Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/2006 Ceresit CE 49 Epoxi-Flexdicht K.A. Page 1 of 9 sds no. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier: Ceresit CE 49 Epoxi-Flexdicht K.A. Relevant identified uses of the substance or mixture and uses advised against: Intended use: Special product Details of the supplier of the safety data sheet: Henkel AG & Co. KGaA Henkelstr Düsseldorf Germany Phone: +49 (211) ua-productsafety.de@henkel.com Emergency Telephone Number: The Henkel information service also provides an around-the-clock telephone service on phone no.+49-(0) for exceptional cases. The product is notified at the 'Information Centers for Cases of Poisoning in Germany'. These centers provide information by telephone day and night in poisoning cases. Central emergency phone number: ++49 (0) Classification of the substance or mixture: SECTION 2: Hazards identification Classification (DPD): Xi - Irritant R36/38 Irritating to eyes and skin. Sensitizing R43 May cause sensitisation by skin contact. N - Dangerous for the environment R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

2 Ceresit CE 49 Epoxi-Flexdicht K.A. Page 2 of 9 Label elements (DPD): Xi - Irritant N - Dangerous for the environment Risk phrases: R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S23 Do not breathe vapour. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S51 Use only in well-ventilated areas. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Additional labeling: Contains epoxide compounds. Observe manufacturer's instructions! Contains: Bisphenol-A epichlorhydrin resin MW <= 700, Bisphenol-F epichlorhydrin resin; MW<700, Oxirane, mono[(c12-14-alkyloxy)methyl] derivates Other hazards: Persons suffering from allergic reactions to epoxides should avoid contact with the product. General chemical description: Reaction resin Base substances of preparation: Epoxy resin combination SECTION 3: Composition/information on ingredients

3 Ceresit CE 49 Epoxi-Flexdicht K.A. Page 3 of 9 Declaration of the ingredients according to CLP (EC) No 1272/2008: Bisphenol-A epichlorhydrin resin MW <= Bisphenol-F epichlorhydrin resin; MW< Oxirane, mono[(c12-14-alkyloxy)methyl] derivates EC Number REACH-Reg No content Classification > 30 % Chronic hazards to the aquatic environment 2 H411 Serious eye irritation 2 H319 Skin irritation 2 H315 Skin sensitizer 1 H < 10 % Serious eye irritation 2 H319 Skin irritation 2 H315 Skin sensitizer 1 H317 Chronic hazards to the aquatic environment 2 H < 10 % Skin irritation 2 H315 Skin sensitizer 1 H317 Only dangerous ingredients for which a CLP classification is already available are displayed in this table. For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. Declaration of ingredients according to DPD (EC) No 1999/45: Bisphenol-A epichlorhydrin resin MW <= Bisphenol-F epichlorhydrin resin; MW< Oxirane, mono[(c alkyloxy)methyl] derivates EC Number REACH-Reg No content Classification > 30 % R43 Xi - Irritant; R36/38 N - Dangerous for the environment; R51/ < 10 % Xi - Irritant; R36/38 Xi - Irritant; R N - Dangerous for the environment; R51/53 < 10 % R43 Xi - Irritant; R38 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available. Description of first aid measures: General information: In case of adverse health effects seek medical advice. Inhalation: Move to fresh air, consult doctor if complaint persists. SECTION 4: First aid measures Skin contact: Rinse with running water and soap. Skin care. Remove contaminated clothes immediately. Eye contact: Rinse immediately with plenty of running water, seek medical advice from a specialist. Ingestion: Rinse mouth and throat. Drink 1-2 glasses of water. Seek medical advice.

4 Ceresit CE 49 Epoxi-Flexdicht K.A. Page 4 of 9 Most important symptoms and effects, both acute and delayed: EYE: Irritation, conjunctivitis. SKIN: Rash, Urticaria. Indication of any immediate medical attention and special treatment needed: See section: Description of first aid measures SECTION 5: Firefighting measures Extinguishing media: Suitable extinguishing media: carbon dioxide, foam, powder, water spray jet, fine water spray Extinguishing media which must not be used for safety reasons: High pressure waterjet Special hazards arising from the substance or mixture: In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released. Advice for firefighters: Wear self-contained breathing apparatus. Wear protective equipment. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures: Avoid contact with skin and eyes. Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not empty into drains / surface water / ground water. Methods and material for containment and cleaning up: Remove mechanically. Dispose of contaminated material as waste according to Chapter 13. Reference to other sections: See advice in chapter 8 Precautions for safe handling: Ensure good ventilation/suction at the workplace. Hygiene measures: Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work. SECTION 7: Handling and storage Conditions for safe storage, including any incompatibilities: Close the container carefully after use and store it at a good ventilated place. Temperatures between - 5 C and + 40 C Do not store together with food or other consumables (coffee, tea, tobacco, etc.). Specific end use(s): Special product

