MATERIAL SAFETY DATA SHEET SECTION 1 - IDENTIFICATION OF PRODUCT AND COMPANY Pfizer Inc Pfizer Animal Health 235 East 42nd Street New York, NY 10017 Product name Therapeutic use Description Emergency telephone Hours of operation Telephone Granulex V Aerosol Spray Veterinary topical wound dressing Aerosol spray 1-866-531-8896 24 Hours 1-800-366-5288 SECTION 2 - COMPOSITION Ingredient CAS Number Amount Balsam of Peru, N.F.* Not assigned Trade secret Castor oil 8001-79-4 Trade secret Trypsin, crystalline* 9002-07-7 Trade secret Inert propellant* Not assigned 25% *Hazardous Note: Ingredient(s) indicated as hazardous have been assessed under standards for workplace safety. SECTION 3 - HAZARDS IDENTIFICATION Signal word Statements of hazard WARNING! FLAMMABLE! MAY BE HARMFUL IF INHALED MAY CAUSE EYE AND SKIN IRRITATION Eye effects Skin effects Inhalation effects Ingestion effects MAY CAUSE ALLERGIC SKIN REACTION May cause irritation based on components. May cause skin irritation. May cause allergic skin reaction. Exposure to sunlight following contact may result in skin reactions. Inhalation of large amounts of propellant components may be harmful. See 'Statements of hazard' and/or 'Other potential health effects' in this section. See 'Statements of hazard', 'Known clinical effects', and/or 'Other potential health effects' in this section. Page 1 of 6
SECTION 3 - HAZARDS IDENTIFICATION... continued Known clinical effects Other potential health effects NOTE: When applied to sensitive areas, a temporary stinging sensation may be noted. Intentional misuse by concentrating and inhaling the contents can be harmful or fatal. Peruvian balsam may cause allergic reactions following internal or external consumption. Peruvian balsam may increase sensitivity to sunlight. Internal or external use of large quantities of Balsam of Peru may damage the kidneys. This document has been prepared in accordance with standards for workplace safety, which require the inclusion of all known hazards of the product or its ingredients regardless of the potential risk. The precautionary statements and warnings included may not apply in all cases. Your needs may vary depending upon the potential for exposure in your workplace. SECTION 4 - FIRST AID MEASURES Skin Eyes Inhalation Ingestion Remove contaminated clothing and shoes. Wash skin with soap and water. This material may not be completely removed by conventional laundering. Consult professional laundry service. Do not home launder. If irritation occurs or persists, get medical attention. Immediately flush eyes with water for at least 15 minutes. If irritation occurs or persists, get medical attention. Remove to fresh air. If not breathing, give artificial respiration. Get medical attention. Get medical attention. Do not induce vomiting unless directed by medical personnel. Never give anything by mouth to an unconscious person. SECTION 5 - FIRE FIGHTING MEASURES General hazard Fire fighting instructions Extinguishing media Flash point Hazardous combustion products Flammable. Contents under pressure. Wear approved positive pressure, self-contained breathing apparatus and full protective turn out gear. Evacuate area and fight fire from a safe distance. Use water, carbon dioxide, foam or dry chemical extinguishers. Page 2 of 6
SECTION 6 - ACCIDENTAL RELEASE MEASURES General Small spill Large spill Review Sections 3, 8 and 12 before proceeding with clean up. Use non-combustible absorbent material to wipe up spill and place in a sealed container for disposal. Clean spill area thoroughly. Collect spill with a non-combustible absorbent material. Transfer all waste to a labeled container and move it to a secure holding area. SECTION 7 - HANDLING AND STORAGE General handling Storage conditions Contents under pressure, do not puncture or incinerate. Eliminate possible ignition sources (e.g., heat, sparks, flame, impact, friction, electricity), and follow appropriate grounding and bonding procedures. Use only in a wellventilated area. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Store in a cool, dry, well-ventilated area. Keep container tightly closed when not in use. Do not expose to temperatures above 120 F. SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation Respiratory protection Eye protection Skin protection Hand protection Local and general ventilation should be used as necessary, when handling this material in bulk. Respiratory protection is not expected to be necessary under normal handling conditions; required only if mist is generated. Safety glasses or goggles Use protective clothing (uniforms, lab coats, disposable coveralls, etc.) in both production and laboratory areas. Chemical protective gloves SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical form Color Molecular weight Molecular formula ph Boiling point Melting point Aerosol Mixture Mixture Not applicable Page 3 of 6
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES... continued Density Vapor pressure Water solubility Solvent solubility SECTION 10 - STABILITY AND REACTIVITY Reactivity Conditions to avoid Incompatibilities Hazardous decomposition products Hazardous polymerization Eliminate possible ignition sources (e.g., heat, sparks, flame, impact, friction, electricity). Do not expose to temperatures above 120 F. Will not occur SECTION 11 - TOXICOLOGY INFORMATION Toxicology summary Acute toxicity Eye Skin Inhalation Ingestion Sensitization Subchronic effects Chronic effects/ carcinogenicity Carcinogen status Additional information The information included in this section describes the potential hazards of the individual ingredients, except where noted. May cause eye irritation. May cause skin irritation. Not determined for this mixture. Ingestion of Balsam of Peru may cause allergic reactions. Skin sensitization and/or photosensitization (allergic response after UV exposure) have been demonstrated with usage of Peruvian balsam. None of the components of this formulation are listed as a carcinogen by IARC, NTP or OSHA. Kidney damage has been observed following internal as well as external consumption of large dosages of Peruvian balsam. Page 4 of 6
SECTION 12 - ECOLOGICAL INFORMATION Environmental overview The environmental characteristics of this mixture have not been fully evaluated. Releases to the environment should be avoided. SECTION 13 - DISPOSAL INFORMATION Disposal procedure Do not incinerate. Observe all local and national regulations when disposing of this material. SECTION 14 - TRANSPORTATION INFORMATION General shipping instructions Proper shipping name This material is regulated for transportation as a hazardous material/dangerous good. Aerosols Identification number UN 1950 Hazard class 2.1 Note: U.S. DOT proper shipping name U.S. DOT hazard class 9 IATA proper shipping name IATA identification number IATA hazard class 2.1 IMDG proper shipping name See 173.306: For small quantities, limited to inner packaging less than or equal to 4 oz capacity and outer packaging less than or equal to 30 kg (66 lb.) gross weight, the following may be used: Consumer Commodity Aerosols UN 1950 Aerosols IMDG Identification No. UN 1950 IMDG hazard class 2.1 IMDG packing group Not applicable SECTION 15 - REGULATORY INFORMATION EU Classification Risk phrases Flammable R10 - Flammable. Page 5 of 6
SECTION 15 - REGULATORY INFORMATION... continued Safety phrases Canadian WHMIS Class B, Division 5 S16 - Keep away from sources of ignition - No smoking. S23 - Do not breathe gas/fumes/vapour/spray. S24/25 - Avoid contact with eyes and skin. S51 - Use only in well-ventilated areas. SECTION 16 - OTHER Disclaimer Pfizer Inc believes that the information contained in this Material Safety Data Sheet is accurate, and while it is provided in good faith, it is without a warranty of any kind, expressed or implied. Page 6 of 6