@ Advanced Materials - Silicones

Transcription

1 Manufactured By: Revised: Preparer: CHEMTREC Chemical Family/Use: Formula: GESA Euless Plant S. Pipeline Rd Euless TX PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS Adhesive Mixture HMlS Flammability: 4 Reactivity: 0 Health: 1 Prot. Equipm.: NFPA Flammability: 4 Reactivity: 0 Health: 1 Special Haz.: PRODUCT COMPOSITION 1 CAS REG NO. I WGT.% A. HAZARDOUS Toluene NAPHTHA (PETROLEUM) Hexane Aromatic Hydrocabon Resin BUTADl ENE-STYRENE COPOLYMER Modified Hydrocarbon Resin % B. NON-HAZARDOUS Limestone Alum inurn Silicate Yo O/o EMERGENCY OVERVIEW Danger! Extremely Flammable Irritating to eyes, respiratory system and skin. Harmful if swallowed, inhaled, or absorbed through the skin. May cause adverse liver, kidney, and CNS effects. May cause allergic skin reaction. May cause adverse reproductive effects. May cause adverse cardiac effects. May cause adverse blood system effects. Form: liquid Color: tan Odor: Hydrocarbons Page 111

2 POTENTIAL HEALTH EFFECTS INGESTION Harmful if swallowed. Irritation of the mouth, throat, and stomach. May cause pulmonary edema. SKIN May cause allergic skin reaction. May be absorbed through skin and produce effects as listed under "Ingestion ". Can cause irritation and reddening of the skin. INHALATION Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Harmful if inhaled. Causes irritation of the mouth, nose, and throat. Can cause unconsciousness if inhaled. Massive inhalation immediately dangerous to life and health. EYES Contact can cause severe irritation and conjunctivitis (redness and swelling). MEDICAL CONDITIONS AGGRAVATED Liver, kidney Central nervous system disorders. Pre-existing skin or respiratory diseases. Eye disorders. SUBCHRONIC (TARGET ORGAN ) Liver and kidney damage.; Reproductive hazard; Central nervous system; Bone marrow and hematopoietic (blood forming) system; Skin; Upper respiratory tract; Cardiovascular effects. CHRONIC EFFECTS / CARCINOGENICITY This product or one of its ingredients present at 0.1 o/o or more is NOT listed as a carcinogen or suspected carcinogen by NTP, IARC, or OSHA. ROUTES OF EXPOSURE dermal: Eyes: Inhalation OTHER Stimulants such as epinephrine may induce ventricular fibrillation. The metabolism of other solvents may be inhibited resulting in a potentiation of toxic effects of those chemicals. Uptake is directly proportional to the amount of body fat. Blood levels may be cumulative when exposure is extended. More severe effects if alcohol is consumed. May cross react with similar compounds. INGESTION Do not induce vomiting. If victim is conscious, give 1-3 glasses of water to drink. Never give anything by mouth to an unconscious person. Get medical attention if irritation persists. SKIN Wash with soap and water. Get medical attention if irritation or symptoms from Section 3 develop. Page 212

3 GE400 CONTRACTOR S GRADE INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration using a barrier device. breathing is difficult give oxygen. Get medical attention. If EYES In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. NOTE TO PHYSICIAN Treatment is symptomatic and supportive. FLASH POINT: METHOD: IGNITION TEMPERATURE: FLAMMABLE LIMITS IN AIR - LOWER (%): FLAMMABLE LIMITS IN AIR - UPPER ( 7 0): SENSITIVITY TO MECHANICAL IMPACT: c C; O F closed cup No SENSITIVITY TO STATIC DISCHARGE Sensitivity to static discharge is not expected. EXTINGUISHING MEDIA All standard extinguishing agents are suitable. SPECIAL FIRE FIGHTING PROCEDURES Firefighters must wear NIOSH/MSHA approved positive pressure self-contained breathing apparatus with full face mask and full protective clothing. ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking surfaces with detergent and water to reduce slipping hazard. Wear proper protective equipment as specified in the protective equipment section. STORAGE Store at room temperature in the original container. Keep container closed. Page 313

