Safety Data Sheet Page 1 of 14 SF-TEROSON EP 5055 PART B EX SDS No. : 352466 V002.2 Revision: 27.10.2016 printing date: 08.02.2018 Section 1. Identification of the substance/prepaion and of the company/undertaking Product name: SF-TEROSON EP 5055 PART B EX Other means of identification: SF-TEROSON EP 5055 PART B EX Product code: IDH1346408 Recommended use of the chemical and restrictions on use Intended use: Part B of 2-Component Epoxy Adhesive. Identification of manufacturer, importer or distributor Manufacturer: Henkel AG & Co. KGaA, Heidelberg, Henkel Teroson Straße 57, 69112 Heidelberg, Germany. Phone: +49-6221-704-0 Fax: +49-6221-704-698 Importer: Henkel Thailand Ltd The Offices at Centralworld, 35th Floor, 999/9 Rama 1 Rd, Kwang Patumwan, Khet Patumwan, Bangkok 10330, Thailand. Phone : + 6622098000 Fax : +6622098008 E-mail address of person responsible for Safety Data Sheet: ap-ua-psra.sea@henkel.com Emergency information: FOR EMERGENCIES ONLY (Spill, major leak, Fire, Exposure, or Accident). Call CHEMTREC: +1 703-741-5970 GHS Classification: Section 2. Hazards identification Hazard Class Hazard Category Route of Exposure Acute toxicity Category 4 Oral Skin corrosion/irritation Category 1B Serious eye damage/eye irritation Category 1 Skin sensitizer Category 1 Acute hazards to the aquatic Category 1 environment Chronic hazards to the aquatic environment Category 1 GHS label elements: Hazard pictogram: Signal word: Danger
Page 2 of 14 Precaution: Hazard statement: H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects. Prevention: P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response: P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340+P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P330 Rinse mouth. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. P391 Collect spillage. Disposal: P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
Page 3 of 14 Section 3. Composition / information on ingredients Substance or Mixture: Mixture Declaion of hazardous chemical: Hazard component CAS-No. Content GHS Classification Fatty acids, C18-unsatd., dimers, reaction products 10-30 % Skin corrosion/irritation 2 with polyethylenepolyamines H315 Serious eye damage/eye irritation 1 H318 Skin sensitizer 1B H317 Acute hazards to the aquatic environment 1 H400 Chronic hazards to the aquatic environment 1 H410 poly(oxypropylene)triamine 5-6PO Talc 10-30 % Acute toxicity 4; Oral H302 Acute toxicity 4; Dermal H312 Serious eye damage/eye irritation 1 H318 Acute hazards to the aquatic environment 2 H401 Chronic hazards to the aquatic environment 2 H411 10-30 % Flammable liquids 3 H226 Acute toxicity 4; Oral H302 Skin corrosion/irritation 1 H314 Skin sensitizer 1 H317 Acute hazards to the aquatic environment 3 H402 1-10 % 1-10 % 1-10 % Acute toxicity 4; Oral H302 Acute toxicity 4; Dermal H312 Skin corrosion/irritation 1 H314 Skin sensitizer 1 H317 Acute hazards to the aquatic environment 3 H402 Chronic hazards to the aquatic environment 3 H412 Section 4. First aid measures Inhalation: Fresh air. Delayed effects possible after inhalation. Inform emergency services. Skin contact: Rinse immediately with plenty of running water (for 10 minutes). Remove all contaminated clothing and apply bandage. Seek medical advice.
