MATERIAL SAFETY DATA SHEET (MSDS)

Transcription

1 SODIUM HYDROXIDE TS (1N) ACC. TO USP MSDS CAS-No. MSDS MATERIAL SAFETY DATA SHEET (MSDS) SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product code Mixture US Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Industrial For professional use only Uses advised against 1.3. Details of the supplier of the safety data sheet LOBA CHEMIE PVT.LTD. 107 Wode House Road, Jehangir Villa, Colaba Mumbai - INDIA T F info@lobachemie.com Emergency telephone number Emergency number (900am pm) SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances SDS EU 2015 According to Regulation (EU) 2015/830 (REACH Annex II) Skin corrosion/irritation, Category 1 H314 Full text of H statements see section 16 Adverse physicochemical, human health and environmental effects 20/12/2018 1/10

2 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS05 Danger H314 - Causes severe skin burns and eye damage. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER/doctor 2.3. Other hazards SECTION 3 Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] WATER AR (CAS-No.) (EC-No.) Not classified SODIUM HYDROXIDE FLAKES Extra Pure (CAS-No.) (EC-No.) Met. Corr. 1, H290 Skin Corr. 1A, H314 Full text of H-statements see section 16 SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Give oxygen or artificial respiration if necessary. Gently wash with plenty of soap and water. If skin irritation or rash occurs Get medical advice/attention. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists Get medical advice/attention. Rinse mouth out with water. If you feel unwell, seek medical advice. 20/12/2018 2/10

3 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects Causes severe skin burns and eye damage Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). Do not use extinguishing media containing water Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protection during firefighting Do not attempt to take action without suitable protective equipment. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Avoid contact with skin, eyes and clothing. Use personal protective equipment as required Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Clean up immediately by sweeping or vacuum Reference to other sections SECTION 7 Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Avoid contact with skin and eyes. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Conditions for safe storage, including any incompatibilities Storage conditions Store in a well-ventilated place. Keep cool Specific end use(s) SECTION 8 Exposure controls/personal protection 8.1. Control parameters 20/12/2018 3/10

4 8.2. Exposure controls Hand protection Eye protection Skin and body protection Respiratory protection Protective gloves Chemical goggles or safety glasses Wear suitable protective clothing Wear respiratory protection. SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits Clear Colorless. No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available 9.2. Other information SECTION 10 Stability and reactivity Reactivity 20/12/2018 4/10

5 10.2. Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Direct sunlight Incompatible materials Hazardous decomposition products SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Not classified Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Causes severe skin burns and eye damage. Serious eye damage, category 1, implicit Not classified Not classified Not classified Reproductive toxicity STOT-single exposure Not classified Not classified STOT-repeated exposure Not classified Aspiration hazard Not classified SECTION 12 Ecological information Toxicity Persistence and degradability Bioaccumulative potential 20/12/2018 5/10

6 12.4. Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13 Disposal considerations Waste treatment methods SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 1824 UN-No. (IMDG) 1824 UN-No. (IATA) 1824 UN-No. (ADN) 1824 UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) Transport document description (IATA) Transport document description (ADN) Transport document description (RID) SODIUM HYDROXIDE SOLUTION SODIUM HYDROXIDE SOLUTION Sodium hydroxide solution SODIUM HYDROXIDE SOLUTION SODIUM HYDROXIDE SOLUTION UN 1824 SODIUM HYDROXIDE SOLUTION, 8, III, (E) UN 1824 SODIUM HYDROXIDE SOLUTION, 8, III UN 1824 Sodium hydroxide solution, 8, III UN 1824 SODIUM HYDROXIDE SOLUTION, 8, III UN 1824 SODIUM HYDROXIDE SOLUTION, 8, III Transport hazard class(es) ADR Transport hazard class(es) (ADR) 8 Danger labels (ADR) 8 IMDG Transport hazard class(es) (IMDG) 8 Danger labels (IMDG) /12/2018 6/10

7 IATA Transport hazard class(es) (IATA) 8 Hazard labels (IATA) 8 ADN Transport hazard class(es) (ADN) 8 Danger labels (ADN) 8 RID Transport hazard class(es) (RID) 8 Danger labels (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information III III III III III No No No supplementary information available Special precautions for user - Overland transport Classification code (ADR) Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) C5 5l E1 P001, IBC03, LP01, R001 MP /12/2018 7/10

8 Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage T4 TP1 L4BN AT Transport category (ADR) 3 Special provisions for carriage - Packages (ADR) V12 Hazard identification number (Kemler No.) 80 Orange plates Tunnel restriction code (ADR) EAC code E 2R - Transport by sea Special provisions (IMDG) 223 Packing instructions (IMDG) IBC packing instructions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) Segregation (IMDG) Properties and observations (IMDG) - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) P001, LP01 IBC03 T4 TP1 F-A S-B A SG35 Colourless liquid. Colourless liquid. Reacts with ammonium salts, evolving ammonia gas. Causes burns to skin, eyes and mucous membranes. Reacts violently with acids. E1 Y841 1L PCA packing instructions (IATA) 852 PCA max net quantity (IATA) 5L CAO packing instructions (IATA) 856 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) 60L A3, A803 8L C5 5 L E1 T Number of blue cones/lights (ADN) 0 PP, EP - Rail transport Classification code (RID) Excepted quantities (RID) Packing instructions (RID) Mixed packing provisions (RID) C5 E1 P001, IBC03, LP01, R001 MP /12/2018 8/10

9 Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) T4 TP1 Transport category (RID) 3 Special provisions for carriage Packages (RID) Colis express (express parcels) (RID) L4BN W12 CE8 Hazard identification number (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany Reference to AwSV 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Water hazard class (WGK) 3, severe hazard to water (Classification according to AwSV, Annex 1) Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling None of the components are listed None of the components are listed None of the components are listed None of the components are listed None of the components are listed Denmark Recommendations Danish Regulation Young people below the age of 18 years are not allowed to use the product Chemical safety assessment 20/12/2018 9/10

10 SECTION 16 Other information Full text of H- and EUH-statements Met. Corr. 1 Corrosive to metals, Category 1 Skin Corr. 1 Skin corrosion/irritation, Category 1 Skin Corr. 1A Skin corrosion/irritation, Category 1A H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 20/12/ /10