: 3010 ULTRA SAFETY DATA SHEET. Revision Date: Version 1. MSDS Number: Date of last issue: - Date of first issue:

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1 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Product code : SDS-Identcode : 379G Manufacturer or supplier's details Company : Bestolife Corporation Address : 2777 N. Stemmons Frwy Ste 1800 Dallas TX 75207, Telephone : / Emergency telephone number : CHEMTREC: , International: Telefax : Recommended use of the chemical and restrictions on use Recommended use : Industrial use Thread Compound (Pipe Dope) and Jacking grease for use in Offshore industries Mining, (without offshore industries) Restrictions on use : Do not use on oxygen lines or in oxygen enriched atmospheres. 2. HAZARDS IDENTIFICATION GHS Classification Not a hazardous substance or mixture. GHS Label element Not a hazardous substance or mixture. Other hazards which do not result in classification None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture 1 / 15

2 Hazardous components Chemical Name CAS-No. Concentration (%) Graphite >= 30 - < 50 Distillates (petroleum), hydrotreated light naphthenic >= 30 - < 50 Talc >= 10 - < 20 Quartz >= 1 - < 10 Boric acid >= < 1 4. FIRST AID MEASURES If inhaled In case of skin contact In case of eye contact If swallowed Most important symptoms and effects, both acute and delayed Protection of first-aiders Notes to physician : If inhaled, remove to fresh air. Get medical attention if symptoms occur. : Wash with water and soap as a precaution. Get medical attention if symptoms occur. : Flush eyes with water as a precaution. Get medical attention if irritation develops and persists. : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water. : None known. : No special precautions are necessary for first aid responders. : Treat symptomatically and supportively. 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Specific extinguishing methods : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical : None known. : Exposure to combustion products may be a hazard to health. : Carbon oxides Silicon oxides : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. 2 / 15

3 Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Follow safe handling advice and personal protective equipment recommendations. : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. : Sweep up or vacuum up spillage and collect in suitable container for disposal. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. 7. HANDLING AND STORAGE Technical measures Local/Total ventilation Advice on safe handling Conditions for safe storage Materials to avoid : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. : Use only with adequate ventilation. : Handle in accordance with good industrial hygiene and safety practice. Take care to prevent spills, waste and minimize release to the environment. : Keep in properly labelled containers. Store in accordance with the particular national regulations. : Do not store with the following product types: Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters 3 / 15

4 Components CAS-No. Value type (Form of exposure) Graphite PEL (long term) (Respirable dust) TWA (Respirable fraction) Distillates (petroleum), hydrotreated PEL (long light naphthenic term) (Mist) PEL (short term) (Mist) TWA (Inhalable fraction) Talc PEL (long term) TWA (Respirable fraction) Quartz PEL (long term) (Respirable dust) TWA (Respirable fraction) Boric acid TWA (Inhalable fraction) STEL (Inhalable fraction) Engineering measures Control parameters / Permissible Basis concentration 2 mg/m3 SG OEL 2 mg/m3 ACGIH 5 mg/m3 SG OEL 10 mg/m3 SG OEL 5 mg/m3 ACGIH 2 mg/m3 SG OEL 2 mg/m3 ACGIH 0.1 mg/m3 SG OEL mg/m3 (Silica) 2 mg/m3 (Borate) 6 mg/m3 (Borate) ACGIH ACGIH ACGIH : Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations. Personal protective equipment Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Filter type : Particulates type Hand protection Remarks Eye protection Skin and body protection Hygiene measures : Wash hands before breaks and at the end of workday. : Wear the following personal protective equipment: Safety glasses : Skin should be washed after contact. : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. 4 / 15

5 Wash contaminated clothing before re-use. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour Odour Odour Threshold ph : Viscous semi-solid : black : Petroleum : Not applicable (not an aqueous solution) Initial boiling point and boiling range : 208 C Flash point : > 150 C Method: Cleveland open cup Evaporation rate : < 1 Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Relative density : 1.3 Density Solubility(ies) Water solubility Partition coefficient: n- octanol/water Auto-ignition temperature Decomposition temperature Viscosity Viscosity, dynamic Viscosity, kinematic : negligible : cst (40 C) 5 / 15

