MICRELL Antibacterial Lotion Soap

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Manufacturer or supplier's details Company : GOJO Australasia Pty Ltd Address : Suite G2, 64 Talavera Road Macquarie Park, NSW, 2113 Telephone : Emergency telephone number : Telefax : Recommended use of the chemical and restrictions on use Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Serious eye damage/eye irritation : Category 2A GHS Label element Hazard pictograms : Signal word Hazard statements Precautionary statements : Warning : H319 Causes serious eye irritation. : Prevention: 1 / 13

2 P280 Wear eye protection/ face protection. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Other hazards which do not result in classification None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical Name CAS-No. Concentration (%) Ethanolamine < 10 Propylene Glycol < 10 Chloroxylenol < 10 SECTION 4. FIRST AID MEASURES General advice If inhaled In case of skin contact In case of eye contact If swallowed Most important symptoms and effects, both acute and delayed Protection of first-aiders : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. : If inhaled, remove to fresh air. If symptoms persist, call a physician. : Wash with water and soap as a precaution. Get medical attention immediately if irritation develops and persists. : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Seek medical advice. : If swallowed, DO NOT induce vomiting. Rinse mouth with water. Obtain medical attention. : Causes serious eye irritation. : First Aid responders should pay attention to self-protection and use the recommended protective clothing SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam 2 / 13

3 Dry chemical Carbon dioxide (CO2) Unsuitable extinguishing media Hazardous combustion products Specific extinguishing methods Special protective equipment for firefighters : None known. : Carbon oxides Metal oxides Sulphur oxides Nitrogen oxides (NOx) : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Material can create slippery conditions. : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. : Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while observing environmental regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : For personal protection see section 8. Do not swallow. Avoid contact with eyes. Keep container closed when not in use. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Do not get in eyes. 3 / 13

4 Conditions for safe storage : Keep in properly labelled containers. Keep container tightly closed in a dry and well-ventilated place. Store in accordance with the particular national regulations. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Ethanolamine TWA 3 ppm AU OEL 7.5 mg/m3 STEL 6 ppm AU OEL 15 mg/m3 TWA 3 ppm ACGIH STEL 6 ppm ACGIH TWA 3 ppm NIOSH REL 8 mg/m3 ST 6 ppm NIOSH REL 15 mg/m3 TWA 3 ppm OSHA Z-1 6 mg/m3 STEL 6 ppm OSHA P0 15 mg/m3 TWA 3 ppm OSHA P0 8 mg/m3 Propylene Glycol TWA (particulate) 10 mg/m3 AU OEL TWA (Total (vapour and particles)) 150 ppm 474 mg/m3 AU OEL Personal protective equipment Respiratory protection TWA 10 mg/m3 US WEEL : No personal respiratory protective equipment normally required. Eye protection Skin and body protection Protective measures : No special measures necessary provided product is used correctly. Wear face-shield and protective suit for abnormal processing problems. : No special measures necessary provided product is used correctly. : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. Ensure that eye flushing systems and safety showers are located close to the working place. 4 / 13

5 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour Odour Odour Threshold : liquid : clear, colourless, yellow : pleasant ph : 7-10 Melting point/freezing point Boiling point/boiling range : C Flash point : C Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Density Solubility(ies) Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity Viscosity, kinematic : Not applicable : g/cm3 : soluble : Not applicable : not determined : The substance or mixture is not classified self-reactive. : 1,000-20,000 mm2/s (20 C) Explosive properties Oxidizing properties : Not explosive : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity Chemical stability : Not classified as a reactivity hazard. : Stable under normal conditions. 5 / 13

6 Incompatible materials Hazardous decomposition products : Oxidizing agents : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Exposure routes : Inhalation Skin contact Eye contact Acute toxicity Product: Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity : Acute toxicity estimate : > 2,000 mg/kg Method: Calculation method : Acute toxicity estimate : > 20 mg/l Exposure time: 4 h Test atmosphere: vapour Method: Calculation method : Acute toxicity estimate : > 2,000 mg/kg Method: Calculation method Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Acute oral toxicity : LD50 (Rat): 1,515 mg/kg : Acute toxicity estimate : 11 mg/l Test atmosphere: vapour Method: Expert judgement Remarks: Based on harmonised classification in EU regulati on 1272/2008, Annex VI : LD50 (Rabbit): 1,025 mg/kg : LD50 (Rat): > 5,000 mg/kg : LC50 (Rabbit): > 159 mg/l, > ppm Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity : Acute toxicity estimate : 500 mg/kg Method: Expert judgement 6 / 13

7 Remarks: Based on harmonised classification in EU regulati on 1272/2008, Annex VI Acute inhalation toxicity Acute dermal toxicity : LC50 (Rat): > 6.29 mg/l Test atmosphere: dust/mist : LD50 (Rat): > 2,000 mg/kg Skin corrosion/irritation Product: Assessment: No skin irritation Species: Rabbit Result: Corrosive after 3 minutes to 1 hour of exposure Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Result: Skin irritation Remarks: Based on harmonised classification in EU regulati on 1272/2008, Annex VI Serious eye damage/eye irritation Causes serious eye irritation. Species: Rabbit Result: Irreversible effects on the eye Species: Rabbit Result: No eye irritation Method: OECD Test Guideline 405 Result: Irreversible effects on the eye Respiratory or skin sensitisation Skin sensitisation: Respiratory sensitisation: Product: Assessment: Does not cause skin sensitisation. 7 / 13

