3M AUSTRALIA PTY LIMITED 3M NEW ZEALAND LTD 950 Pacific Highway 250 Archers Road Pymble NSW 2073 Glenfield Auckland N.Z. Phone: 136 136 Phone: (9) 444 4760 24HR EMERGENCY: 1800 097 146 (Australia only). ============================================================================ MATERIAL SAFETY DATA SHEET ============================================================================ Document ID : 16-0603-7 Issue date : 07/06/2006 Version : 1.06 Supersedes date : 02/06/2006 Document status : Issued This MSDS has been prepared by 3M Australia Pty Ltd Toxicology Dept. 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME 3M AVAGARD 9232 ANTISEPTIC HAND AND BODY WASH WITH DIVISION Commercial Care Division 3M Product ID AH-1000-1010-9, AH-1000-1013-3, AH-1000-1011-7, AH-1000-1012-5 RECOMMENDED USE: Hand/skin wash. For professional or industrial use only. 2 HAZARDS IDENTIFICATION NOTE: NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. POISONS SCHEDULE. Risk Codes and Phrases R43 May cause sensitisation by skin contact. Safety Codes and Phrases S2 Keep out of the reach of children. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 3 COMPOSITION Ingredient Name CAS number Percentage ------------------------------------- ------------------ ------------- WATER 7732-18-5 60-100 PROPYL ALCOHOL 71-23-8 5-10 (HYDROXYETHYL)CELLULOSE 9004-62-0 5-10 DECYL GLUCOSIDE 54549-25-6 1-5 DIGLUCONATE 18472-51-0 1-5 N-COCO ALKYL-2,2'-IMINOBISETHANOL 61791-31-9 0.5-1.5 GLYCERIN 56-81-5 0.5-1.5 2-PHENOXYETHANOL 122-99-6 0.5-1.5 LAURYLDIMETHYLAMINE OXIDE 1643-20-5 0.5-1.5 Page 1
3M AVAGARD 9232 ANTISEPTIC HAND AND BODY WASH WITH Page 2 of 6. COCOAMPHODIPROPIONATE 68604-71-7 0.1-1.0 LACTIC ACID 50-21-5 0.1-1.0 FRAGRANCE --- 0.1-1.0 COLOURANT 2353-45-9 < 1 4 FIRST AID MEASURES EYE CONTACT SKIN CONTACT INHALATION IF SWALLOWED 5 FIRE FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA Water spray. Carbon dioxide. Dry chemical. Foam. Alcohol-type foam. FIRE FIGHTING PROCEDURES Wear full protective clothing, including helmet, self-contained, positive pressure or positive pressure demand self-contained breathing apparatus, tunic and pants, bands around arms, waist and legs, full facepiece, and protective covering for exposed areas of the head. For leaks or spills which have not ignited, water spray can be used to disperse the flammable vapour and protect personnel attempting to stop the leak. Combustion Products from Fire Combustion Products from Fire are listed in Section 10, STABILITY AND REACTIVITY. 6 ACCIDENTAL RELEASE MEASURES (SPILL) Personal Precautions Observe precautions from other sections of this Material Safety Data Sheet. Spill Response Ventilate area with fresh air. Contain spill. Cover with absorbent material. Collect as much of the spilled material as possible. Clean up residue with water. Place in a closed container approved for transportation by appropriate authorities. Page 2
3M AVAGARD 9232 ANTISEPTIC HAND AND BODY WASH WITH Page 3 of 6. 7 HANDLING AND STORAGE Precautions for Safe Handling Keep container tightly closed when not in use. Conditions for Safe Storage Refer to Incompatibility - Materials to Avoid. Incompatibility - Materials to Avoid Store away from heat. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION PROPYL ALCOHOL (71-23-8) NATIONAL EXPOSURE STANDARDS: TWA 200ppm 492mg/m3 STEL 250ppm 614mg/m3 Overall exposure for this substance will be influenced by skin exposure, including mucous membranes and eyes, either by airborne or more particularly by direct contact with the substance. The presence of other solvents may alter skin absorption. GLYCERIN (56-81-5) NATIONAL EXPOSURE STANDARDS: TWA 10mg/m3 (as mist) Special Information, Exposure/Protection The extent to which the following recommendations for exposure control and protection are observed should depend on the risk assessment undertaken for the specific conditions under which this product is used, including occupational hygiene measurements. Recommended Ventilation Eye Protection Avoid eye contact. Skin Protection Avoid prolonged or repeated skin contact. Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Prevention of Accidental Ingestion Do not ingest. 9 PHYSICAL/CHEMICAL PROPERTIES Appearance and Odour Viscous aqua coloured liquid; fruity odour. 3M AVAGARD 9232 ANTISEPTIC HAND AND BODY WASH WITH Page 4 of 6. Page 3
ph 4-7 Vapour pressure Vapour density Boiling point Melting point Water Solubility Specific gravity Flash point Flammable Limits - LEL Flammable Limits - UEL Autoignition temperature Complete 0.98 (Water=1) Not determined Volatile organic compounds (VOC) 6 % content Evaporation rate Viscosity 500-1500 centipoise 10 STABILITY AND REACTIVITY Stability Stable. Hazardous polymerisation will not occur. Materials to Avoid None known. Hazardous Decomposition Products Carbon Monoxide, Carbon Dioxide. Hydrocarbons. 11 TOXICOLOGICAL INFORMATION Effects from Eye Contact Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Effects from Skin Contact Prolonged or repeated exposure may cause: Allergic Skin Reaction (non-photo induced): Signs/symptoms can include redness, swelling, blistering and itching. Effects from Inhalation No health effects are expected. 3M AVAGARD 9232 ANTISEPTIC HAND AND BODY WASH WITH Page 5 of 6. Page 4
Effects from Ingestion Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhoea and vomiting. 12 ECOLOGICAL INFORMATION Environmental Data Not determined 13 DISPOSAL CONSIDERATIONS Disposal methods Flush spent solutions and small quantities (less than 19 Litres (5 gal.) to a wastewater treatment system. Incinerate large quantities in an industrial or commercial incinerator. 14 TRANSPORT INFORMATION ADG (Road/Rail) --------------- UN NUMBER PROPER SHIPPING NAME DANGEROUS GOODS CLASS SUBSIDIARY RISK PACKING GROUP IATA (Airfreight) ----------------- UN NUMBER PROPER SHIPPING NAME DANGEROUS GOODS CLASS SUBSIDIARY RISK PACKING GROUP IMO (Seafreight) ---------------- UN NUMBER 3M AVAGARD 9232 ANTISEPTIC HAND AND BODY WASH WITH Page 6 of 6. Page 5
PROPER SHIPPING NAME DANGEROUS GOODS CLASS SUBSIDIARY RISK PACKING GROUP 15 REGULATORY INFORMATION Product Certifications TGA approved. 16 OTHER INFORMATION REASON FOR REISSUE This MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of the product have not changed. We encourage you to re-read the MSDS and review the information. The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet, which involves using the product, or otherwise that in accordance with instructions of use on product packaging is the responsibility of the user. If clarification or further information is needed to ensure that an appropriate risk assessment can be made, the user should contact the Snr Regulatory Services Officer on (02)9498-9287. Page 6