SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification. Other means of identification SDS number 11 Recommended use

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification SDS number 11 Recommended use Automotive Oxime curing RTV silicone sealant. Recommended restrictions ne known. Manufacturer/Importer/Supplier/Distributor information Manufacturer: Hylomar Ltd. Address: Hylo House, Cale Lane, New Springs, Wigan, Greater Manchester, UK, WN2 1JT Telephone number: +44(0) address: Contact person: Technical Department Emergency telephone: (USA, Canada, Mexico) Access code: Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements t classified. Serious eye damage/eye irritation Sensitization, skin Specific target organ toxicity, repeated exposure t classified. Category 2A Category 1 Category 2 (lungs) Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Warning Causes serious eye irritation. May cause an allergic skin reaction. May cause damage to organs (lungs) through prolonged or repeated exposure. Do not breathe mist or vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Get medical advice/attention if you feel unwell. If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Store away from incompatible materials. Dispose of contents/container in accordance with local/regional/national/international regulations. ne known. ne Version #: 02 Revision date: 03-January-2018 Issue date: 24-May / 7

2 3. Composition/information on ingredients Mixtures Chemical name Siloxanes and silicones, di-me, hydroxy-terminated Polydimethylsiloxane Kaolin, calcined Silica, amorphous, fumed Butan-2-one O,O',O''-(methylsilylidyne)trioxi me Butan-2-one O,O',O'',O'''-silanetetrayltetraox ime 3-aminopropyltriethoxysilane CAS number % <1 Composition comments 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods General fire hazards 6. Accidental release measures Personal precautions, protective equipment and emergency procedures All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Components not listed are either non-hazardous or are below reportable limits. Move to fresh air. Call a physician if symptoms develop or persist. Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause an allergic skin reaction. Dermatitis. Rash. Prolonged exposure may cause chronic effects. Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. unusual fire or explosion hazards noted. Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS Version #: 02 Revision date: 03-January-2018 Issue date: 24-May / 7

3 Methods and materials for containment and cleaning up The product is immiscible with water and will sediment in water systems. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-3 (29 CFR ) Components Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. Do not breathe mist or vapor. Avoid contact with eyes, skin, and clothing. Persons susceptible to allergic reactions should not handle this product. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). Type Value Silica, amorphous, fumed (CAS ) TWA US. NIOSH: Pocket Guide to Chemical Hazards Components Type 0.8 mg/m3 20 mppcf Value Silica, amorphous, fumed (CAS ) Biological limit values Exposure guidelines Appropriate engineering controls TWA biological exposure limits noted for the ingredient(s). 6 mg/m3 Occupational Exposure Limits are not relevant to the current physical form of the product. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide easy access to water supply and eye wash facilities. Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles). Eye/face protection Skin protection Hand protection Wear appropriate chemical resistant gloves. Nitrile, butyl rubber or neoprene gloves are recommended. Skin protection Other Respiratory protection Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Physical state Form Color Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In case of inadequate ventilation or risk of inhalation of vapors, use suitable respiratory equipment with combination filter. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. Liquid. Paste. Black Version #: 02 Revision date: 03-January-2018 Issue date: 24-May / 7

4 Odor Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Characteristic. Oxime odor F (200.0 C) (Approx.) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Solubility (solvents) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Explosive limit Explosive properties Oxidizing properties VOC 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information 1.17 (20 C/68 F) Insoluble in water. Miscible in acetone. 824 F (440 C) t explosive. t oxidizing. 0 (Hylomar Test Method 1.1A Determination of Volatile Matter) The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. dangerous reaction known under conditions of normal use. Contact with incompatible materials. Strong oxidizing agents. Fluorine. Chlorine. Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors. Silicon oxides. Information on likely routes of exposure Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics May cause an allergic skin reaction. Causes serious eye irritation. May cause discomfort if swallowed. However, ingestion is not likely to be a primary route of occupational exposure. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause an allergic skin reaction. Dermatitis. Rash Version #: 02 Revision date: 03-January-2018 Issue date: 24-May / 7

5 Information on toxicological effects Acute toxicity Components t expected to be acutely toxic. Species 3-aminopropyltriethoxysilane (CAS ) Acute Test Results Dermal LD50 Rabbit 4076 mg/kg (Male and female) Oral LD50 Rat 2688 mg/kg (Female) Butan-2-one O,O',O'',O'''-silanetetrayltetraoxime (CAS ) Acute 1492 mg/kg (Male) Dermal LD50 Rabbit > 2000 mg/kg Oral LD50 Rat 2453 mg/kg Polydimethylsiloxane (CAS ) Acute Dermal LD50 Rabbit > 5000 mg/kg Oral LD50 Rat > mg/kg Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Prolonged skin contact may cause temporary irritation. Causes serious eye irritation. t a respiratory sensitizer. May cause an allergic skin reaction. data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. t classifiable as to carcinogenicity to humans. IARC Monographs. Overall Evaluation of Carcinogenicity Silica, amorphous, fumed (CAS ) NTP Report on Carcinogens OSHA Specifically Regulated Substances (29 CFR ) Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Further information 12. Ecological information Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil 3 t classifiable as to carcinogenicity to humans. This product is not expected to cause reproductive or developmental effects. t classified. May cause damage to organs (lungs) through prolonged or repeated exposure. t an aspiration hazard. May cause damage to organs through prolonged or repeated exposure. Symptoms may be delayed. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. data is available on the degradability of this product. data available. The product is insoluble in water. Expected to have low mobility in soil Version #: 02 Revision date: 03-January-2018 Issue date: 24-May / 7

6 Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT t regulated as dangerous goods. IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) SARA 304 Emergency release notification OSHA Specifically Regulated Substances (29 CFR ) Superfund Amendments and Reauthorization Act of 1986 (SARA) SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical Classified hazard categories SARA 313 (TRI reporting) Other federal regulations Serious eye damage or eye irritation Respiratory or skin sensitization Specific target organ toxicity (single or repeated exposure) Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) US state regulations US. Massachusetts RTK - Substance List Silica, amorphous, fumed (CAS ) Version #: 02 Revision date: 03-January-2018 Issue date: 24-May / 7

7 US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania Worker and Community Right-to-Know Law Silica, amorphous, fumed (CAS ) US. Rhode Island RTK California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines Taiwan United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Taiwan Chemical Substance Inventory (TCSI) Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s). A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Revision date Version # 02 HMIS ratings NFPA ratings 24-May January-2018 Health: 2* Flammability: 1 Physical hazard: List of abbreviations LD50: Lethal Dose, 50%. TWA: Time weighted average. References Disclaimer This SDS contains revisions in the following section(s): IARC Monographs. Overall Evaluation of Carcinogenicity HSDB - Hazardous Substances Data Bank The information in the sheet was written based on the best knowledge and experience currently available. 11, Version #: 02 Revision date: 03-January-2018 Issue date: 24-May / 7