Page 4 of 14 Eye contact: Immediately flush eyes with soft jet of water or eye rinse solution for at least 15 minutes. Hold eyelid wide-open. Seek a doctor/hospital, eye flushing should continue during transportation to a doctor. Ingestion: Rinse the mouth. Drink plenty of water. Immediate medical advice necessary. Do not induce vomiting. Indication of immediate medical attention and special treatment needed: See section: Description of first aid measures Suitable extinguishing media: All common extinguishing agents are suitable. Improper extinguishing media: High pressure waterjet Specific hazards arising from the chemical: In case of fire toxic gases can be released. Section 5. Fire fighting measures Special protection equipment and precautions for firefighters: Wear protective equipment. Wear self-contained breathing appaus. Personal precautions: Wear protective equipment. Avoid contact with skin and eyes. Keep unprotected persons away. Section 6. Accidental release measures Environmental precautions: Do not empty into drains / surface water / ground water. Inform authorities in the event of product spillage to water courses or sewage systems. Clean-up methods: Remove mechanically. Dispose of contaminated material as waste according to Section 13. Section 7. Handling and storage Handling: Avoid contact with eyes, skin and clothing. Avoid breathing fumes if this product is used at high tempeures. Use only with adequate ventilation. Do not take internally. For industrial use only. Storage: Ensure good ventilation/extraction. Store in a cool, dry place. Tempeures between + 5 C and + 35 C
Page 5 of 14 Components with specific control parameters for workplace: Section 8. Exposure controls / personal protection TALC, CONTAINING NO ASBESTOS FIBERS, RESPIRABLE FRACTION TALC - NON-ASBESTOS FORM Time Weighted Average (TWA): mg/m 3 2 Remarks ACGIH The value is for particulate matter containing no asbestos and <1% crystalline silica. Time Weighted Average (TWA): Remarks mg/m 3 10 TH OEL Time Weighted Average (TWA): Respiory protection: In case of dust formation, we recommend wearing of appropriate respiory protection equipment with particle filter P (EN 14387). This recommendation should be matched to local conditions. Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) This information is based on liteure references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. tempeure). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Goggles which can be tightly sealed. Protective eye equipment should conform to EN166. Body protection: Wear protective equipment. Protective clothing that covers arms and legs. Protective clothing should conform to EN 14605 for liquid splashes or to EN 13982 for dusts. Engineering controls: Ensure good ventilation/extraction. Hygienic measures: Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Section 9. Physical and chemical properties Appearance: Odor: Odor threshold (CA): ph: Melting point / freezing point: Specific gravity: Boiling point: Flash point: Evapoion e: Gray green paste amine-like > 100 C (> 212 F)
Page 6 of 14 Flammability (solid, gas): Lower explosive limit: Upper explosive limit: Vapor pressure: Vapor density: Density: Solubility: Partition coefficient: n- octanol/water: Auto ignition: Decomposition tempeure: Viscosity: (; 23 C (73.4 F); : no method) VOC content: 1.11 g/cm3 75 mpa.s Reactivity/Incompatible materials: None if used for intended purpose. Chemical stability: Stable under recommended storage conditions. Conditions to avoid: None if used for intended purpose. Hazardous decomposition products: No decomposition if used according to specifications. Section 10. Stability and reactivity Section 11. Toxicological information General toxicological information: Oral toxicity: Dermal toxicity: Persons suffering from allergic reactions to amines should avoid contact with the product. Acute toxicity estimate (ATE) : 1,686 mg/kg : Calculation method Acute toxicity estimate (ATE) : > 2,000 mg/kg : Calculation method
