ANC-MORT-(WIT-P200)-COAXCART-420ML

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Product code : (A) Manufacturer or supplier's details Company : Wurth Australia Pty Ltd Address : 2/1 Healey Road Dandenong South, Victoria, 3175 Telephone : Emergency telephone number : Advisory office in case of poisoning - National Poisons Centre: address : prodsafe@wuerth.com Recommended use of the chemical and restrictions on use Recommended use : Adhesives SECTION 2. HAZARDS IDENTIFICATION GHS Classification Serious eye damage/eye irritation : Category 2A Skin sensitisation : Category 1 GHS label elements Hazard pictograms : Signal word : Warning Hazard statements : H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. Precautionary statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/ eye protection/ face protection. Response: 1 / 19

2 P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P363 Wash contaminated clothing before reuse. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards which do not result in classification None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Concentration (% w/w) Titanium dioxide >= 60 -<= 100 Quartz >= 60 -<= 100 Tetramethylene dimethacrylate >= 10 -< 30 vinyltoluene < 10 Quartz < 10 2,2'-[(4-methylphenyl)imino]bisethanol < 10 SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. Get medical attention if symptoms occur. In case of skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Get medical attention. If swallowed : If swallowed, DO NOT induce vomiting. 2 / 19

3 Get medical attention if symptoms occur. Rinse mouth thoroughly with water. Most important symptoms and effects, both acute and delayed : May cause an allergic skin reaction. Causes serious eye irritation. Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. Notes to physician : Treat symptomatically and supportively. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Specific extinguishing methods Special protective equipment for firefighters : None known. : Exposure to combustion products may be a hazard to health. : Carbon oxides Nitrogen oxides (NOx) Metal oxides Silicon oxides : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. 3 / 19

4 Methods and materials for containment and cleaning up : Sweep up or vacuum up spillage and collect in suitable container for disposal. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use only with adequate ventilation. Advice on safe handling : Do not get on skin or clothing. Do not swallow. Do not get in eyes. Handle in accordance with good industrial hygiene and safety practice. Take care to prevent spills, waste and minimize release to the environment. Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. Conditions for safe storage : Keep in properly labelled containers. Store in accordance with the particular national regulations. Materials to avoid : Do not store with the following product types: Strong oxidizing agents Recommended storage temperature : 5-25 C SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Titanium dioxide TWA 10 mg/m3 AU OEL Further information: This value is for inhalable dust containing no asbestos and < 1% crystalline silica TWA 10 mg/m3 ACGIH (Titanium dioxide) Quartz TWA (Res- 0.1 mg/m3 AU OEL 4 / 19

5 pirable dust) vinyltoluene TWA 50 ppm AU OEL 242 mg/m3 STEL 100 ppm AU OEL 483 mg/m3 TWA 50 ppm ACGIH STEL 100 ppm ACGIH Quartz TWA (Res- 0.1 mg/m3 AU OEL pirable dust) TWA (Respirable fraction) mg/m3 (Silica) ACGIH These substance(s) are inextricably bound in the product and therefore do not contribute to a dust inhalation hazard. Titanium dioxide Quartz Engineering measures : Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations. Personal protective equipment Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Filter type : Combined particulates and organic vapour type Hand protection Material : Nitrile rubber Break through time : > 480 min Glove thickness : 0.5 mm Directive : DIN EN 374 Material : Chemical-resistant gloves Remarks : Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Safety goggles Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure 5 / 19

6 potential. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc). SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Pasty solid Colour : beige Odour : characteristic Odour Threshold : No data available ph : No data available Melting point/freezing point : No data available Initial boiling point and boiling range : No data available Flash point : Not applicable Evaporation rate : Not applicable Flammability (solid, gas) : Not classified as a flammability hazard Upper explosion limit / Upper flammability limit Lower explosion limit / Lower flammability limit : No data available : No data available Vapour pressure : Not applicable Relative vapour density : Not applicable Density : g/cm3 (20 C) Solubility(ies) Water solubility : insoluble (20 C) Partition coefficient: n- octanol/water : Not applicable Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity Viscosity, kinematic : Not applicable Explosive properties : Not explosive 6 / 19

