PHTHALIC ANHYDRIDE FOR SYNTHESIS MSDS. CAS No: MSDS MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 MSDS CAS No: MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance : EC index no : EC no : CAS No : Product code : Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : Industrial. For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number : (9:00am - 6:00 pm) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Serious eye damage/eye irritation, Category 1 Sensitisation Respiratory, category 1 Acute toxicity (oral), Category 4 Skin corrosion/irritation, Category 2 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation Sensitisation Skin, category 1 H318 H334 H302 H315 H335 H317 Full text of classification categories and H statements : see section 16 Version: 1 15/09/2016 1/10

2 Classification according to Directive 67/548/EEC or 1999/45/EC Xn; R22 R42 Xi; R41 Xi; R37/38 R43 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) : Danger GHS05 GHS08 GHS07 : H302 - Harmful if swallowed H315 - Causes skin irritation H317 - May cause an allergic skin reaction H318 - Causes serious eye damage H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 - May cause respiratory irritation : P261 - Avoid breathing dust/fume/gas/mist/vapours/spray P280 - Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER/doctor/ 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Name : PHTHALIC ANHYDRIDE FOR SYNTHESIS CAS No : EC no : EC index no : Full text of R- and H-phrases: see section 16 Version: 1 15/09/2016 2/10

3 3.2. Mixture Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. : Wash with plenty of soap and water. Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. : Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell. : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation. : Causes skin irritation. : Causes serious eye damage. : Swallowing a small quantity of this material will result in serious health hazard Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Evacuate unnecessary personnel. : Use personal protective equipment as required Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers Reference to other sections Version: 1 15/09/2016 3/10

4 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Avoid contact with skin and eyes. Avoid dust formation. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour. : Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Storage conditions : Keep container tightly closed. Store in a well-ventilated place Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection : Protective gloves : Chemical goggles or face shield : Wear suitable protective clothing : In case of inadequate ventilation wear respiratory protection SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Colour Odour Odour threshold : White crystalline. : characteristic choking odor. ph : 2 at 6 g/l at 20 C Relative evaporation rate (butylacetate=1) Melting point : C Freezing point Boiling point : 284 C Flash point : 152 C Auto-ignition temperature : 570 C Decomposition temperature Flammability (solid, gas) Vapour pressure : < 0.01 hpa at 20 C Version: 1 15/09/2016 4/10

5 Relative vapour density at 20 C : 6.6 Relative density Density : 1.53 g/cm³ Solubility : Water: C Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : vol % 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Incompatible materials Oxidizing agent Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Oral: Harmful if swallowed. Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity : Causes skin irritation. ph: 2 at 6 g/l at 20 C : Causes serious eye damage. ph: 2 at 6 g/l at 20 C : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. : Not classified : Not classified Reproductive toxicity : Not classified Version: 1 15/09/2016 5/10

6 Specific target organ toxicity (single exposure) : May cause respiratory irritation. Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential adverse human health effects and symptoms : Harmful if swallowed. SECTION 12: Ecological information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose of contents/container to.. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) : 2214 UN-No. (IMDG) : 2214 UN-No.(IATA) : 2214 UN-No.(ADN) UN-No. (RID) Version: 1 15/09/2016 6/10

7 14.2. UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) : PHTHALIC ANHYDRIDE : PHTHALIC ANHYDRIDE : PHTHALIC ANHYDRIDE : UN 2214 PHTHALIC ANHYDRIDE, 8, III, (E) : UN 2214 PHTHALIC ANHYDRIDE, 8, III : UN 2214 PHTHALIC ANHYDRIDE, 8, III Transport hazard class(es) ADR Transport hazard class(es) (ADR) : 8 Danger labels (ADR) : 8 : IMDG Transport hazard class(es) (IMDG) : 8 Danger labels (IMDG) : 8 : IATA Transport hazard class(es) (IATA) : 8 Hazard labels (IATA) : 8 : ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment : III : III : III : No Version: 1 15/09/2016 7/10

8 Marine pollutant Other information : No : No supplementary information available Special precautions for user - Overland transport Classification code (ADR) : C4 Special provision (ADR) : 169 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Special packing provisions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage : 5kg : E1 : P002, IBC08, LP02, R001 : B3 : MP10 : T1 : TP33 : SGAV, L4BN : AT Transport category (ADR) : 3 Special provisions for carriage - Bulk (ADR) Hazard identification number (Kemler No.) : 80 Orange plates : : VC1, VC2, AP7 Tunnel restriction code (ADR) EAC code : E : 2X - Transport by sea Special provision (IMDG) : 169, 939 Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) IBC packing instructions (IMDG) IBC special provisions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) : 5 kg : E1 : P002, LP02 : IBC08 : B3 : T1 : TP33 : F-A : S-B : A : E1 : Y845 : 5kg PCA packing instructions (IATA) : 860 PCA max net quantity (IATA) : 25kg CAO packing instructions (IATA) : 864 CAO max net quantity (IATA) Special provision (IATA) ERG code (IATA) : 100kg : A74 : 8L Version: 1 15/09/2016 8/10

9 - Inland waterway transport Not regulated - Rail transport Not regulated Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions PHTHALIC ANHYDRIDE FOR SYNTHESIS is not on the REACH Candidate List PHTHALIC ANHYDRIDE FOR SYNTHESIS is not on the REACH Annex XIV List National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to VwVwS, Annex 2; WGK No 732) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Classification remarks Recommendations Danish Regulation : Emergency management guidelines for the storage of flammable liquids must be followed : Young people below the age of 18 years are not allowed to use the product Chemical safety assessment SECTION 16: Other information Full text of R-, H- and EUH-phrases: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Resp. Sens. 1 Sensitisation Respiratory, category 1 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation Skin, category 1 Version: 1 15/09/2016 9/10

10 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H302 Harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 May cause respiratory irritation R22 Harmful if swallowed R37/38 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R42 May cause sensitization by inhalation R43 May cause sensitisation by skin contact Xi Irritant Xn Harmful This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product Version: 1 15/09/ /10