5 Ceresit CE 49 Epoxi-Flexdicht K.A. Page 5 of 9 SECTION 8: Exposure controls/personal protection Control parameters: Valid for Germany Basis Germany - Occupational Exposure Limits None Exposure controls: Respiratory protection: When processing large amounts. Suitable breathing mask when there is inadequate ventilation. Hand protection: Recommended are gloves made from Nitril rubber ( Material thickness >0,1 mm, Perforation time < 30s).Gloves should be replaced after each short time contact or contamination. Available at laboratory specialized trade or at pharmacies / chemist's shops. Eye protection: Goggles which can be tightly sealed. Skin protection: Suitable protective clothing SECTION 9: Physical and chemical properties Information on basic physical and chemical properties: Appearance liquid pasty anthracite Odor characteristic ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density (20 C (68 F)) Bulk density Viscosity (Haake; 20 C (68 F)) Viscosity (kinematic) Explosive properties Solubility (qualitative) (23 C (73.4 F); Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties 1,3 g/cm mpa.s Not miscible or difficult to mix Other information:

6 Ceresit CE 49 Epoxi-Flexdicht K.A. Page 6 of 9 SECTION 10: Stability and reactivity Reactivity: Reaction with strong acids. Reaction with strong bases Reacts with strong oxidants. Chemical stability: Stable under recommended storage conditions. Possibility of hazardous reactions: See section reactivity Conditions to avoid: None if used for intended purpose. Incompatible materials: None if used properly. Hazardous decomposition products: None known SECTION 11: Toxicological information General toxicological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Cross-reactions with other epoxide compounds possible. Persons suffering from allergic reactions to epoxides should avoid contact with the product. Skin irritation: Primary skin irritation: irritating Eye irritation: Primary eye irritation: irritating Sensitizing: May cause sensitization by skin contact. Germ cell mutagenicity: Bisphenol-A epichlorhydrin resin MW <= Result Type of study / Route of administration positive bacterial reverse mutation assay (e.g Ames test) Metabolic activation / Exposure time with and without Species Method SECTION 12: Ecological information General ecological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Do not empty into drains, soil or bodies of water.

7 Ceresit CE 49 Epoxi-Flexdicht K.A. Page 7 of 9 Toxicity: Oxirane, mono[(c alkyloxy)methyl] derivates Oxirane, mono[(c alkyloxy)methyl] derivates Value type Value Acute Toxicity Study Exposure time Species Method LC mg/l Fish 96 h OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) Persistence and degradability: Oxirane, mono[(c alkyloxy)methyl] derivates Result Route of Degradability application aerobic < 10 % Method SECTION 13: Disposal considerations Waste treatment methods: Product disposal: Dispose of waste and residues in accordance with local authority requirements. Disposal of uncleaned packages: Use packages for recycling only when totally empty. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances Road transport ADR: SECTION 14: Transport information Classification code: M6 Hazard ident. number: 90 Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (epoxy resin) Tunnelcode: (E) Railroad transport RID: Classification code: M6 Hazard ident. number: 90 Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (epoxy resin) Tunnelcode:

8 Ceresit CE 49 Epoxi-Flexdicht K.A. Page 8 of 9 Inland water transport ADN: Classification code: M6 Hazard ident. number: Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (epoxy resin) Marine transport IMDG: EmS: F-A,S-F Seawater pollutant: Marine pollutant Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (epoxy resin) Air transport IATA: Packaging instructions (passenger) 964 Packaging instructions (cargo) 964 Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (epoxy resin) SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture: VOC Paints and Varnishes (EU): Regulatory Basis: Product (sub)category: Phase I (from ): Phase II (from ): max. VOC content: Directive 2004/42/EC Two-pack reactive performance coatings for specific end use such as floors 550 g/l 500 g/l 0 g/l National regulations/information (Germany): WGK: 2, water-endangering product. (German VwVwS of May 17, 1999 ) Classification in conformity with the calculation method BG regulations, rules, infos: BG information: BGI 655 Epoxy resins in the construction industry BG regulation: BGV B 1 Handling hazardous substances BG data sheet: ZH 1 / 301 Polyester and epoxy resins Storage class VCI: 10 GISCODE: RE3 Epoxy resin products, containing solvents, sensitizing

9 Ceresit CE 49 Epoxi-Flexdicht K.A. Page 9 of 9 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R36/38 Irritating to eyes and skin. R38 Irritating to skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. Further information: The product is intended for industrial use. This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.