7 Oxidizing properties : The substance or mixture is not classified as oxidizing. Particle size : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : Can react with strong oxidizing agents. Conditions to avoid : None known. Incompatible materials : Oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION Exposure routes : Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 2,000 mg/kg Method: Calculation method Acute inhalation toxicity : Acute toxicity estimate: > 20 mg/l Exposure time: 4 h Test atmosphere: vapour Method: Calculation method Titanium dioxide: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 6.82 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Quartz: 7 / 19

8 Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute oral toxicity : LD50 (Rat): 10,066 mg/kg Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Acute oral toxicity : LD50 (Rat): 3,300 mg/kg Acute inhalation toxicity : LC50 (Rat): 17 mg/l Exposure time: 4 h Test atmosphere: vapour Acute dermal toxicity : LD50 (Rabbit): > 4,500 mg/kg Quartz: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute oral toxicity : LD50 (Rat): 2,000 mg/kg Method: OECD Test Guideline 423 Skin corrosion/irritation Not classified based on available information. Titanium dioxide: Species: Rabbit Result: No skin irritation Species: Rabbit Result: No skin irritation Result: Skin irritation Method: OECD Test Guideline 439 Result: Skin irritation Serious eye damage/eye irritation Causes serious eye irritation. 8 / 19

9 Titanium dioxide: Species: Rabbit Result: No eye irritation Species: Rabbit Result: No eye irritation Result: Irritation to eyes, reversing within 21 days Result: Irreversible effects on the eye Method: Bovine cornea (BCOP) Respiratory or skin sensitisation Skin sensitisation May cause an allergic skin reaction. Respiratory sensitisation Not classified based on available information. Titanium dioxide: Test Type: Local lymph node assay (LLNA) Exposure routes: Skin contact Species: Mouse Test Type: Local lymph node assay (LLNA) Exposure routes: Skin contact Species: Mouse Method: OECD Test Guideline 429 Result: positive Assessment: Probability or evidence of low to moderate skin sensitisation rate in humans Test Type: Maximisation Test Exposure routes: Skin contact Species: Guinea pig Method: OECD Test Guideline / 19

10 Chronic toxicity Germ cell mutagenicity Not classified based on available information. Titanium dioxide: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Genotoxicity in vivo : Test Type: In vivo micronucleus test Species: Mouse Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 : Test Type: Chromosome aberration test in vitro Method: OECD Test Guideline 473 : Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Method: OECD Test Guideline 474 Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) : Test Type: In vitro mammalian cell gene mutation test Genotoxicity in vivo : Test Type: Mutagenicity (in vivo mammalian bone-marrow cytogenetic test, chromosomal analysis) Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline / 19

11 Carcinogenicity Not classified based on available information. Titanium dioxide: Application Route: inhalation (dust/mist/fume) Exposure time: 2 Years Method: OECD Test Guideline 453 Result: positive Remarks: The mechanism or mode of action may not be relevant in humans. These substance(s) are inextricably bound in the product and therefore do not contribute to a dust inhalation hazard. Carcinogenicity - Assessment : Limited evidence of carcinogenicity in inhalation studies with animals. Application Route: inhalation (vapour) Exposure time: 103 weeks Quartz: Species: Humans Application Route: inhalation (dust/mist/fume) Result: positive Remarks: IARC: (International Agency for Research on Cancer) These substance(s) are inextricably bound in the product and therefore do not contribute to a dust inhalation hazard. Carcinogenicity - Assessment : Positive evidence from human epidemiological studies (inhalation) Reproductive toxicity Not classified based on available information. Effects on fertility : Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Method: OECD Test Guideline 422 Effects on foetal develop- : Test Type: Combined repeated dose toxicity study with the 11 / 19

12 ment reproduction/developmental toxicity screening test Method: OECD Test Guideline 422 Effects on fertility : Test Type: Two-generation reproduction toxicity study Effects on foetal development : Test Type: Embryo-foetal development Effects on fertility : Test Type: Reproduction/Developmental toxicity screening test Method: OECD Test Guideline 421 Effects on foetal development : Test Type: Reproduction/Developmental toxicity screening test Method: OECD Test Guideline 421 STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Quartz: Exposure routes: inhalation (dust/mist/fume) Target Organs: Lungs Assessment: Shown to produce significant health effects in animals at concentrations of 0.02 mg/l/6h/d or less. 12 / 19

