MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Version # 05 Issue date Revision date Supersedes date CAS # Old Fashioned Whiting Compound, 3 lb Mixture Product code Manufacturer information 2. Hazards Identification BROWNELLS, INC. 200 South Front Street Montezuma, Iowa United States (641) hour Emergency Number, Domestic: (800) hour Emergency Number, Foreign: +1(352) INFOTRAC Registrant #79335 Emergency overview WARNING Harmful in contact with eyes. Irritating to eyes, respiratory system and skin. OSHA regulatory status Potential health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms Potential environmental effects Exposure to powder or dusts may be irritating to eyes, nose and throat. May cause damage to organs through prolonged or repeated exposure. Prolonged exposure may cause chronic effects. Dangerous for the environment if discharged into watercourses. This product is considered hazardous under 29 CFR (Hazard Communication). Inhalation. Ingestion. Skin contact. Eye contact. Do not get this material in contact with eyes. Dust may cause mechanical irritation to eyes. Eye contact may result in corneal injury. Avoid contact with the skin. Irritating to skin. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Do not breathe dust. May cause irritation to the respiratory system. Do not ingest. May cause irritation. Components of the product may be absorbed into the body by ingestion. Eyes. Respiratory system. Skin. Conjunctiva. Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. Corneal damage. Conjunctivitis. Irritation of eyes and mucous membranes. Irritating to mouth, throat, and stomach. Skin irritation. Defatting of the skin. Rash. Prolonged exposure may cause chronic effects. Respiratory disease may be aggravated by exposure. May cause long-term adverse effects in the environment. Potentially toxic to aquatic life. 3. Composition / Information on Ingredients Components CAS # Percent CALCIUM CARBONATE / 6

2 4. First Aid Measures First aid procedures Eye contact Skin contact Inhalation Ingestion tes to physician General advice Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention if symptoms persist. Remove and isolate contaminated clothing and shoes. Wash off skin immediately with plenty of soap and water for at least 15 minutes. If symptoms persist, get medical attention. For minor skin contact, avoid spreading material on unaffected skin. Wash clothing separately before reuse. Remove to fresh air. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. If symptoms persist, get medical attention. Rinse mouth thoroughly. Never give anything by mouth to an unconscious person. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. If symptoms persist, get medical attention. Provide general supportive measures and treat symptomatically. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. If you feel unwell, seek medical advice (show the label where possible). Wash contaminated clothing before reuse. Show this material safety data sheet (MSDS) to the doctor in attendance. 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods The product is non-combustible. Use fire-extinguishing media appropriate for surrounding materials. Avoid extinguishing media unsuitable for surrounding materials. Use protective equipment appropriate for surrounding materials. In the event of fire, cool tanks with water spray. Cool containers exposed to flames with water until well after the fire is out. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. See Section 8 of the MSDS for Personal Protective Equipment. Ventilate closed spaces before entering them. Avoid dust formation. Avoid inhalation of dust from the spilled material. Avoid release to the environment. Prevent entry into waterways, sewer, basements or confined areas. Avoid dust formation. Ventilate the contaminated area. Should not be released into the environment. Use dustless methods for cleanup. Collect dust using a vacuum cleaner equipped with HEPA filter. If not possible, moisten dust with water before it is collected with shovel, broom or the like. Avoid dry sweeping. Place material in appropriate container for disposal. Other information Never return spills in original containers for re-use. For waste disposal, see section 13 of the MSDS. Clean up in accordance with all applicable regulations. 2 / 6