8 Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Assessment: Probability or evidence of skin sensitisation in humans Remarks: Based on harmonised classification in EU regulati on 1272/2008, Annex VI Chronic toxicity Germ cell mutagenicity Genotoxicity in vitro Genotoxicity in vivo Genotoxicity in vitro Genotoxicity in vivo Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Test species: Mouse Method: OECD Test Guideline 474 : Test Type: Bacterial reverse mutation assay (AMES) : Test Type: In vivo micronucleus test Test species: Mouse Application Route: Intraperitoneal injection : Test Type: Bacterial reverse mutation assay (AMES) Carcinogenicity Species: Rat Exposure time: 2 Years 8 / 13

9 Reproductive toxicity Effects on fertility Effects on foetal development Effects on fertility Effects on foetal development : Test Type: Two-generation reproduction toxicity study Species: Rat : Test Type: Embryo-foetal development Species: Rat Method: OECD Test Guideline 414 : Species: Mouse : Test Type: Embryo-foetal development Species: Mouse STOT - single exposure Assessment: May cause respiratory irritation. STOT - repeated exposure Exposure routes: inhalation (dust/mist/fume) Assessment: No significant health effects observed in animals at concentrations of 0.2 mg/l/6h/d or less. Repeated dose toxicity Species: Rat NOAEL: 150 mg/m3 Application Route: inhalation (dust/mist/fume) Exposure time: 28 d Species: Rat NOAEL: 1,700 mg/kg 9 / 13

10 Exposure time: 2 y Species: Rabbit LOAEL: 180 mg/kg Application Route: Skin contact Exposure time: 90 d Aspiration toxicity SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae : LC50 (Cyprinus carpio (Carp)): 349 mg/l Exposure time: 96 h : EC50 (Daphnia magna (Water flea)): 65 mg/l Exposure time: 48 h : ErC50 (Selenastrum capricornutum (green algae)): 2.8 mg/l Exposure time: 72 h NOEC (Scenedesmus capricornutum (fresh water algae)): 1 mg/l Exposure time: 72 h Toxicity to fish (Chronic toxicity) Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) Toxicity to bacteria Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Toxicity to fish (Chronic toxicity) Toxicity to daphnia and other aquatic invertebrates (Chron- : NOEC (Oryzias latipes (Orange-red killifish)): 1.24 mg/l Exposure time: 41 d : NOEC (Daphnia magna (Water flea)): 0.85 mg/l Exposure time: 21 d : EC50 (Pseudomonas putida): 110 mg/l Exposure time: 17 h : LC50 (Oncorhynchus mykiss (rainbow trout)): 40,613 mg/l Exposure time: 96 h : EC50 (Ceriodaphnia Dubia (water flea)): 18,340 mg/l Exposure time: 48 h : EC50 (Skeletonema costatum (marine diatom)): 19,000 mg/l Exposure time: 48 h Method: OECD Test Guideline 201 : Chronic Toxicity Value: 2,500 mg/l Exposure time: 30 d : NOEC (Ceriodaphnia Dubia (water flea)): 29,000 mg/l Exposure time: 7 d 10 / 13

11 ic toxicity) Toxicity to bacteria Toxicity to fish Toxicity to daphnia and other aquatic invertebrates M-Factor (Acute aquatic toxicity) : NOEC (Pseudomonas putida): > 20,000 mg/l Exposure time: 18 h : LC50 (Oncorhynchus mykiss (rainbow trout)): 0.76 mg/l Exposure time: 96 h : EC50 (Daphnia magna (Water flea)): 7.7 mg/l Exposure time: 48 h : 1 Persistence and degradability Biodegradability Biodegradability : Result: Readily biodegradable. Biodegradation: > 90 % Exposure time: 21 d : Result: Readily biodegradable. Biodegradation: 98.3 % Exposure time: 28 d Method: OECD Test Guideline 301F Bioaccumulative potential Partition coefficient: n- octanol/water Partition coefficient: n- octanol/water Partition coefficient: n- octanol/water : log Pow: : log Pow: : log Pow: 3.27 Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of wastes in an approved waste disposal facility. 11 / 13

12 Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. SECTION 14. TRANSPORT INFORMATION International Regulation IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good National Regulations ADG Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Standard for the Uniform Scheduling of Medicines and Poisons : Schedule 5 Prohibition/Licensing Requirements : There is no applicable prohibition or notification/licensing requirements, including for carcinogens under Commonwealth, State or Territory legislation. The components of this product are reported in the following inventories: CH INV TSCA DSL AICS NZIoC ENCS ISHL KECI PICCS IECSC : All components of this product are on the Canadian DSL. 12 / 13

13 EINECS Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION Date format : dd.mm.yyyy The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 13 / 13