13 Repeated dose toxicity Titanium dioxide: NOAEL: 24,000 mg/kg Exposure time: 28 Days NOAEL: 10 mg/m3 Application Route: inhalation (dust/mist/fume) Exposure time: 2 yr Remarks: These substance(s) are inextricably bound in the product and therefore do not contribute to a dust inhalation hazard. NOAEL: 300 mg/kg Exposure time: 33 Days Method: OECD Test Guideline 422 Quartz: Species: Humans LOAEL: mg/m3 Application Route: inhalation (dust/mist/fume) Remarks: These substance(s) are inextricably bound in the product and therefore do not contribute to a dust inhalation hazard. NOAEL: >= 75 mg/kg Exposure time: 28 Days Method: OECD Test Guideline 407 Aspiration toxicity Not classified based on available information. The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard. 13 / 19

14 SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Titanium dioxide: Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h Toxicity to algae : EC50 (Skeletonema costatum (marine diatom)): > 10,000 mg/l Exposure time: 72 h Toxicity to microorganisms : EC50: > 1,000 mg/l Exposure time: 3 h Method: OECD Test Guideline 209 Quartz: Ecotoxicology Assessment Acute aquatic toxicity : No toxicity at the limit of solubility Chronic aquatic toxicity : No toxicity at the limit of solubility Toxicity to fish : EC50 (Leuciscus idus (Golden orfe)): 32.5 mg/l Exposure time: 48 h Method: DIN Toxicity to algae : EC10 (Desmodesmus subspicatus (green algae)): 4.35 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 ErC50 (Desmodesmus subspicatus (green algae)): 9.79 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : EC10 (Daphnia magna (Water flea)): 7.51 mg/l Exposure time: 21 d Method: OECD Test Guideline 211 Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 5.2 mg/l Exposure time: 96 h Method: OECD Test Guideline / 19

15 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 1.3 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae : ErC50 (Pseudokirchneriella subcapitata (green algae)): 2.6 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 NOEC (Pseudokirchneriella subcapitata (green algae)): 1.6 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Quartz: Ecotoxicology Assessment Acute aquatic toxicity : No toxicity at the limit of solubility Chronic aquatic toxicity : No toxicity at the limit of solubility Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 140 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): 10.8 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 EC10 (Desmodesmus subspicatus (green algae)): 8.1 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to fish (Chronic toxicity) Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Danio rerio (zebra fish)): 100 mg/l Exposure time: 8 d : NOEC (Daphnia magna (Water flea)): 13 mg/l Exposure time: 21 d Method: OECD Test Guideline 211 Toxicity to microorganisms : NOEC: 499 mg/l Exposure time: 3 h 15 / 19

16 Persistence and degradability Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 28 d Method: OECD Test Guideline 310 Biodegradability : Result: rapidly degradable Biodegradability : Result: Not readily biodegradable. Biodegradation: 24 % Exposure time: 28 d Method: OECD Test Guideline 301B Bioaccumulative potential Partition coefficient: n- octanol/water : log Pow: 3.1 Bioaccumulation : Species: Lepomis macrochirus (Bluegill sunfish) Bioconcentration factor (BCF): <= 180 Partition coefficient: n- octanol/water : log Pow: 3.35 Partition coefficient: n- octanol/water : log Pow: 1.09 Mobility in soil No data available Other adverse effects No data available 16 / 19

17 SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal. If not otherwise specified: Dispose of as unused product. SECTION 14. TRANSPORT INFORMATION International Regulations UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations ADG Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Standard for the Uniform Scheduling of Medicines and Poisons : No poison schedule number allocated Prohibition/Licensing Requirements : Quartz Quartz Refer to model WHS Act and Regulations for prohibition, authorisation and restricted use. The components of this product are reported in the following inventories: AICS : All ingredients listed or exempt. SECTION 16. OTHER INFORMATION Further information 17 / 19

18 Revision Date : Sources of key data used to compile the Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD echem Portal search results and European Chemicals Agency, Items where changes have been made to the previous version are highlighted in the body of this document by two vertical lines. Date format : dd.mm.yyyy Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) AU OEL : Australia. Workplace Exposure Standards for Airborne Contaminants. ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit AU OEL / TWA : Exposure standard - time weighted average AU OEL / STEL : Exposure standard - short term exposure limit AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen, Mutagen or Reproductive Toxicant; CPR - Controlled Products Regulations; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; SADT - Self- Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vpvb - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System 18 / 19

19 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the appropriateness of the SDS material in the user s end product, if applicable. AU / EN 19 / 19