Material Safety Data Sheet Revision Number: 003.2 Issue date: 03/22/2013 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Product type: Company address: Henkel Corporation 32100 Stephenson Highway Madison Heights, MI 48071 BONDERITE O-WP ZE WELDABLE PRIMER known as GRANOCOAT ZE Paints and coatings Region: United States Contact information: Telephone: 248.583.9300 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Viscous HEALTH: *2 Color: Blue, grey FLAMMABILITY: 3 Odor: Solvent PHYSICAL HAZARD: 0 Personal Protection: See MSDS Section 8 WARNING: FLAMMABLE LIQUID AND VAPOR. MAY CAUSE EYE AND SKIN IRRITATION. MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. MAY BE HARMFUL IF INHALED. Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: May cause respiratory tract irritation. Inhalation of high vapor concentrations may produce respiratory irritation, and may cause central nervous system (CNS) depression. This product may cause irritation to the skin. Prolonged or repeated skin contact may result in redness, burning sensation or dermatitis. Contact can cause moderate to severe irritation and possible injury to the eyes. Ingestion of this product is unlikely. However, ingestion of product may produce gastrointestinal irritation and disturbances. Eye, skin and respiratory disorders. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). See Section 11 for additional toxicological information. Page 1 of 6
3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Zinc powder 7440-66-6 30-60 Butyl diethylene glycol acetate 124-17-4 10-30 1-Methoxy -2-propanol 107-98-2 5-10 1-Butoxypropan-2-ol 5131-66-8 1-5 Petroleum naphtha, light aromatic Proprietary 1-5 1,2,4-Trimethylbenzene 95-63-6 0.1-1 n-butyl acetate 123-86-4 0.1-1 2-Methylpropan-1-ol 78-83-1 0.1-1 N-Methyl-2-pyrrolidone 872-50-4 0.1-1 Mesitylene 108-67-8 0.1-1 Propylbenzene 103-65-1 0.1-1 Cumene 98-82-8 0.1-1 4. FIRST AID MEASURES Inhalation: Skin contact: If mist or vapor of this product is inhaled, remove person immediately to fresh air. Seek medical attention if symptoms develop or persist. Remove contaminated clothing and footwear. For skin contact, flush with large amounts of water. Seek immediate medical attention. Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Ingestion: Get medical attention. DO NOT induce vomiting unless directed to do so by medical personnel. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: 30.0 C (86 F) Pensky Martens closed cup Water spray (fog), foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Upon decomposition, this product emits oxides of sulfur, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Prevent further leakage or spillage if safe to do so. Eliminate all sources of ignition or flammables that may come into contact with a spill of this material. Wear appropriate personal protective equipment. Page 2 of 6
Clean-up methods: Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations. 7. HANDLING AND STORAGE Handling: Storage: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists of this product. Wash thoroughly after handling. For industrial use only. For safe storage, store between 5 C (41 F) and 30 C (86 F) Storage within given temperature limit Outside temperature limits, the properties of the product will change. At the usual storage and transportation conditions no impairments of the product are to be expected. Store in original container until ready to use. Keep out of reach of children and away from food and drink. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Zinc powder 10 mg/m3 TWA Inhalable dust. 3 mg/m3 TWA Respirable fraction. 15 mg/m3 TWA Total dust. 5 mg/m3 TWA Respirable fraction. Butyl diethylene glycol acetate 1-Methoxy -2-propanol 150 ppm STEL 100 ppm TWA 1-Butoxypropan-2-ol Petroleum naphtha, light aromatic 50 ppm 1,2,4-Trimethylbenzene 25 ppm TWA n-butyl acetate 150 ppm TWA 150 ppm (710 200 ppm STEL mg/m3) TWA 2-Methylpropan-1-ol 50 ppm TWA 100 ppm (300 mg/m3) TWA 10 ppm (40 N-Methyl-2-pyrrolidone mg/m3) TWA (SKIN) Mesitylene 25 ppm TWA Propylbenzene 50 ppm (245 Cumene 50 ppm TWA mg/m3) TWA (SKIN) Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product. If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, appropriate NIOSH/MSHA respiratory protection must be provided. Wear chemical goggles; face shield (if splashing is possible). Chemical resistant, impermeable gloves. Gloves should be tested to determine suitability for prolonged contact. Use of impervious apron and boots are recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Color: Viscous Blue, grey Page 3 of 6
Odor: Solvent Odor threshold: Not available. ph: Not applicable Vapor pressure: Boiling point/range: > 100.0 C (> 212 F) calculated Melting point/ range: Specific gravity: 1.99 Vapor density: Flash point: 30.0 C (86 F) Pensky Martens closed cup Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Negligible Partition coefficient (n-octanol/water): VOC content: 28.5 % (calculated) 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable at normal conditions. Will not occur. Upon decomposition, this product may yield sulfur dioxide, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. This product may react with strong oxidizing agents. Avoid strong oxidizing agents. 11. TOXICOLOGICAL INFORMATION Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Zinc powder No No No Butyl diethylene glycol acetate No No No 1-Methoxy -2-propanol No No No 1-Butoxypropan-2-ol No No No Petroleum naphtha, light aromatic No No No 1,2,4-Trimethylbenzene No No No n-butyl acetate No No No 2-Methylpropan-1-ol No No No N-Methyl-2-pyrrolidone No No No Mesitylene No No No Propylbenzene No No No Cumene No Group 2B No Hazardous components Zinc powder Butyl diethylene glycol acetate 1-Methoxy -2-propanol 1-Butoxypropan-2-ol Petroleum naphtha, light aromatic 1,2,4-Trimethylbenzene n-butyl acetate 2-Methylpropan-1-ol N-Methyl-2-pyrrolidone Mesitylene Propylbenzene Cumene Health Effects/Target Organs Blood, Central nervous system, Eyes, Immune system, Irritant, Kidney, Metabolic, Pancreas, Respiratory Central nervous system, Irritant, Kidney Central nervous system, Developmental, Irritant Irritant Irritant Central nervous system, Irritant, Respiratory Irritant, Central nervous system Allergen, Cardiac, Central nervous system, Irritant, Kidney, Liver, Lung Blood, Bone Marrow, Central nervous system, Immune system, Irritant, Lung Central nervous system, Irritant, Respiratory Central nervous system, Irritant, Kidney, Liver Central nervous system, Irritant, Lung Page 4 of 6
12. ECOLOGICAL INFORMATION Ecological information: Harmful to aquatic organisms. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal. Hazardous waste number: If discarded, this product is considered a RCRA ignitable waste, D001. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Paint Hazard class or division: 3 Identification number: UN 1263 Packing group: III International Air Transportation (ICAO/IATA) Proper shipping name: Paint Hazard class or division: 3 Identification number: UN 1263 Packing group: III 14. TRANSPORT INFORMATION Water Transportation (IMO/IMDG) Proper shipping name: PAINT (Zinc powder) Hazard class or division: 3 Identification number: UN 1263 Packing group: III Marine pollutant: Zinc powder United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. above reporting de minimus above reporting de minimis Immediate Health, Delayed Health, Fire This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Zinc powder (CAS# 7440-66-6). Butyl diethylene glycol acetate (CAS# 124-17- 4). This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: One or more components are not listed on, and are not exempt from listing on either the Domestic Substances List or the Non-Domestic Substances List. B.2, D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New information added in Section(s): 2 Page 5 of 6
Prepared by: Regulatory Affairs DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 6 of 6