6 1.817 mm2/s (40 C) Flow time Explosive properties Oxidizing properties Molecular weight : Not explosive : The substance or mixture is not classified as oxidizing. 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Not classified as a reactivity hazard. : Stable under normal conditions. : Can react with strong oxidizing agents. : None known. : Oxidizing agents : No hazardous decomposition products are known. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Skin contact Ingestion Eye contact Acute toxicity Acute oral toxicity Acute inhalation toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 401 Assessment: The substance or mixture has no acute oral toxicity : LC50 (Rat): > 2 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Assessment: The substance or mixture has no acute inhalation toxicity Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg 6 / 15

7 Method: OECD Test Guideline 401 Acute inhalation toxicity Acute dermal toxicity Acute oral toxicity Quartz: Acute oral toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity : LC50 (Rat): > 5.53 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Assessment: The substance or mixture has no acute inhalation toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg Remarks: Based on data from similar materials : LD50 (Rat): > 5,000 mg/kg : LD50 (Rat): 3,500-4,100 mg/kg : LC50 (Rat): > 2.03 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Assessment: The substance or mixture has no acute inhalation toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Skin corrosion/irritation Method: OECD Test Guideline 404 Result: No skin irritation Result: No skin irritation Result: No skin irritation Result: No skin irritation 7 / 15

8 Serious eye damage/eye irritation Result: No eye irritation Result: No eye irritation Result: No eye irritation Result: No eye irritation Respiratory or skin sensitisation Skin sensitisation: Respiratory sensitisation: Test Type: Local lymph node assay (LLNA) Exposure routes: Skin contact Species: Mouse Test Type: Buehler Test Exposure routes: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Exposure routes: Skin contact Species: Humans Exposure routes: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Germ cell mutagenicity 8 / 15

9 Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 476 Genotoxicity in vivo Genotoxicity in vitro Genotoxicity in vivo Genotoxicity in vitro Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Method: OECD Test Guideline 474 : Test Type: DNA damage and repair, unscheduled DNA synthesis in mammalian cells (in vitro) : Test Type: Chromosome aberration test in vitro : Test Type: Bacterial reverse mutation assay (AMES) : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Carcinogenicity Species: Mouse Application Route: Skin contact Exposure time: 78 weeks Species: Mouse Application Route: inhalation (dust/mist/fume) Exposure time: 2 Years 9 / 15

10 Quartz: Species: Humans Application Route: inhalation (dust/mist/fume) Result: positive Remarks: IARC (International Agency for Research on Cancer) The substance is inextricably bound in the product and therefore does not contribute to a dust inhalation hazard. Carcinogenicity - Assessment : Positive evidence from human epidemiological studies (inhalation) Species: Mouse Exposure time: 103 weeks Method: OECD Test Guideline 451 Reproductive toxicity Effects on fertility : Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Method: OECD Test Guideline 422 Effects on foetal development : Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Method: OECD Test Guideline 422 Effects on fertility : Test Type: Reproduction/Developmental toxicity screening test Effects on foetal development Effects on foetal development : Test Type: Embryo-foetal development Application Route: Skin contact : Test Type: Embryo-foetal development 10 / 15

11 Effects on fertility Effects on foetal development Reproductive toxicity - Assessment : Test Type: Three-generation reproduction toxicity study Result: positive : Test Type: Embryo-foetal development Result: positive : Clear evidence of adverse effects on sexual function and fertility, based on animal experiments., Clear evidence of adverse effects on development, based on animal experiments. STOT - single exposure STOT - repeated exposure Quartz: Exposure routes: inhalation (dust/mist/fume) Target Organs: Lungs Assessment: Shown to produce significant health effects in animals at concentrations of 0.02 mg/l/6h/d or less. Repeated dose toxicity NOAEL: 12 mg/m3 Application Route: inhalation (dust/mist/fume) Exposure time: 28 d Method: OECD Test Guideline 412 NOAEL: 1,000 mg/kg Application Route: Skin contact Exposure time: 4 w Method: OECD Test Guideline 410 Quartz: Species: Humans LOAEL: mg/m3 Application Route: inhalation (dust/mist/fume) Remarks: The substance is inextricably bound in the product and therefore does not contribute to a dust inhalation hazard. 11 / 15

