Safety Data Sheet. according to Regulation (EU) No. 1907/2006. SYMPROfluid universal

Transcription

1 Page 1 of 5 1. Identification of the substance/preparation and of the company/undertaking Identification of the substance or preparation Use of the substance/preparation Special denture cleaner for use in a denture cleaning appliance with needles. Company/undertaking identification Company name : Street : Untere Giesswiesen 2 Place : D-7247 Hilzingen Telephone : Telefax : Contact person : Frau Andris Telephone : andris@renfert.com Internet : Emergency telephone : Vergiftungs-Zentrale Freiburg Hazards identification Classification Indications of danger : Irritant R-phrases : Irritating to eyes, respiratory system and skin. 3. Composition/information on ingredients Chemical characterization ( Mixture ) Acid cleaning agent Hazardous components EC-No. CAS-No. Chemical name Quantity Classification hydrochloric acid... % < 10 % C, Xi R methanesulphonic acid < 5 % C R Fettalkohol, ethoxyliert < 5 % Xi R (2-butoxyethoxy)ethanol, diethylene < 5 % Xi R36 glycol monobutyl ether Full text of each relevant R phrase can be found in heading First aid measures General information Take off immediately all contaminated clothing After inhalation Provide fresh air. After contact with skin After contact with skin, wash immediately with plenty of Water and soap. In case of skin irritation, seek medical treatment. After contact with eyes In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After ingestion

2 Page 2 of 5 5. Fire-fighting measures Rinse mouth immediately and drink large quantities of water. Do not induce vomiting. Immediately get medical attention. Suitable extinguishing media Material is not combustible. Extinguishing materials should be selected according to the surrounding area. Special exposure hazards arising from substance or preparation itself, combustion products, resulting gases In case of fire may form: Hydrochloric (HCl). Sulfur oxides. Special protective equipment for fire-fighters In case of fire: Wear self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. 6. Accidental release measures Personal precautions Wear personal protection equipment. Provide adequate ventilation. Environmental precautions Methods for cleaning up/taking up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Collect in closed containers for disposal. 7. Handling and storage Handling Advice on safe handling Handle open container with care. Wear personal protection equipment. Avoid contact with skin and eyes. Advice on protection against fire and explosion No special precautionary measures are necessary. Storage Requirements for storage rooms and vessels Keep only in the original container in a cool, well ventilated place. Keep container tightly closed. Advice on storage compatibility Do not store together with: Alkalis (alkalis). Further information on storage conditions Keep away from food, drink and animal feeding stuffs.. Exposure controls/personal protection Exposure limit values

3 Page 3 of 5 Exposure limits (EH40) CAS-No. Chemical name ml/m³ mg/m³ F/ml Category Origin (2-Butoxyethoxy)ethanol ,2 TWA ( h) WEL Exposure controls Occupational exposure controls See chapter 7. No further action is necessary ,5 STEL (15 min) WEL Protective and hygiene measures Take off immediately all contaminated clothing "Wash hands when done working with material; at breaks, lunch, shift changes, etc." Avoid contact with skin and eyes. Respiratory protection Provide adequate ventilation. Respiratory protection required in case of: aerosol or mist generation. Hand protection Tested protective gloves are to be worn: CR (polychloroprenes, Chloroprene rubber). Butyl rubber. FKM (Fluoroelastomer (Viton)). In the cases of special applications, it is recommended to check the chemical resistance with the manufacturer of the gloves. Eye protection Tightly sealed safety glasses. Environmental exposure controls 9. Physical and chemical properties General information Physical state : Colour : Odour : liquid colourless fruity Important health, safety and environmental information ph-value (at 20 C) : 1 Changes in the physical state Boiling point : Flash point : Density (at 20 C) : Water solubility : Viscosity / dynamic : > 100 C not applicable 1,02-1,06 g/cm³ complete miscible product has not been tested. Test method 10. Stability and reactivity Conditions to avoid Thermal decomposition can lead to the escape of irritating gases and vapors. Materials to avoid Reacts with : Alkalis (alkalis). Corrosive to most metals. Hazardous decomposition products Hydrochloric (HCl). sulfur oxides.

4 Page 4 of Toxicological information Corrosive and irritant effects Irritant effect on the skin: irritant. Irritant effect on the eye: irritant. Sensitising effects no danger of sensitization. Additional information on tests The classification was undertaken in accordance with the calculation method governed by the Preparations Directive (1999/45/EC). Empirical data on effects on humans Irritating to eyes, respiratory system and skin. 12. Ecological information Persistence and degradability The surfactants contained in the product are biodegradable according to the requirements of the Detergent Directive 64/2004/EC. Other adverse effects product is acid. The product needs to apply neutralizing agents before draining to wastewater treatment plants. Further information Water risk class: 1 Mild water pollutant 13. Disposal considerations Advice on disposal Remove according to the regulations. product is acid. The product needs to apply neutralizing agents before draining to wastewater treatment plants. Waste disposal number of waste from residues/unused products MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND INSTITUTIONAL WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS; separately collected fractions (except 15 01); detergents containing dangerous substances Classified as hazardous waste. Contaminated packaging Handle contaminated packaging in the same way as the substance itself. 14. Transport information Land transport (ADR/RID) UN number : ADR/RID class : Warning plate ADR/RID packing group : ÄTZENDER SAURER ANORGANISCHER FLÜSSIGER STOFF, N.A.G. Marine transport UN number : IMDG code :

5 Page 5 of 5 Marine pollutant : IMDG packing group : no CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Alkylsulphonic acid and hydrochloric acid mixture) Air transport UN/ID number : ICAO/IATA-DGR : ICAO packing group : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Alkylsulphonic acid and hydrochloric acid mixture) 15. Regulatory information Labelling Danger symbols : Xi - Irritant R phrases 36/37/3 Irritating to eyes, respiratory system and skin. S phrases 24/25 Avoid contact with skin and eyes. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. EU regulatory information 1999/13/EC (VOC) : 0 g/l Additional information Labelling for contents according to regulation (EC) No 64/2004: < 5% non-ionic surfactants, perfumes National regulatory information Water contaminating class (D) : 1 - slightly water contaminating Additional information M 004 Reizende Stoffe / Ätzende Stoffe (BGI 595) 16. Other information Full text of R-phrases referred to under sections 2 and 3 34 Causes burns. 36 Irritating to eyes. 36/37/3 Irritating to eyes, respiratory system and skin. 37 Irritating to respiratory system. 3 Irritating to skin. Further Information The information is based on present level of our knowledge. It does not, however, give assurances of product properties and establishes no contract legal rights. The receiver of our product is singulary responsible for adhering to existing laws and regulations. Reserved for industrial and professional use. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)