Material safety data sheet Metalaxyl 8% + Mancozeb 64 % WP

Transcription

1 1. IDENTIFICATION OF COMPANY & PRODUCT Product Name : Metalaxyl 8% + Mancozeb 64% WP Chemical Name : manganese ethylenebis (dithiocarbamate) (polymeric) complex with zinc salt Metalaxyl: - 2-[(2, 6-dimethylphenyl) - (2-methoxy-1-oxoethyl) amino] propionic acid methyl ester Brand Name : IBEX Users : Fungicide Molecular Formula : Metalaxyl: C15H21NO4; Mancozeb: (C4H6MnN2S4) X (Zn) Y Manufacturer : CROP LIFE SCIENCE LTD. Address : Plot No. 5165, 5166, 5151, G.I.D.C., Ankleshwar Gujarat, India Tele Fax Number : COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS # Percent Or Content(W/W) Metalaxyl % Mancozeb % Other ingredients -- Q.S. 3. HEALTH HAZARDS IDENTIFICATION Eye contact Skin contact : May cause irritation of nose, throat and lungs. : Direct contact with material may cause irritation. : Prolonged or repeated skin contact may cause possible skin irritation, or dermatitis due to skin sensitization. 4. FIRST AID MEASURES Eye contact Skin contact : Move subject to fresh air. : Flush eyes with water. Consults a physician if irritation persists. : Wash affected skin areas thoroughly with soap and water. Consult a physician if irritation persists. Remove and wash contaminated clothing thoroughly. Do not take clothing home to be laundered. Ingestion: If swallowed, give 2 glasses of water to drink. See a physician. Never give anything by mouth to an unconscious person. Page 1 of 5

2 5. FIRE FIGHTING MEASURES Flammability : Non-flammable solid. Extinguishing media : Dry powder, CO2, Water spray or Foam. Special fire fighting Procedures Unusual fire and Explosion hazards 6. ACCIDENTAL RELEASE MEASURES : Wear full protective clothing and self-contained breathing apparatus. Use water spray cooling tank or container. Keep persons remove and upwind. : Hazardous gases or vapors produced in fire areh2s, CS2 and oxides of carbon, nitrogen & sulfur. Personal protection : Appropriate protective equipment must be worn when handling as pill of this material. See SECTION 8, Exposure Controls/Personal Protection, for recommendations. If exposed to material during cleanup operation, see SECTION 4, First Aid Measures, for actions to follow. Remove all contaminated clothing promptly. Wash all exposed skin areas with soap and water immediately after exposure. Thoroughly launder clothing before reuse. Do not take clothing home to be laundered. Procedures: Keep spectators away. Avoid breathing dust. Transfer spilled material to suitable containers for recovery or disposal. Keep dust to a minimum. CAUTION! Keep spills and cleaning runoff out of municipal sewers and open bodies of water. 7. HANDLING AND STORAGE Storage conditions: Do not store this material near food, feedstuff or drinking water. Store in a dry, wellventilated area in original package. Keep container tightly closed when not in use. Handling procedures: Do not handle material near food, feedstuff or drinking water. When handling and processing this material local exhaust ventilation may be required to control dust and reduce exposure to vapors. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION : Use local exhaust ventilation with a minimum capture velocity of 45 m/min. at the point of dust evolution. Page 2 of 5

3 Exposure limit Information Respiratory Protection Eye protection Hand protection Other protection : Mancozeb: 5 mg/m 3 (ACGIH_STEL) : Use appropriate respiratory protection whenever workplace conditions warrant a respirator s use. : Use chemical splash goggles. Eye protection worn must be compatible with respiratory protection system employed. : Chemical-resistant gloves should be worn whenever this material is handled. Rinse and remove gloves immediately after use. Wash hands with soap and water. : Use chemically resistant apron or other impervious clothing to avoid prolonged or repeated skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Greyish yellow loose fine Powder Odor : Musty odor Specific Gravity/density: Not available Melting point : Not applicable Solubility in water : Form suspension with water Molecular formula : Metalaxyl: C15H21NO4; Mancozeb: (C4H6MnN2S4) X (Zn) Y Molecular weight : Metalaxyl: 279.3; Mancozeb: STABILITY AND REACTIVITY Stability Incompatibility Hazard Decomposition Hazardous Polymerization : Stable under normal storage conditions. Keep away from moisture, heat or fire. : Avoid contact with moisture, oxidizing agents and acids. : Thermal decomposition may yield carbon disulfide and hydrogen sulfide. : Will not occur. Page 3 of 5

4 11. TOXICOLOGICAL INFORMATION Acute oral : LD50 for rats >5000mg/kg. Low toxicity. Acute Dermal : LD50 for rabbits >5000mg/kg. Low toxicity. : LC50 for rats >2.0mg/L for 4 hours. Low toxicity. Skin irritation : Practically non-irritating (rabbits) Eye irritation : Irritation (rabbits) 12. ECOLOGICAL INFORMATION Metalaxyl: Bees Mancozeb: Bees LD50 for Japanese quail (7 days) 923 mg/kg; Mallard ducks (8 days) 1466 mg/kg. LC50 (8 days) Japanese quail, bobwhite quail and mallard ducks > mg/kg LC50 (96 h) for rainbow trout, carp, and bluegill sunfish > 100 mg/l : LD50 (48 h) (contact) > 200 µg/bee; (oral) µg/bee Worms: LC50 (14 days) for Eisenia foetida > 1000 mg/kg Soil Daphnia: LC50 (48 h) >28 mg/l Algae: IC50 (5 days) for Scenedesmus subspicatus 33 mg/l In ten-day dietary studies, there were no mortalities in mallard ducks at 6400 mg/kg daily and in Japanese quail at 3200 mg/kg daily LC50 (48 h) for goldfish 9.0 mg/l; rainbow trout 2.2mg/l; catfish 5.2 mg/l; carp 4.0 mg/l : LC mg/bee According to the above information, REMEX 72 WP is practically non-toxic to birds and moderately toxic to fish 13. DISPOSAL CONSIDERATIONS For disposal, incinerate this material at a facility that complied with local, state and country regulations. Page 4 of 5

5 14. TRANSPORT INFORMATION Class: 9 UN number: 3077 Packing group: III Shipping name: Environmentally Hazardous Substance, Solid 15. REGULATORY INFORMATION Hazard Classification: Risk Phrases: R 22 Harmful if swallowed R 36/38 Irritating to eyes and skin R 37 Irritating to respiratory system R 43 May cause sensitization by skin contact Safety Phrases: S 2 Keep out of reach of children S 8 keep container dry S 24/25 Avoid contact with skin and eyes S 36/37 Wear suitable protective clothing and gloves 16. OTHER INFORMATION The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall CLSL be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if CLSL has been advised of the possibility of such damages. Page 5 of 5