4 @ Advanced Materials - Siiicones GE400 CONTRACTOR S GRADE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Avoid contact with skin, eyes and clothing. Keep away from children. Attention: Not for injection into humans. May generate formaldehyde at temperatures greater than 150 C (300 F). See Section 10 of MSDS for details. ENGINEERING CONTROLS Eyewash stations; Showers; Exhaust ventilation RESPIRATORY PROTECTION If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Supplied air respirators may be required for non-routine or emergency situations. Respiratory protection must be provided in accordance with OSHA regulations (see 29 CFR ). PROTECTIVE GLOVES Cloth gloves. EYE AND FACE PROTECTION Safety glasses with side-shields OTHER PROTECTIVE EQUIPMENT Wear suitable protective clothing and eye/face protection. Exposure Guidelines Component CAS RN Source Value Toluene ACGIH, TWA 50 PPm Toluene ACGIH, SKIN-DES Can be absorbed through the skin. Toluene OSHA Z1A, TWA 100 ppm; 375 mg/m3 Toluene OSHA Z1A, STEL 150 ppm; 560 mglm3 Hexane ACGIH, TWA 50 PPm Hexane ACGIH, SKIN-DES Can be absorbed through the skin. Hexane OSHA Z1A, TWA 50 ppm; 180 mg/m3 Absence of values indicates none found PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value: TWA -Time Weighted Average OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 1lih Circuit Court of Appeals decision (AFL-CIO v. OSHA) effective June 30, See 29 CFR (58 FR 35338). BOILING POINT - C & F: >57.22 C; O F Page 414

5 VAPOR PRESSURE (20 C) (MM HG): VAPOR DENSITY (AIR=l): FREEZING POINT: MELTING POINT: PHYSICAL STATE: ODOR: COLOR: EVAPORATION RATE (BUTYL ACETATEGl): SPECIFIC GRAVITY (WATER=l): DENSITY: ph: VOLATILE ORGANIC CONTENT (VOL): SOLUBILITY IN WATER (20 C): SOLUBILITY IN ORGANIC SOLVENT (STATE SOLVENT): VOC EXCL. H20 81EXEMPTS (G/L): >1 not applicable not applicable liquid Hydrocarbons tan 1.1 1,100 g/cm3 not applicable %(m) insoluble Soluble, Petroleum Solvents c 392 STAB1LlTY Stable HAZARD0US POLYMERI2ATI0N HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS Carbon monoxide: Carbon dioxide (C02): Toxic fumes.; Hydrocarbons INCOMPATIBILITY (MATERIALS TO AVOID) Acids Bases Oxidizing agents Strong oxidizing agents CONDITIONS TO AVOID Keep away from heat, sparks and flame. ACUTE ORAL Remarks: ACUTE DERMAL Remarks: ACUTE INHALATION Remarks: OTHER Page 515

6 Verslon: I25l2QQ6 SENSITIZATION SKIN IRRITATION EYE IRRITATION MUTAGENICITY ECOTOXICOLOGY CHEMICAL FATE DISTRIBUTION DISPOSAL METHOD Disposal should be made in accordance with federal, state and local regulations. Further Information: This product considered hazardous for trasportation. GE Advanced Materials, Silicones ships this material under Limited Quantity or Consumer Commodity provisions of the transport regulations. Inventories Canada DSL Inventory China Inventory of Existing Chemical Substances TSCA list y (positive listing) y (positive listing) y (positive listing) Page 616

7 Canada NDSL Inventory Japan Inventory of Existing i3 New Chemical Substances (ENCS) Korea Existing Chemicals Inventory (KECI) Australia Inventory of Chemical Substances (AICS) Philippines Inventory of Chemicals and Chemical Substances (PICCS) For inventories that are marked as quantity restricted or special cases, please contact GE. US Regulatory Information CERCLA PRODUCT COMPOSITION CLEAN AIR ACT Chemical CERCLA Reportable Quantity CLEAN WATER ACT SARA SECTION 302 SARA (311,312) HAZARD CLASS Acute Health Hazard; Chronic Health Hazard; Fire Hazard SARA (313) CHEMICALS Canadian Regulatory Information WHMIS HAZARD CLASS Flammable Liquid, D2A VERY TOXIC MATERIALS, D2B TOXIC MATERIALS Other SCHDLE B/HTSUS: ECCN: Mastics based on rubber EAR99 CALIFORNIA PROPOSITION 65 Warning! This product contains a chemical known to the State of California to cause cancer, birth defects or other reproductive harm Toluene. Page 717

8 OTHER C = ceiling limit NEGL = negligible EST = estimated NF = none found NA = not applicable UNKN = unknown NE = none established REC = recommended ND = none determined V = recommended by vendor SKN = skin TS =trade secret R = recommended MST = mist NT = not tested STEL = short term exposure limit ppm = parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status not required under 40 CFR part (h -2)., These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. Page 81%