Page 7 of 14 Health Effects: Ingestion: Skin: Symptoms of Overexposure: Harmful if swallowed. May cause an allergic skin reaction. Causes burns. SKIN: Rash, Urticaria. INGESTION: Nausea, vomiting, diarrhea, abdominal pain. Acute oral toxicity: Fatty acids, C18-unsatd., dimers, reaction products with polyethylenepolyamines poly(oxypropylene)triamine 5-6PO Talc > 8,000 mg/kg not specified 550 mg/kg not specified > 2,000 mg/kg EU B.1 (Acute Toxicity (Oral)) > 2,000 mg/kg OECD Guideline 420 (Acute Oral Toxicity) 1,591.4 mg/kg OECD Guideline 401 (Acute Oral Toxicity)
Page 8 of 14 Acute inhalative toxicity: Acute toxicity estimate (ATE) 5.1 mg/l Expert judgement LC0 0.0812 mg/l 90 min Acute dermal toxicity: poly(oxypropylene)triamine 5-6PO poly(oxypropylene)triamine 5-6PO Skin corrosion/irritation: Acute toxicity estimate (ATE) 1,100 mg/kg Expert judgement > 1,000 mg/kg > 2,000 mg/kg OECD Guideline 402 (Acute Dermal Toxicity) 1,465 mg/kg OECD Guideline 402 (Acute Dermal Toxicity) Fatty acids, C18-unsatd., dimers, reaction products with polyethylenepolyamines poly(oxypropylene)triamine 5-6PO Talc irritating Human, EpiDermTM SIT (EPI-200), Reconstructed Human Epidermis (RHE) OECD Guideline 439 (In Vitro Skin Irritation: Reconstructed Human Epidermis (RHE) Test ) not irritating OECD Guideline 404 (Acute Dermal Irritation / Corrosion) slightly irritating 4 h OECD Guideline 404 (Acute Dermal Irritation / Corrosion) not irritating 4 h OECD Guideline 404 (Acute Dermal Irritation / Corrosion) corrosive not specified
Page 9 of 14 Serious eye damage/irritation: poly(oxypropylene)triamine 5-6PO Talc Talc Respiory or skin sensitization: Category 1 (irreversible effects on the eye) 1 s OECD Guideline 405 (Acute Eye Irritation / Corrosion) modeely irritating 24 h OECD Guideline 405 (Acute Eye Irritation / Corrosion) slightly irritating EU B.5 (Acute Toxicity: Eye Irritation / Corrosion) not irritating OECD Guideline 405 (Acute Eye Irritation / Corrosion) Germ cell mutagenicity: Test type Test type Test type Test type sensitising guinea pig not specified sensitising Guinea pig maximisation test guinea pig OECD Guideline 406 (Skin Sensitisation) not sensitising Mouse local lymphnode assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) sensitising Guinea pig maximisation test guinea pig Magnusson and Kligman Repeated dose toxicity: Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / / Frequency of treatment negative bacterial reverse mutation assay (e.g Ames test) with and without OECD Guideline 471 (Bacterial Reverse Mutation Assay) negative in vitro mammalian chromosome aberion test with and without OECD Guideline 473 (In vitro Mammalian Chromosome Aberion Test) negative mammalian cell gene mutation assay with and without OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test) positive bacterial reverse mutation assay (e.g Ames test) with and without not specified NOAEL=1,000 mg/kg oral: gavage 48 ddaily OECD Guideline 422 (Combined Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening Test)
Page 10 of 14 Section 12. Ecological information General ecological information: Ecotoxicity: Do not empty into drains, soil or bodies of water. Very toxic to aquatic life with long lasting effects. Toxicity: Fatty acids, C18-unsatd., dimers, reaction products with polyethylenepolyamines Fatty acids, C18-unsatd., dimers, reaction products with polyethylenepolyamines Fatty acids, C18-unsatd., dimers, reaction products with polyethylenepolyamines Fatty acids, C18-unsatd., dimers, reaction products with polyethylenepolyamines poly(oxypropylene)triamine 5-6PO poly(oxypropylene)triamine 5-6PO LC50 2.4 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) 0.46 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) NOEC 0.4 mg/l Scenedesmus subspicatus (new name: Desmodesmus subspicatus) 0.9 mg/l Scenedesmus subspicatus (new name: Desmodesmus subspicatus) 314 mg/l Bacteria 3 h activated sludge of a predominantly domestic sewage OECD Guideline 209 (Activated Sludge, Respiion Inhibition Test) LC50 > 120 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) 4.4 mg/l Pseudokirchnerella subcapitata NOEC 1 mg/l Pseudokirchnerella subcapitata LC50 122 mg/l Fish 96 h Leuciscus idus DIN 38412-15 59.5 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) 56.2 mg/l