12 NOAEL: 100 mg/kg LOAEL: 334 mg/kg Exposure time: 2 y Aspiration toxicity 12. ECOLOGICAL INFORMATION Ecotoxicity Toxicity to fish Toxicity to daphnia and other aquatic invertebrates : LC50 (Danio rerio (zebra fish)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 : EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): > 100 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to bacteria : EC50: > 1,012.5 mg/l Exposure time: 3 h Method: OECD Test Guideline 209 Toxicity to fish : LL50 (Pimephales promelas (fathead minnow)): > 100 mg/l Exposure time: 96 h Test substance: Water Accommodated Fraction Toxicity to daphnia and other aquatic invertebrates : EL50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 48 h Test substance: Water Accommodated Fraction Toxicity to algae : NOELR (Pseudokirchneriella subcapitata (green algae)): >= 100 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) Toxicity to bacteria : NOEC (Daphnia magna (Water flea)): 10 mg/l Exposure time: 21 d : NOEC (Photobacterium phosphoreum): > 2.17 mg/l Exposure time: 4 d 12 / 15

13 Toxicity to fish Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae : LC50 (Brachydanio rerio (zebrafish)): > 100,000 mg/l Exposure time: 24 h : LC50 (Oncorhynchus kisutch (coho salmon)): 600 mg/l Exposure time: 96 h : EC50 (Daphnia magna (Water flea)): 133 mg/l Exposure time: 48 h : EC50 (Selenastrum capricornutum (green algae)): 52.4 mg/l Exposure time: 72 h NOEC (Selenastrum capricornutum (green algae)): 17.5 mg/l Exposure time: 72 h Toxicity to fish (Chronic toxicity) Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) Toxicity to bacteria : NOEC (Pimephales promelas (fathead minnow)): 11.2 mg/l Exposure time: 32 d : NOEC (Chironomus riparius (harlequin fly)): 32 mg/l Exposure time: 28 d : EC50: > 175 mg/l Exposure time: 3 h Method: OECD Test Guideline 209 Persistence and degradability Biodegradability : Result: Not readily biodegradable. Biodegradation: 2-8 % Exposure time: 28 d Method: OECD Test Guideline 301B Bioaccumulative potential Bioaccumulation Partition coefficient: n- octanol/water : Species: Oysters Bioconcentration factor (BCF): : log Pow: -9 Mobility in soil No data available 13 / 15

14 Other adverse effects No data available 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues Contaminated packaging : Dispose of in accordance with local regulations. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. TRANSPORT INFORMATION International Regulation UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Workplace Safety and Health Act and Workplace Safety and Health (General Provisions) Regulations: This product is subjected to the SDS, labelling, PEL and other requirements in the Act/Regulations. Environmental Protection and Management Act and : Boric acid Environmental Protection and Management (Hazardous Substances) Regulations The components of this product are reported in the following inventories: DSL : All components of this product are on the Canadian DSL TSCA : All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. Inventories 14 / 15

15 AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) 16. OTHER INFORMATION Further information Sources of key data used to compile the Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD echem Portal search results and European Chemicals Agency, Items where changes have been made to the previous version are highlighted in the body of this document by two vertical lines. Date format : dd.mm.yyyy Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) SG OEL : Singapore. Workplace Safety and Health Act - First Schedule Permissible Exposure Limits of Toxic Substances ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit SG OEL / PEL (long term) : Permissible Exposure Level (PEL) Long Term SG OEL / PEL (short term) : Permissible Exposure Level (PEL) Short Term The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user s end product, if applicable. SG / EN 15 / 15

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