 12.04.2011 MSDS: Page of 5 point of decomposition: Flash point: Lower explosion limits: Upper explosion limits: Vapour pressure: (at 20 C) Density: Water solubility: (at 20 C) Vapour density: Other information Ignition temperature: > 100 C 10 C 2,1 vol. % 12,5 vol. % 40 hpa ca. 1,1 g/cm³ 16 g/l > 1 > 40 C 10. Stability and reactivity Conditions to avoid heat. Light. Decompostion takes place from temperatures above: 100 C Materials to avoid Keep away from strong acids, leachates, heavy metal salts and reducing materials. Hazardous decomposition products Can be released in case of fire: Gas / vapours, irritant. (Acrylate., pungent) Additional information Substances sensitive to light. 11. Toxicological information Specific effects in experiment on an animal LD50: (Rat.) > 8.000 mg/kg (MMA) > 5.000 mg/kg (Acrylate.) Corrosive and irritant effects Irritant effect on the eye: In rare cases, product may cause temporary redness of the skin. Frequently or prolonged contact with skin may cause dermal irritation. Sensitising effects May cause sensitization by skin contact. Additional information on tests Contains Methyl methacrylate.: May produce an allergic reaction. May cause sensitization by skin contact. 12. Ecological information Ecotoxicity Product is partially biodegradable. >50 % Acute fish toxicity LC50: >20 mg / l / 96 h Persistence and degradability Preparation not tested. Do not empty into drains or the aquatic environment. Leakage into the environment must be prevented.
Print date: 12.04.2011 MSDS: Page 4 of 5 1. Disposal considerations Advice on disposal Can be burnt together with household waste in compliance with official regulations in contact with approved waste disposal companies and with authorities in charge. Waste disposal number of waste from residues/unused products 180106 WASTES FROM HUMAN OR ANIMAL HEALTH CARE AND/OR RELATED RESEARCH (except kitchen and restaurant wastes not arising from immediate health care); wastes from natal care, diagnosis, treatment or prevention of disease in humans; chemicals consisting of or containing dangerous substances Classified as hazardous waste. 14. Transport information Land transport (ADR/RID) UN number: ADR/RID class: Classification code: Warning plate Hazard-no.: Hazard label: ADR/RID packing group: Limited quantity: 1247 F1 9 II LQ4 Description of the goods METHYL METHACRYLATE MONOMER, STABILIZED Other applicable information (land transport) E2 : 2 : D/E Marine transport UN number: IMDG code: Hazard label: IMDG packing group: EmS: Limited quantity: 1247 II F-E, S-D 1 L Description of the goods METHYL METHACRYLATE MONOMER, STABILIZED Other applicable information (marine transport) Special provisions: - Air transport UN/ID number: ICAO/IATA-DGR: Hazard label: ICAO packing group: Limited quantity Passenger: 1247 II 1 L IATA-packing instructions - Passenger: 05
Print date: 12.04.2011 MSDS: Page 5 of 5 IATA-max. quantity - Passenger: IATA-packing instructions - Cargo: IATA-max. quantity - Cargo: 5 L 07 60 L Description of the goods METHYL METHACRYLATE MONOMER, STABILIZED Other applicable information (air transport) E2 : Y05 60 L 15. Regulatory information Labelling Danger symbols: F - Highly flammable; Xi - Irritant Hazardous components which must be listed on the label Methyl methacrylate. R phrases 11 Highly flammable. 6/7/8 Irritating to eyes, respiratory system and skin. 4 May cause sensitization by skin contact. S phrases 09 Keep container in a well-ventilated place. 16 Keep away from sources of ignition - No smoking. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 28 After contact with skin, wash immediately with plenty of Wasser und Seife. 29 Do not empty into drains. National regulatory information Water contaminating class (D): 16. Other information 1 - slightly water contaminating Full text of R-phrases referred to under sections 2 and 11 Highly flammable. 6/7/8 Irritating to eyes, respiratory system and skin. 7/8 Irritating to respiratory system and skin. 4 May cause sensitization by skin contact. Further Information - (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)