Page 11 of 14 Talc Scenedesmus subspicatus (new name: Desmodesmus subspicatus) EC10 17 mg/l Bacteria 18 h Pseudomonas putida DIN 38412, part 8 (Pseudomonas Zellvermehrungshemm-Test) LC50 > 100 g/l Fish 24 h Brachydanio rerio (new name: Danio rerio) OECD Guideline 203 (Fish, Acute Toxicity Test) NOEC 14 mg/l Desmodesmus subspicatus LC50 570 mg/l Fish 96 h Poecilia reticulata OECD Guideline 203 (Fish, Acute Toxicity Test) 31 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC10 < 2.5 mg/l Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) 20 mg/l Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) EC0 137 mg/l Bacteria 30 min not specified Persistence and degradability: Fatty acids, C18-unsatd., dimers, reaction products with polyethylenepolyamines poly(oxypropylene)triamine 5-6PO Not readily biodegradable. aerobic Degradability > 0 - < 60 % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test) aerobic Degradability < 20 % OECD Guideline 302 B (Inherent biodegradability: Zahn-Wellens/EMPA Test) aerobic Degradability < 5 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test)
Page 12 of 14 inherently biodegradable not specified Degradability 100 % OECD Guideline 302 B (Inherent biodegradability: Zahn-Wellens/EMPA Test) readily biodegradable aerobic Degradability 65 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) aerobic Degradability 0 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) under test conditions no biodegradation observed aerobic Degradability 0 % OECD Guideline 302 B (Inherent biodegradability: Zahn-Wellens/EMPA Test) Bioaccumulative potential / Mobility in soil: Fatty acids, C18-unsatd., dimers, reaction products with polyethylenepolyamines LogPow 8.71 Tempeure QSAR (Quantitative Structure Activity Relationship) LogPow -0.352 Tempeure 25 C OECD Guideline 107 (Partition Coefficient (n-octanol / water), Shake Flask ) LogPow -2.12 Tempeure QSAR (Quantitative Structure Activity Relationship) LogPow -2.65 Tempeure OECD Guideline 107 (Partition Coefficient (n-octanol / water), Shake Flask ) Section 13. Disposal consideions Product Packaging of disposal: In consultation with the responsible local authority, must be subjected to special treatment. Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incineed. Disposal must be made according to official regulations. Section 14. Transport information
Page 13 of 14 Road transport ADR: Class: 8 Packing group: III Classification code: C8 Hazard ident. number: 80 UN no.: 3259 Label: 8 Technical name: AMINES, SOLID, CORROSIVE, N.O.S. (Dimethylaminopropylamine,,Polyamide resin) Railroad transport RID: Class: 8 Packing group: III Classification code: C8 Hazard ident. number: 80 UN no.: 3259 Label: 8 Technical name: AMINES, SOLID, CORROSIVE, N.O.S. (Dimethylaminopropylamine,,Polyamide resin) Inland water transport ADN: Class: 8 Packing group: III Classification code: C8 Hazard ident. number: UN no.: 3259 Label: 8 Technical name: AMINES, SOLID, CORROSIVE, N.O.S. (Dimethylaminopropylamine,,Polyamide resin) Marine transport IMDG: Class: 8 Packing group: III UN no.: 3259 Label: 8 EmS: F-A,S-B Seawater pollutant: Marine pollutant Proper shipping name: AMINES, SOLID, CORROSIVE, N.O.S. (Dimethylaminopropylamine,,Polyamide resin) Air transport IATA: Class: 8 Packing group: III Packaging instructions (passenger): 860 Packaging instructions (cargo): 864 UN no.: 3259 Label: 8 Proper shipping name: Amines, solid, corrosive, n.o.s. (Dimethylaminopropylamine,,Polyamide resin)
Page 14 of 14 Section 15. Regulatory information Regulatory Information: Ministry of Industry Notice. The system to classify and communicate the hazard of hazardous material, BE. 2555 Global inventory status: Regulatory list TSCA AICS DSL KECI (KR) PICCS (PH) IECSC NZIOC Notification yes yes yes yes yes yes yes Section 16. Other information Disclaimer: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.