3 7. Handling and Storage Handling Storage 8. Exposure Controls / Personal Protection Occupational exposure limits ACGIH Components CALCIUM CARBONATE (CAS ) Do not handle until all safety precautions have been read and understood. Avoid dust formation. Provide appropriate exhaust ventilation at places where dust is formed. Do not breathe dust from this material. Avoid contact with skin and eyes. Avoid prolonged exposure. In case of insufficient ventilation, wear suitable respiratory equipment. See Section 8 of the MSDS for Personal Protective Equipment. Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Practice good housekeeping. Avoid release to the environment. Store in a dry area. Store in a well-ventilated place. Store in a closed container away from incompatible materials (see Section 10 of the MSDS for incompatible materials). Protect against physical damage. Avoid dust formation. Keep away from food, drink and animal feedingstuffs. Keep out of the reach of children. Use care in handling/storage. Type Value TWA 10 mg/m3 Dust US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Components Type CALCIUM CARBONATE (CAS ) US. NIOSH: Pocket Guide to Chemical Hazards Components Type CALCIUM CARBONATE (CAS ) Engineering controls Personal protective equipment Eye / face protection Skin protection Respiratory protection General hygiene considerations 9. Physical & Chemical Properties Appearance Appearance Odor Physical state Color Odor threshold ph Vapor pressure Vapor density Boiling point Melting point/freezing point Solubility (water) Value PEL 5 mg/m3 Respirable fraction. 15 mg/m3 Total dust. Value TWA 5 mg/m3 Respirable. 10 mg/m3 Total Ventilation should be sufficient to effectively remove and prevent buildup of any dusts or fumes that may be generated during handling or thermal processing. Provide eyewash station. Do not get in eyes. Chemical goggles are recommended. Use tight fitting goggles if dust is generated. Eye wash fountain is recommended. Avoid contact with the skin. Wear suitable protective clothing, gloves, and footwear, selected with regard for use conditions and exposure. Wear appropriate chemical resistant gloves. Wear respirator with dust filter. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. When using, do not eat, drink or smoke. Do not breathe dust. Do not get in eyes. Avoid contact with skin. Wash hands before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practice. Gray powder. Solid. Powder. Gray. Odorless (5% water suspension) 1.3 g/l 3 / 6

4 Specific gravity Relative density Flash point Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Auto-ignition temperature Evaporation rate Other data Decomposition temperature Density Flammability (solid, gas) 2.70 g/cm3 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions Material is stable under normal conditions. ne. Strong acids. Fluorine. ne. Hazardous polymerization does not occur. 11. Toxicological Information Sensitization Acute effects Local effects Chronic effects Carcinogenicity Skin corrosion/irritation Epidemiology Mutagenicity Reproductive effects Symptoms and target organs Further information Components of the product may be absorbed into the body through the skin. Irritating to eyes, respiratory system and skin. Inhalation of dusts may cause respiratory irritation. Hazardous by OSHA criteria. Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. May cause damage to organs through prolonged or repeated exposure. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Causes skin irritation. Irritant effects. 12. Ecological Information Ecotoxicity Environmental effects Aquatic toxicity Persistence and degradability Bioaccumulation / Accumulation Mobility in environmental media Toxic to aquatic life. Contains a substance which causes risk of hazardous effects to the environment. Toxic to aquatic organisms. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Toxic to aquatic organisms. Product contains alkaline material potentially toxic to aquatic life if concentration is high for extended periods of time. 13. Disposal Considerations Disposal instructions Dispose of in accordance with current, applicable local, state, and federal regulations. 4 / 6

5 Waste from residues / unused products Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport Information DOT t regulated as dangerous goods. IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. 15. Regulatory Information US federal regulations All components are on the U.S. EPA TSCA Inventory List. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR (b) and (f)(2) and Chemical Code Number t listed. Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR (c)) DEA Exempt Chemical Mixtures Code Number TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) CERCLA (Superfund) reportable quantity ne Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical Inventory status Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) State regulations WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. 5 / 6

6 US - California Proposition 65 - CRT: Listed date/carcinogenic substance Listed: October 1, 1992 Carcinogenic. US - California Proposition 65 - CRT: Listed date/developmental toxin Listed: February 27, 1987 Developmental toxin. US - California Proposition 65 - CRT: Listed date/female reproductive toxin Listed: February 27, 1987 Female reproductive toxin. US - California Proposition 65 - CRT: Listed date/male reproductive toxin US - New Jersey RTK - Substances: Listed substance CALCIUM CARBONATE (CAS ) US. Massachusetts RTK - Substance List CALCIUM CARBONATE (CAS ) US. Pennsylvania RTK - Hazardous Substances CALCIUM CARBONATE (CAS ) US. Rhode Island RTK 16. Other Information Recommended use Recommended restrictions Further information HMIS ratings Health: 1 Flammability: 0 Physical hazard: 0 Personal protection: E NFPA ratings Health: 1 Flammability: 0 Instability: 0 Disclaimer This data sheet contains changes from the previous version in section(s): Listed: February 27, 1987 Male reproductive toxin. Listed. Listed. HMIS is a registered trade and service mark of the NPCA. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. First Aid Measures: General advice 6 / 6